Pore-scale supercritical CO2 dissolution and mass transfer under drainage conditions

Chang, Chun; Zhou, Quanlin; Oostrom, Mart; Kneafsey, Timothy J.; Mehta, Hardeep

doi:10.1016/j.advwatres.2016.12.003

Title: Pore-scale supercritical CO₂ dissolution and mass transfer under drainage conditions

Abstract

No abstract.

Authors:

Chang, Chun ^[1]; Zhou, Quanlin ^[2]; Oostrom, Mart ^[3]; Kneafsey, Timothy J. ^[2]; Mehta, Hardeep ^[3]

China Univ. of Mining & Technology, Beijing (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Publication Date:: Mon Dec 05 00:00:00 EST 2016

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI Identifier:: 1379705

Alternate Identifier(s):: OSTI ID: 1426303; OSTI ID: 1471017

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Advances in Water Resources

Additional Journal Information:: Journal Volume: 100; Journal ID: ISSN 0309-1708

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 54 ENVIRONMENTAL SCIENCES; Geological carbon sequestration; Micromodel; Drainage; Dissolution; Mass transfer

Citation Formats


                    Chang, Chun, Zhou, Quanlin, Oostrom, Mart, Kneafsey, Timothy J., and Mehta, Hardeep. Pore-scale supercritical CO2 dissolution and mass transfer under drainage conditions.  United States: N. p., 2016. 
Web.  doi:10.1016/j.advwatres.2016.12.003.

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                    Chang, Chun, Zhou, Quanlin, Oostrom, Mart, Kneafsey, Timothy J., & Mehta, Hardeep. Pore-scale supercritical CO2 dissolution and mass transfer under drainage conditions.  United States.  https://doi.org/10.1016/j.advwatres.2016.12.003

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                    Chang, Chun, Zhou, Quanlin, Oostrom, Mart, Kneafsey, Timothy J., and Mehta, Hardeep. Mon .  
"Pore-scale supercritical CO2 dissolution and mass transfer under drainage conditions".  United States.  https://doi.org/10.1016/j.advwatres.2016.12.003.  https://www.osti.gov/servlets/purl/1379705.

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@article{osti_1379705,

  title        = {Pore-scale supercritical CO2 dissolution and mass transfer under drainage conditions},

  author       = {Chang, Chun and Zhou, Quanlin and Oostrom, Mart and Kneafsey, Timothy J. and Mehta, Hardeep},

  abstractNote = {No abstract.},

  doi          = {10.1016/j.advwatres.2016.12.003},

  journal      = {Advances in Water Resources},

  number       = ,

  volume       = 100,

  place        = {United States},

  year         = {Mon Dec 05 00:00:00 EST 2016},

  month        = {Mon Dec 05 00:00:00 EST 2016}

}

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https://doi.org/10.1016/j.advwatres.2016.12.003

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Cited by: 19 works

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Works referenced in this record:

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Works referencing / citing this record:

Microfluidics for Porous Systems: Fabrication, Microscopy and Applications
journal, November 2018

Gerami, Alireza; Alzahid, Yara; Mostaghimi, Peyman
Transport in Porous Media, Vol. 130, Issue 1
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Impacts of Mixed‐Wettability on Brine Drainage and Supercritical CO ₂ Storage Efficiency in a 2.5‐D Heterogeneous Micromodel
journal, June 2020

Chang, Chun; Kneafsey, Timothy J.; Wan, Jiamin
Water Resources Research, Vol. 56, Issue 7
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Wettability impact on supercritical CO ₂ capillary trapping: Pore-scale visualization and quantification : WETTABILITY ON CO
journal, August 2017

Hu, Ran; Wan, Jiamin; Kim, Yongman
Water Resources Research, Vol. 53, Issue 8
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Non-Darcy interfacial dynamics of air-water two-phase flow in rough fractures under drainage conditions
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Chang, Chun; Ju, Yang; Xie, Heping
Scientific Reports, Vol. 7, Issue 1
DOI: 10.1038/s41598-017-04819-x

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Pore-scale supercritical CO₂ dissolution and mass transfer under drainage conditions

Journal Article Chang, Chun ; Zhou, Quanlin ; Oostrom, Mart ; ... - Advances in Water Resources

Abstract: Recently, both core- and pore-scale imbibition experiments have shown non-equilibrium dissolution of supercritical CO₂ (scCO₂) and a prolonged depletion of residual scCO₂. In this study, pore-scale scCO₂ dissolution and mass transfer under drainage conditions were investigated using a two-dimensional heterogeneous micromodel and a novel fluorescent water dye with a sensitive pH range between 3.7 and 6.5. Drainage experiments were conducted at 9 MPa and 40 °C by injecting scCO₂ into the sandstone-analogue pore network initially saturated by water without dissolved CO₂ (dsCO₂). During the experiments, time-lapse images of dye intensity, reflecting water pH, were obtained. These images show non-uniformmore »« less
https://doi.org/10.1016/j.advwatres.2016.12.003
Pore-scale supercritical CO2 dissolution and mass transfer under imbibition conditions

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In modeling of geological carbon storage, dissolution of supercritical CO2 (scCO2) is often assumed to be instantaneous with equilibrium phase partitioning. In contrast, recent core-scale imbibition experiments have shown a prolonged depletion of residual scCO2 by dissolution, implying a non-equilibrium mechanism. In this study, eight pore-scale scCO2 dissolution experiments in a 2D heterogeneous, sandstone-analogue micromodel were conducted at supercritical conditions (9 MPa and 40 °C). The micromodel was first saturated with deionized (DI) water and drained by injecting scCO2 to establish a stable scCO2 saturation. DI water was then injected at constant flow rates after scCO2 drainage was completed. Highmore »« less
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Geological carbon storage in deep aquifers involves displacement of resident brine by supercritical CO₂ (scCO₂), which is an unstable drainage process caused by the invasion of less viscous scCO₂. The unstable drainage is greatly complicated by aquifer heterogeneity and anisotropy and regarded as one of the key factors accounting for the uncertainty in storage capacity estimates. The impacts of pore-scale characteristics on the unstable drainage remain poorly understood. In this study, scCO₂ drainage experiments were conducted at 40 °C and 9 MPa using a homogeneous elliptical micromodel with low or high anisotropy, a homogeneous/isotropic hexagonal micromodel, and a heterogeneous sandstone-analog micromodel. Each initially water-saturated micromodel was invaded by scCO₂ at different rates with logC_a (the capillary number) ranging from -7.6 to -4.4, and scCO₂/water images were obtained. The measured CO₂ saturations in these centimeter-scale micromodels vary considerably from 0.08 to 0.93 depending on the pore-scale characteristics and capillary number. It was also observed that scCO₂ drainage follows the classic flow-regime transition from capillary fingering through crossover to viscous fingering for either of the low-anisotropy elliptical and heterogeneous micromodels, but with disparate crossover zones. The crossover zones of scCO₂ saturation were then unified with the minimum scCO₂ saturation occurring at logCmore » $$_a^*$$= -4.0 using the complete capillary number (C$$_a^*$$)that considers pore characteristics. For the hexagonal and the high-anisotropy elliptical micromodels, a monotonic increase in scCO₂ saturation with increasing C$$_a^*$$ (without crossover) was observed. It appears that the complete capillary number is more appropriate than the classic capillary number when characterizing flow regimes and CO₂ saturation in different pore networks.« less
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We report that wettability is an important factor controlling the displacement of immiscible fluids in porous media and therefore affects the flow and transport of supercritical (sc) CO₂ in geologic carbon sequestration. Because few studies have focused on the wettability effect in scCO₂-brine flow systems, we experimentally and numerically tested influences of wettability on drainage at the pore network scale. Using a high-pressure micromodel-microscopy system, we performed experiments of scCO₂ invasion into brine-saturated water-wet and intermediate-wet micromodels, and recorded the scCO₂ invasion morphology under reservoir relevant conditions. We also performed pore-scale numerical simulations to infer 3D details of fluid–fluid displacementmore »« less
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Title: Pore-scale supercritical CO2 dissolution and mass transfer under drainage conditions

Abstract

Citation Formats

Experimental study on effects of geologic heterogeneity in enhancing dissolution trapping of supercritical CO 2 journal, March 2015

Effects of micro-heterogeneity and hydrodynamic dispersion on the dissolution rate of carbon dioxide in water-saturated porous media journal, September 2012

Relative permeability hysteresis and capillary trapping characteristics of supercritical CO2/brine systems: An experimental study at reservoir conditions journal, February 2013

Displacement and mass transfer between saturated and unsaturated CO2–brine systems in sandstone journal, January 2013

CO2 migration and pressure evolution in deep saline aquifers journal, September 2015

A Study of Microscale Gas Trapping Using Etched Silicon Micromodels journal, August 2012

Dynamic displacement and non-equilibrium dissolution of supercritical CO2 in low-permeability sandstone: An experimental study journal, May 2013

Supercritical CO 2 dissolution and mass transfer in low-permeability sandstone: Effect of concentration difference in water-flood experiments journal, September 2014

Pore-scale supercritical CO2 dissolution and mass transfer under imbibition conditions journal, June 2016

Measured Mass Transfer Coefficients in Porous Media Using Specific Interfacial Area journal, September 2005

Analysis of pore-scale nonaqueous phase liquid dissolution in etched silicon pore networks: PORE-SCALE NAPL DISSOLUTION journal, September 2003

Role of Convective Mixing in the Long-Term Storage of Carbon Dioxide in Deep Saline Formations journal, September 2005

Prediction of carbon dioxide dissolution in bulk water under isothermal pressure decay at different boundary conditions journal, February 2015

Static and dynamic reservoir modeling for geological CO2 sequestration at Cranfield, Mississippi, U.S.A. journal, October 2013

Laboratory Flow Experiments for Visualizing Carbon Dioxide-Induced, Density-Driven Brine Convection journal, October 2009

Relative permeability and trapping of CO 2 and water in sandstone rocks at reservoir conditions : MULTIPHASE FLOW OF CO journal, February 2012

Spreading and convective dissolution of carbon dioxide in vertically confined, horizontal aquifers: DISSOLUTION OF CO journal, November 2012

Convective dissolution of carbon dioxide in saline aquifers: CONVECTIVE DISSOLUTION OF CARBON DIOXIDE journal, November 2010

High-resolution simulation and characterization of density-driven flow in CO2 storage in saline aquifers journal, April 2010

Simultaneous determination of capillary pressure and relative permeability curves from core-flooding experiments with various fluid pairs: Capillary Pressure and Relative Permeability Curves journal, June 2013

Characterization and scaling of mesoscale heterogeneities in sandstones: CAPILLARY HETEROGENEITY AND SCALING journal, August 2013

Capillary pressure and heterogeneity for the CO2/water system in sandstone rocks at reservoir conditions journal, March 2012

ECO2N – A fluid property module for the TOUGH2 code for studies of CO2 storage in saline aquifers journal, June 2007

Onset of convection in a gravitationally unstable diffusive boundary layer in porous media journal, February 2006

Effects of shear-thinning fluids on residual oil formation in microfluidic pore networks journal, June 2016

Integrated reservoir modeling at the Illinois Basin - Decatur Project: Integrated reservoir modeling journal, September 2014

Supercritical CO2 core flooding and imbibition in Tako sandstone—Influence of sub-core scale heterogeneity journal, January 2011

CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar journal, August 2003

CO2-H2O mixtures in the geological sequestration of CO2. II. Partitioning in chloride brines at 12–100°C and up to 600 bar journal, July 2005

Experimental Study of Crossover from Capillary to Viscous Fingering for Supercritical CO 2 –Water Displacement in a Homogeneous Pore Network journal, June 2012

Evaluation of the Effects of Porous Media Structure on Mixing-Controlled Reactions Using Pore-Scale Modeling and Micromodel Experiments journal, May 2008

Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I Brine Pilot journal, March 2010

Liquid CO 2 Displacement of Water in a Dual-Permeability Pore Network Micromodel journal, September 2011

A full chain CCS demonstration project in northeast Ordos Basin, China: Operational experience and challenges journal, July 2016

A method for quick assessment of CO2 storage capacity in closed and semi-closed saline formations journal, October 2008

Modeling Basin- and Plume-Scale Processes of CO2 Storage for Full-Scale Deployment journal, December 2009

Micromodel investigations of CO2 exsolution from carbonated water in sedimentary rocks journal, March 2013

Microfluidics for Porous Systems: Fabrication, Microscopy and Applications journal, November 2018

Impacts of Mixed‐Wettability on Brine Drainage and Supercritical CO 2 Storage Efficiency in a 2.5‐D Heterogeneous Micromodel journal, June 2020

Wettability impact on supercritical CO 2 capillary trapping: Pore-scale visualization and quantification : WETTABILITY ON CO journal, August 2017

Non-Darcy interfacial dynamics of air-water two-phase flow in rough fractures under drainage conditions journal, July 2017

Title: Pore-scale supercritical CO₂ dissolution and mass transfer under drainage conditions

Experimental study on effects of geologic heterogeneity in enhancing dissolution trapping of supercritical CO ₂
journal, March 2015

Effects of micro-heterogeneity and hydrodynamic dispersion on the dissolution rate of carbon dioxide in water-saturated porous media
journal, September 2012

Relative permeability hysteresis and capillary trapping characteristics of supercritical CO2/brine systems: An experimental study at reservoir conditions
journal, February 2013

Displacement and mass transfer between saturated and unsaturated CO2–brine systems in sandstone
journal, January 2013

CO2 migration and pressure evolution in deep saline aquifers
journal, September 2015

A Study of Microscale Gas Trapping Using Etched Silicon Micromodels
journal, August 2012

Dynamic displacement and non-equilibrium dissolution of supercritical CO2 in low-permeability sandstone: An experimental study
journal, May 2013

Supercritical CO 2 dissolution and mass transfer in low-permeability sandstone: Effect of concentration difference in water-flood experiments
journal, September 2014

Pore-scale supercritical CO2 dissolution and mass transfer under imbibition conditions
journal, June 2016

Measured Mass Transfer Coefficients in Porous Media Using Specific Interfacial Area
journal, September 2005

Analysis of pore-scale nonaqueous phase liquid dissolution in etched silicon pore networks: PORE-SCALE NAPL DISSOLUTION
journal, September 2003

Role of Convective Mixing in the Long-Term Storage of Carbon Dioxide in Deep Saline Formations
journal, September 2005

Prediction of carbon dioxide dissolution in bulk water under isothermal pressure decay at different boundary conditions
journal, February 2015

Static and dynamic reservoir modeling for geological CO2 sequestration at Cranfield, Mississippi, U.S.A.
journal, October 2013

Laboratory Flow Experiments for Visualizing Carbon Dioxide-Induced, Density-Driven Brine Convection
journal, October 2009

Relative permeability and trapping of CO ₂ and water in sandstone rocks at reservoir conditions : MULTIPHASE FLOW OF CO
journal, February 2012

Spreading and convective dissolution of carbon dioxide in vertically confined, horizontal aquifers: DISSOLUTION OF CO
journal, November 2012

Convective dissolution of carbon dioxide in saline aquifers: CONVECTIVE DISSOLUTION OF CARBON DIOXIDE
journal, November 2010

High-resolution simulation and characterization of density-driven flow in CO2 storage in saline aquifers
journal, April 2010

Simultaneous determination of capillary pressure and relative permeability curves from core-flooding experiments with various fluid pairs: Capillary Pressure and Relative Permeability Curves
journal, June 2013

Characterization and scaling of mesoscale heterogeneities in sandstones: CAPILLARY HETEROGENEITY AND SCALING
journal, August 2013

Capillary pressure and heterogeneity for the CO2/water system in sandstone rocks at reservoir conditions
journal, March 2012

ECO2N – A fluid property module for the TOUGH2 code for studies of CO2 storage in saline aquifers
journal, June 2007

Onset of convection in a gravitationally unstable diffusive boundary layer in porous media
journal, February 2006

Effects of shear-thinning fluids on residual oil formation in microfluidic pore networks
journal, June 2016

Integrated reservoir modeling at the Illinois Basin - Decatur Project: Integrated reservoir modeling
journal, September 2014

Supercritical CO2 core flooding and imbibition in Tako sandstone—Influence of sub-core scale heterogeneity
journal, January 2011

CO₂-H₂O mixtures in the geological sequestration of CO₂. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar
journal, August 2003

CO2-H2O mixtures in the geological sequestration of CO2. II. Partitioning in chloride brines at 12–100°C and up to 600 bar
journal, July 2005

Experimental Study of Crossover from Capillary to Viscous Fingering for Supercritical CO ₂ –Water Displacement in a Homogeneous Pore Network
journal, June 2012

Evaluation of the Effects of Porous Media Structure on Mixing-Controlled Reactions Using Pore-Scale Modeling and Micromodel Experiments
journal, May 2008

Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I Brine Pilot
journal, March 2010

Liquid CO ₂ Displacement of Water in a Dual-Permeability Pore Network Micromodel
journal, September 2011

A full chain CCS demonstration project in northeast Ordos Basin, China: Operational experience and challenges
journal, July 2016

A method for quick assessment of CO2 storage capacity in closed and semi-closed saline formations
journal, October 2008

Modeling Basin- and Plume-Scale Processes of CO2 Storage for Full-Scale Deployment
journal, December 2009

Micromodel investigations of CO2 exsolution from carbonated water in sedimentary rocks
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