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Title: Cobalt complexes of the chelating dicarboxylate ligand “esp”: a paddlewheel-type dimer and a heptanuclear coordination cluster

Abstract

Reaction of CoCO 3 with α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid (H 2 esp) in EtOH forms the paddlewheel-type dimer Co 2 (esp) 2 (EtOH) 2 , which hydrolyzes in MeCN to give a bowl-shaped heptacobalt coordination cluster complex; both compounds display antiferromagnetic interactions between high-spin Co( ii ) ions.

Authors:
ORCiD logo [1]; ORCiD logo [1]
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  1. Department of Chemistry, University of Wisconsin – Madison, Madison, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1471425
Grant/Contract Number:  
SC0016442
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 39; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Pakula, Ryan J., and Berry, John F. Cobalt complexes of the chelating dicarboxylate ligand “esp”: a paddlewheel-type dimer and a heptanuclear coordination cluster. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT03030H.
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Pakula, Ryan J., & Berry, John F. Cobalt complexes of the chelating dicarboxylate ligand “esp”: a paddlewheel-type dimer and a heptanuclear coordination cluster. United Kingdom. https://doi.org/10.1039/C8DT03030H
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Pakula, Ryan J., and Berry, John F. Tue . "Cobalt complexes of the chelating dicarboxylate ligand “esp”: a paddlewheel-type dimer and a heptanuclear coordination cluster". United Kingdom. https://doi.org/10.1039/C8DT03030H.
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@article{osti_1471425,
title = {Cobalt complexes of the chelating dicarboxylate ligand “esp”: a paddlewheel-type dimer and a heptanuclear coordination cluster},
author = {Pakula, Ryan J. and Berry, John F.},
abstractNote = {Reaction of CoCO 3 with α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid (H 2 esp) in EtOH forms the paddlewheel-type dimer Co 2 (esp) 2 (EtOH) 2 , which hydrolyzes in MeCN to give a bowl-shaped heptacobalt coordination cluster complex; both compounds display antiferromagnetic interactions between high-spin Co( ii ) ions.},
doi = {10.1039/C8DT03030H},
journal = {Dalton Transactions},
number = 39,
volume = 47,
place = {United Kingdom},
year = {Tue Oct 09 00:00:00 EDT 2018},
month = {Tue Oct 09 00:00:00 EDT 2018}
}
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https://doi.org/10.1039/C8DT03030H
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