Hybrid Dion–Jacobson 2D Lead Iodide Perovskites
Abstract
The three-dimensional hybrid organic–inorganic perovskites have shown huge potential for use in solar cells and other optoelectronic devices. Although these materials are under intense investigation, derivative materials with lower dimensionality are emerging, offering higher tunability of physical properties and new capabilities. Here, we present two new series of hybrid two-dimensional (2D) perovskites that adopt the Dion–Jacobson (DJ) structure type, which are the first complete homologous series reported in halide perovskite chemistry. Lead iodide DJ perovskites adopt a general formula A'An–1PbnI3n+1 (A' = 3-(aminomethyl)piperidinium (3AMP) or 4-(aminomethyl)piperidinium (4AMP), A = methylammonium (MA)). These materials have layered structures where the stacking of inorganic layers is unique as they lay exactly on top of another. With a slightly different position of the functional group in the templating cation 3AMP and 4AMP, the as-formed DJ perovskites show different optical properties, with the 3AMP series having smaller band gaps than the 4AMP series. Analysis on the crystal structures and density functional theory (DFT) calculations suggest that the origin of the systematic band gap shift is the strong but indirect influence of the organic cation on the inorganic framework. Fabrication of photovoltaic devices utilizing these materials as light absorbers reveals that (3AMP)(MA)3Pb4I13 has the best powermore »
- Authors:
-
[1];
[1];
[2];
[1];
[2];
[2];
[3];
[1];
[3]
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Univ. Rennes, Rennes (France); National Centre for Scientific Research (CNRS), Rennes (France)
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry, and Argonne-Northwestern Solar Energy Research (ANSER) Center
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER); Univ. of California, Santa Barbara, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1470389
- Alternate Identifier(s):
- OSTI ID: 1599733
- Grant/Contract Number:
- SC0001059; SC0012541
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 140; Journal Issue: 10; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (homogeneous); catalysis (heterogeneous); solar (photovoltaic); solar (fuels); photosynthesis (natural and artificial); bio-inspired; hydrogen and fuel cells; electrodes - solar; defects; charge transport; spin dynamics; membrane; materials and chemistry by design; optics; synthesis (novel materials); 36 MATERIALS SCIENCE
Citation Formats
Mao, Lingling, Ke, Weijun, Pedesseau, Laurent, Wu, Yilei, Katan, Claudine, Even, Jacky, Wasielewski, Michael R., Stoumpos, Constantinos C., and Kanatzidis, Mercouri G. Hybrid Dion–Jacobson 2D Lead Iodide Perovskites. United States: N. p., 2018.
Web. doi:10.1021/jacs.8b00542.
Mao, Lingling, Ke, Weijun, Pedesseau, Laurent, Wu, Yilei, Katan, Claudine, Even, Jacky, Wasielewski, Michael R., Stoumpos, Constantinos C., & Kanatzidis, Mercouri G. Hybrid Dion–Jacobson 2D Lead Iodide Perovskites. United States. https://doi.org/10.1021/jacs.8b00542
Mao, Lingling, Ke, Weijun, Pedesseau, Laurent, Wu, Yilei, Katan, Claudine, Even, Jacky, Wasielewski, Michael R., Stoumpos, Constantinos C., and Kanatzidis, Mercouri G. Wed .
"Hybrid Dion–Jacobson 2D Lead Iodide Perovskites". United States. https://doi.org/10.1021/jacs.8b00542. https://www.osti.gov/servlets/purl/1470389.
@article{osti_1470389,
title = {Hybrid Dion–Jacobson 2D Lead Iodide Perovskites},
author = {Mao, Lingling and Ke, Weijun and Pedesseau, Laurent and Wu, Yilei and Katan, Claudine and Even, Jacky and Wasielewski, Michael R. and Stoumpos, Constantinos C. and Kanatzidis, Mercouri G.},
abstractNote = {The three-dimensional hybrid organic–inorganic perovskites have shown huge potential for use in solar cells and other optoelectronic devices. Although these materials are under intense investigation, derivative materials with lower dimensionality are emerging, offering higher tunability of physical properties and new capabilities. Here, we present two new series of hybrid two-dimensional (2D) perovskites that adopt the Dion–Jacobson (DJ) structure type, which are the first complete homologous series reported in halide perovskite chemistry. Lead iodide DJ perovskites adopt a general formula A'An–1PbnI3n+1 (A' = 3-(aminomethyl)piperidinium (3AMP) or 4-(aminomethyl)piperidinium (4AMP), A = methylammonium (MA)). These materials have layered structures where the stacking of inorganic layers is unique as they lay exactly on top of another. With a slightly different position of the functional group in the templating cation 3AMP and 4AMP, the as-formed DJ perovskites show different optical properties, with the 3AMP series having smaller band gaps than the 4AMP series. Analysis on the crystal structures and density functional theory (DFT) calculations suggest that the origin of the systematic band gap shift is the strong but indirect influence of the organic cation on the inorganic framework. Fabrication of photovoltaic devices utilizing these materials as light absorbers reveals that (3AMP)(MA)3Pb4I13 has the best power conversion efficiency (PCE) of 7.32%, which is much higher than that of the corresponding (4AMP)(MA)3Pb4I13.},
doi = {10.1021/jacs.8b00542},
journal = {Journal of the American Chemical Society},
number = 10,
volume = 140,
place = {United States},
year = {Wed Feb 21 00:00:00 EST 2018},
month = {Wed Feb 21 00:00:00 EST 2018}
}
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Structural and thermodynamic limits of layer thickness in 2D halide perovskites
journal, December 2018
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The templating effect of 1,2-cyclohexanediamine configuration on iodoplumbate organic–inorganic hybrid structures
journal, February 2020
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- Journal of Coordination Chemistry, Vol. 73, Issue 3
Skillfully deflecting the question: a small amount of piperazine-1,4-diium iodide radically enhances the thermal stability of CsPbI 3 perovskite
journal, January 2019
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- Journal of Materials Chemistry C, Vol. 7, Issue 38
Metal halide perovskite nanostructures for optoelectronic applications and the study of physical properties
journal, February 2019
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Unraveling the mechanochemical synthesis and luminescence in MnII-based two-dimensional hybrid perovskite (C4H9NH3)2PbCl4
journal, March 2019
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Merits and Challenges of Ruddlesden-Popper Soft Halide Perovskites in Electro-Optics and Optoelectronics
journal, October 2018
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A Review on Additives for Halide Perovskite Solar Cells
journal, April 2020
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Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission
journal, December 2018
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Organic intercalation engineering of quasi-2D Dion–Jacobson α-CsPbI 3 perovskites
journal, January 2020
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A photo-crosslinkable bis-triarylamine side-chain polymer as a hole-transport material for stable perovskite solar cells
journal, January 2020
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Nonconfinement Structure Revealed in Dion–Jacobson Type Quasi‐2D Perovskite Expedites Interlayer Charge Transport
journal, October 2019
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A two-dimensional bilayered Dion–Jacobson-type perovskite hybrid with a narrow bandgap for broadband photodetection
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Highly stable hybrid perovskite light-emitting diodes based on Dion-Jacobson structure
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The Spacer Cations Interplay for Efficient and Stable Layered 2D Perovskite Solar Cells
journal, October 2019
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Vertical Orientated Dion–Jacobson Quasi‐2D Perovskite Film with Improved Photovoltaic Performance and Stability
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From Pb to Bi: A Promising Family of Pb‐Free Optoelectronic Materials and Devices
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Tolerance factors of hybrid organic–inorganic perovskites: recent improvements and current state of research
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The templating effect of 1,2-cyclohexanediamine configuration on iodoplumbate organic–inorganic hybrid structures
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Hybrid Halide Perovskites: Discussions on Terminology and Materials
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The templating effect of 1,2-cyclohexanediamine configuration on iodoplumbate organic–inorganic hybrid structures
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Computational Design of Two-Dimensional Perovskites with Functional Organic Cations
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Incorporating Large A Cations into Lead Iodide Perovskite Cages: Relaxed Goldschmidt Tolerance Factor and Impact on Exciton–Phonon Interaction
journal, July 2019
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Highly stable hybrid perovskite light-emitting diodes based on Dion-Jacobson structure
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Recent progress in perovskite solar cells: the perovskite layer
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