Pressure-mediated structural transitions in bulk
Abstract
The high pressure structural phase diagram of EuTiO3 is revisited by means of single crystal x-ray diffraction at pressures below 30GPa. We report a transition at about 3GPa with a surprisingly small lattice distortion. At 23GPa we have detected a yet unknown transition into a new orthorhombic phase (space group Ibam). Combining our observations on structures obtained on single crystals and polycrystalline samples with complementary methods, such as electrical resistivity and nuclear forward scattering of synchrotron radiation measured on polycrystalline samples, we address issues relevant to chemistry and disorder.
- Authors:
-
- Delft Univ. of Technology (Netherlands)
- Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
- RIKEN, Hyogo (Japan)
- European Synchrotron Radiation Facility (ESRF), Grenoble (France)
- Univ. Munster (Germany)
- Univ. of Bayreuth (Germany)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1470847
- Alternate Identifier(s):
- OSTI ID: 1463757
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 98; Journal Issue: 5; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Bessas, D., Glazyrin, K., Ellis, D. S., Kantor, I., Merkel, D. G., Cerantola, V., Potapkin, V., van Smaalen, S., Baron, A. Q. R., and Hermann, R. P. Pressure-mediated structural transitions in bulk EuTiO3. United States: N. p., 2018.
Web. doi:10.1103/PhysRevB.98.054105.
Bessas, D., Glazyrin, K., Ellis, D. S., Kantor, I., Merkel, D. G., Cerantola, V., Potapkin, V., van Smaalen, S., Baron, A. Q. R., & Hermann, R. P. Pressure-mediated structural transitions in bulk EuTiO3. United States. https://doi.org/10.1103/PhysRevB.98.054105
Bessas, D., Glazyrin, K., Ellis, D. S., Kantor, I., Merkel, D. G., Cerantola, V., Potapkin, V., van Smaalen, S., Baron, A. Q. R., and Hermann, R. P. Thu .
"Pressure-mediated structural transitions in bulk EuTiO3". United States. https://doi.org/10.1103/PhysRevB.98.054105. https://www.osti.gov/servlets/purl/1470847.
@article{osti_1470847,
title = {Pressure-mediated structural transitions in bulk EuTiO3},
author = {Bessas, D. and Glazyrin, K. and Ellis, D. S. and Kantor, I. and Merkel, D. G. and Cerantola, V. and Potapkin, V. and van Smaalen, S. and Baron, A. Q. R. and Hermann, R. P.},
abstractNote = {The high pressure structural phase diagram of EuTiO3 is revisited by means of single crystal x-ray diffraction at pressures below 30GPa. We report a transition at about 3GPa with a surprisingly small lattice distortion. At 23GPa we have detected a yet unknown transition into a new orthorhombic phase (space group Ibam). Combining our observations on structures obtained on single crystals and polycrystalline samples with complementary methods, such as electrical resistivity and nuclear forward scattering of synchrotron radiation measured on polycrystalline samples, we address issues relevant to chemistry and disorder.},
doi = {10.1103/PhysRevB.98.054105},
journal = {Physical Review B},
number = 5,
volume = 98,
place = {United States},
year = {2018},
month = {8}
}
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Works referenced in this record:
Universality aspects of the metal-nonmetal transition in condensed media
journal, March 1978
- Edwards, Peter Phillip; Sienko, Michell J.
- Physical Review B, Vol. 17, Issue 6
Structural and magnetic phase transitions in
journal, July 2015
- Li, Ling; Morris, James R.; Koehler, Michael R.
- Physical Review B, Vol. 92, Issue 2
Pressure-temperature phase diagram of multiferroic
journal, August 2015
- Parisiades, P.; Liarokapis, E.; Köhler, J.
- Physical Review B, Vol. 92, Issue 6
High pressure antiferrodistortive phase transition in mixed crystals of EuTiO 3 and SrTiO 3
journal, June 2016
- Parisiades, Paraskevas; Saltarelli, Francesco; Liarokapis, Efthymios
- AIP Advances, Vol. 6, Issue 6
Nuclear resonance scattering of synchrotron radiation at the 21.5 keV resonance of 151 Eu
journal, September 1996
- Leupold, O.; Pollmann, J.; Gerdau, E.
- Europhysics Letters (EPL), Vol. 35, Issue 9
X‐Ray Diffractometry of Low‐Temperature Phase Transformations in Strontium Titanate
journal, July 1964
- Lytle, Farrel W.
- Journal of Applied Physics, Vol. 35, Issue 7
Reversible control of magnetic interactions by electric field in a single-phase material
journal, January 2013
- Ryan, P. J.; Kim, J-W; Birol, T.
- Nature Communications, Vol. 4, Issue 1
Effect of an Eu3+ impurity on the antiferrodistortion and ferroelectric instabilities in an EuTiO3 bulk crystal and thin films
journal, January 2015
- Zhandun, V. S.; Zamkova, N. G.; Zinenko, V. I.
- Journal of Experimental and Theoretical Physics, Vol. 120, Issue 1
Elastic and anelastic relaxations associated with phase transitions in
journal, August 2014
- Spalek, Leszek J.; Saxena, Siddharth S.; Panagopoulos, Christos
- Physical Review B, Vol. 90, Issue 5
Lattice instabilities in bulk EuTiO
journal, October 2013
- Bessas, D.; Rushchanskii, K. Z.; Kachlik, M.
- Physical Review B, Vol. 88, Issue 14
An Antiferro-to-Ferromagnetic Transition in EuTiO 3– x H x Induced by Hydride Substitution
journal, January 2015
- Yamamoto, Takafumi; Yoshii, Ryuta; Bouilly, Guillaume
- Inorganic Chemistry, Vol. 54, Issue 4
Structural instability of EuTiO 3 from X-ray powder diffraction
journal, November 2012
- Köhler, J.; Dinnebier, R.; Bussmann-Holder, A.
- Phase Transitions, Vol. 85, Issue 11
Reentrant Valence Transition in EuO at High Pressures: Beyond the Bond-Valence Model
journal, July 2012
- Souza-Neto, N. M.; Zhao, J.; Alp, E. E.
- Physical Review Letters, Vol. 109, Issue 2
Nonlinear pressure dependence of T N in almost multiferroic EuTiO 3
journal, August 2013
- Guguchia, Z.; Caslin, K.; Kremer, R. K.
- Journal of Physics: Condensed Matter, Vol. 25, Issue 37
Pressure-temperature phase diagram of up to 53 GPa
journal, February 2010
- Guennou, Mael; Bouvier, Pierre; Kreisel, Jens
- Physical Review B, Vol. 81, Issue 5
Antiferrodistortive phase transition in EuTiO
journal, August 2012
- Goian, V.; Kamba, S.; Pacherová, O.
- Physical Review B, Vol. 86, Issue 5
Rare earth titanates with a perovskite structure
journal, January 1953
- Brous, J.; Fankuchen, I.; Banks, E.
- Acta Crystallographica, Vol. 6, Issue 1
Magnetoelastic relaxations in EuTiO 3
journal, March 2015
- Schiemer, J.; Spalek, L. J.; Saxena, S. S.
- EPL (Europhysics Letters), Vol. 109, Issue 5
Hydrostatic limits of 11 pressure transmitting media
journal, March 2009
- Klotz, S.; Chervin, J-C.; Munsch, P.
- Journal of Physics D: Applied Physics, Vol. 42, Issue 7, Article No. 075413
X-ray study of the structural distortion in EuTiO3
journal, June 2014
- Ellis, David S.; Uchiyama, Hiroshi; Tsutsui, Satoshi
- Physica B: Condensed Matter, Vol. 442
Structure and thermoelectric properties of EuTi(O,N) 3 ± δ
journal, July 2013
- Sagarna, L.; Rushchanskii, K. Z.; Maegli, A.
- Journal of Applied Physics, Vol. 114, Issue 3
Emergent Superstructural Dynamic Order due to Competing Antiferroelectric and Antiferrodistortive Instabilities in Bulk
journal, January 2013
- Kim, Jong-Woo; Thompson, Paul; Brown, Simon
- Physical Review Letters, Vol. 110, Issue 2
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration
journal, May 2015
- Prescher, Clemens; Prakapenka, Vitali B.
- High Pressure Research, Vol. 35, Issue 3
Studies of the antiferrodistortive transition in EuTiO 3
journal, November 2014
- Kennedy, Brendan J.; Murphy, Gabriel; Reynolds, Emily
- Journal of Physics: Condensed Matter, Vol. 26, Issue 49
Hyperfine Splitting and Room-Temperature Ferromagnetism of Ni at Multimegabar Pressure
journal, October 2013
- Sergueev, I.; Dubrovinsky, L.; Ekholm, M.
- Physical Review Letters, Vol. 111, Issue 15
Relation between structural instabilities in EuTiO and SrTiO
journal, June 2011
- Bussmann-Holder, A.; Köhler, J.; Kremer, R. K.
- Physical Review B, Vol. 83, Issue 21
Nuclear forward scattering by the 68.7 keV state of 73 Ge in CaGeO 3 and GeO 2
journal, October 2013
- Simon, R. E.; Sergueev, I.; Persson, J.
- EPL (Europhysics Letters), Vol. 104, Issue 1
Role of intrinsic disorder in the structural phase transition of magnetoelectric EuTiO
journal, May 2012
- Allieta, Mattia; Scavini, Marco; Spalek, Leszek J.
- Physical Review B, Vol. 85, Issue 18
Magnetic Properties of Some Divalent Europium Compounds
journal, April 1963
- McGuire, T. R.; Argyle, B. E.; Shafer, M. W.
- Journal of Applied Physics, Vol. 34, Issue 4
Influence of the Oxygen Content on the Electronic Transport Properties of Sr x Eu 1– x TiO 3-δ
journal, April 2014
- Sagarna, Leyre; Populoh, Sascha; Shkabko, Andrey
- The Journal of Physical Chemistry C, Vol. 118, Issue 15
Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996
- Hammersley, A. P.; Svensson, S. O.; Hanfland, M.
- High Pressure Research, Vol. 14, Issue 4-6, p. 235-248
Nonlinear behavior of thin film SrTiO3 capacitors at microwave frequencies
journal, September 1998
- Kozyrev, A. B.; Samoilova, T. B.; Golovkov, A. A.
- Journal of Applied Physics, Vol. 84, Issue 6
Phonon softening and dispersion in EuTiO
journal, December 2012
- Ellis, David S.; Uchiyama, Hiroshi; Tsutsui, Satoshi
- Physical Review B, Vol. 86, Issue 22
Nonlinear pressure dependence ofTNin almost multiferroic EuTiO3
text, January 2013
- Guguchia, Z.; Caslin, K.; Kremer, R. K.
- IOP Publishing
Reversible Control of Magnetic Interactions by Electric Field in a Single Phase Material
text, January 2012
- Ryan, P. J.; Kim, J. -W.; Birol, T.
- arXiv
Nonlinear pressure dependence of T_N in almost multiferroic EuTiO_3
text, January 2013
- Guguchia, Z.; Caslin, K.; Kremer, R.
- arXiv
Lattice instabilities in bulk EuTiO3
text, January 2013
- Bessas, D.; Rushchanskii, K. Z.; Kachlik, M.
- arXiv
Works referencing / citing this record:
Multicaloric effect in multiferroic EuTiO3 thin films
journal, February 2020
- Zhao, Yi-Quan; Cao, Hai-Xia
- Journal of Materials Science, Vol. 55, Issue 14