X-ray emission spectroscopy: an effective route to extract site occupation of cations

Bhargava, Anuj; Chen, Cindy Y.; Finkelstein, Kenneth D.; Ward, Matthew J.; Robinson, Richard D.

doi:10.1039/C8CP04628J

Title: X-ray emission spectroscopy: an effective route to extract site occupation of cations

Journal Article · 28 November 2018 · Physical Chemistry Chemical Physics. PCCP

DOI: https://doi.org/10.1039/C8CP04628J · OSTI ID:1471782

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Department of Materials Science and Engineering, Cornell University, Ithaca, USA
Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, USA
Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, USA, CLS@APS

Cation site occupation is an important determinant of materials properties, especially in a complex system with multiple cations such as in ternary spinels. In this work, we show that XES provides not only the site occupation information as EXAFS, but also additional information on the oxidation states of the cations at each site. Additionally, we show that XES is a superior and a far more accurate method than EXAFS.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1471782

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 46 Vol. 20; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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