Title: Simultaneous nitrosylation and N-nitrosation of a Ni-thiolate model complex of Ni-containing SOD

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/C8SC03321H · OSTI ID:1471780
ORCiD logo [1]; ORCiD logo [1];  [2];  [3];  [2]; ORCiD logo [1]
  1. Department of Chemistry, Center for Metalloenzyme Studies, The University of Georgia, Athens, USA
  2. Departments of Pharmaceutical Sciences, Biochemistry, and Molecular Biology, Wayne State University, Detroit, USA
  3. Department of Chemistry and Biochemistry, Florida International University, Miami, USA

Nitric oxide reacts with a NiSOD model complex to yield a thiolate-ligated/N-nitrosated {NiNO} 10 species with unusually labile Ni–NO bonds.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
National Institutes of Health (NIH); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1471780
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 45 Vol. 9; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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