A New Insight into Cross-Sensitivity to Humidity of SnO2 Sensor

Zhu, He; Li, Qiang; Ren, Yang; Gao, Qilong; Chen, Jun; Wang, Na; Deng, Jinxia; Xing, Xianran

doi:10.1002/smll.201703974

Title: A New Insight into Cross-Sensitivity to Humidity of SnO₂ Sensor

Journal Article · 29 January 2018 · Small

DOI: https://doi.org/10.1002/smll.201703974 · OSTI ID:1471538

Zhu, He ^[1]; Li, Qiang ^[1]; Ren, Yang ^[2]; Gao, Qilong ^[1]; Chen, Jun ^[1]; Wang, Na ^[1]; Deng, Jinxia ^[1]; Xing, Xianran ^[1]

Univ. of Science and Technology Beijing, Beijing (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

Abstract The efficiency of gas sensors varies enormously from fundamental study to practical application. This big gap comes mainly from the complex and unpredictable effect of atmospheric environment, especially in humidity. Here, the cross‐sensitivity to humidity of a SnO ₂ sensor from local structural and lattice evolutions is studied. The sensing response of ethanol is found to be efficiently activated by adsorbing trace of water but inhibited as humidity increases. By X‐ray diffraction, pair distribution function of synchrotron and ab initio calculations, the independent effect of water and ethanol on lattice and local structure are clearly revealed, which elucidate the intricate sensing reactions. The formation of hydrogen bonds and repulsion of ethoxides play key roles in the structural distortions, and also in adsorption energies that are critical to the sensitive behavior. The results show the sensor performance coupled with local structural evolution, which provides a new insight into the controversial effects of humidity on SnO ₂ sensors.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities

Grant/Contract Number:: AC02-06CH11357; AC02‐06CH11357

OSTI ID:: 1471538

Alternate ID(s):: OSTI ID: 1418415

Journal Information:: Small, Vol. 14, Issue 13; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 35 works

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