Performance Enhancement of Lead-Free Tin-Based Perovskite Solar Cells with Reducing Atmosphere-Assisted Dispersible Additive

Song, Tze-Bin; Yokoyama, Takamichi; Aramaki, Shinji; Kanatzidis, Mercouri G.

doi:10.1021/acsenergylett.7b00171

Title: Performance Enhancement of Lead-Free Tin-Based Perovskite Solar Cells with Reducing Atmosphere-Assisted Dispersible Additive

Journal Article · 10 March 2017 · ACS Energy Letters

DOI: https://doi.org/10.1021/acsenergylett.7b00171 · OSTI ID:1470357

Song, Tze-Bin ^[1];

^[2]; Aramaki, Shinji ^[3];

^[1]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; Mitsubishi Chemical Group Science and Technology Research Center, Inc., (Japan)
Mitsubishi Chemical Group Science and Technology Research Center, Inc., (Japan)

Sn-based halide perovskite materials have attracted tremendous attention and have been employed successfully in solar cells. However, their high conductivities resulting from the unstable divalent Sn state in the structure cause poor device performance and poor reproducibility. Herein, we used excess tin iodide (SnI₂) in Sn-based halide perovskite solar cells (ASnI₃, A = Cs, methylammonium and formamidinium tin iodide as the representative light absorbers), combined with a reducing atmosphere to stabilize the Sn²⁺ state. Excess SnI₂ can disperse uniformly into the perovskite films and functions as a compensator as well as a suppressor of Sn²⁺ vacancies thereby effectively reducing the p-type conductivity. This process significantly improved the solar-cell performances of all the ASnI3 materials on mesoporous TiO₂. Optimized CsSnI3 devices achieved a maximum power conversion efficiency of 4.81%, which is the highest among all inorganic Pb-free perovskite solar cells to date.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001059

OSTI ID:: 1470357

Journal Information:: ACS Energy Letters, Vol. 2, Issue 4; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (42)

Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors Zhu, Haiming; Fu, Yongping; Meng, Fei Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4271	journal	April 2015
Solution-processed hybrid perovskite photodetectors with high detectivity Dou, Letian; Yang, Yang (Micheal); You, Jingbi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6404	journal	November 2014
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Accounts of Chemical Research, Vol. 48, Issue 10 https://doi.org/10.1021/acs.accounts.5b00229	journal	September 2015
Halide Perovskites: Poor Man's High-Performance Semiconductors Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Advanced Materials, Vol. 28, Issue 28 https://doi.org/10.1002/adma.201600265	journal	May 2016
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange Yang, W. S.; Noh, J. H.; Jeon, N. J. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa9272	journal	May 2015
A molecularly engineered hole-transporting material for efficient perovskite solar cells Saliba, Michael; Orlandi, Simonetta; Matsui, Taisuke Nature Energy, Vol. 1, Issue 2 https://doi.org/10.1038/nenergy.2015.17	journal	January 2016
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance De Wolf, Stefaan; Holovsky, Jakub; Moon, Soo-Jin The Journal of Physical Chemistry Letters, Vol. 5, Issue 6 https://doi.org/10.1021/jz500279b	journal	March 2014
Rain on Methylammonium Lead Iodide Based Perovskites: Possible Environmental Effects of Perovskite Solar Cells Hailegnaw, Bekele; Kirmayer, Saar; Edri, Eran The Journal of Physical Chemistry Letters, Vol. 6, Issue 9 https://doi.org/10.1021/acs.jpclett.5b00504	journal	April 2015
Overcoming Short-Circuit in Lead-Free CH ₃ NH ₃ SnI ₃ Perovskite Solar Cells via Kinetically Controlled Gas–Solid Reaction Film Fabrication Process Yokoyama, Takamichi; Cao, Duyen H.; Stoumpos, Constantinos C. The Journal of Physical Chemistry Letters, Vol. 7, Issue 5 https://doi.org/10.1021/acs.jpclett.6b00118	journal	February 2016
Hybrid Germanium Iodide Perovskite Semiconductors: Active Lone Pairs, Structural Distortions, Direct and Indirect Energy Gaps, and Strong Nonlinear Optical Properties Stoumpos, Constantinos C.; Frazer, Laszlo; Clark, Daniel J. Journal of the American Chemical Society, Vol. 137, Issue 21 https://doi.org/10.1021/jacs.5b01025	journal	May 2015
Lead-free germanium iodide perovskite materials for photovoltaic applications Krishnamoorthy, Thirumal; Ding, Hong; Yan, Chen Journal of Materials Chemistry A, Vol. 3, Issue 47 https://doi.org/10.1039/C5TA05741H	journal	January 2015
Can Pb-Free Halide Double Perovskites Support High-Efficiency Solar Cells? Savory, Christopher N.; Walsh, Aron; Scanlon, David O. ACS Energy Letters, Vol. 1, Issue 5 https://doi.org/10.1021/acsenergylett.6b00471	journal	October 2016
Cs ₂ InAgCl ₆ : A New Lead-Free Halide Double Perovskite with Direct Band Gap Volonakis, George; Haghighirad, Amir Abbas; Milot, Rebecca L. The Journal of Physical Chemistry Letters, Vol. 8, Issue 4 https://doi.org/10.1021/acs.jpclett.6b02682	journal	January 2017
Thin-Film Preparation and Characterization of Cs ₃ Sb ₂ I ₉ : A Lead-Free Layered Perovskite Semiconductor Saparov, Bayrammurad; Hong, Feng; Sun, Jon-Paul Chemistry of Materials, Vol. 27, Issue 16 https://doi.org/10.1021/acs.chemmater.5b01989	journal	August 2015
Toward Lead-Free Perovskite Solar Cells Giustino, Feliciano; Snaith, Henry J. ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00499	journal	November 2016
Lead-free solid-state organic–inorganic halide perovskite solar cells Hao, Feng; Stoumpos, Constantinos C.; Cao, Duyen Hanh Nature Photonics, Vol. 8, Issue 6 https://doi.org/10.1038/nphoton.2014.82	journal	May 2014
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038 https://doi.org/10.1021/ic401215x	journal	July 2013
Lead-free organic–inorganic tin halide perovskites for photovoltaic applications Noel, Nakita K.; Stranks, Samuel D.; Abate, Antonio Energy Environ. Sci., Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01076K	journal	January 2014
Lead-Free Inverted Planar Formamidinium Tin Triiodide Perovskite Solar Cells Achieving Power Conversion Efficiencies up to 6.22% Liao, Weiqiang; Zhao, Dewei; Yu, Yue Advanced Materials, Vol. 28, Issue 42 https://doi.org/10.1002/adma.201602992	journal	August 2016
CsSnI₃ : Semiconductor or Metal? High Electrical Conductivity and Strong Near-Infrared Photoluminescence from a Single Material. High Hole Mobility and Phase-Transitions Chung, In; Song, Jung-Hwan; Im, Jino Journal of the American Chemical Society, Vol. 134, Issue 20, p. 8579-8587 https://doi.org/10.1021/ja301539s	journal	May 2012
Hall mobility in tin iodide perovskite CH3NH3SnI3: Evidence for a doped semiconductor Takahashi, Yukari; Hasegawa, Hiroyuki; Takahashi, Yukihiro Journal of Solid State Chemistry, Vol. 205 https://doi.org/10.1016/j.jssc.2013.07.008	journal	September 2013
Lead free CH ₃ NH ₃ SnI ₃ perovskite thin-film with p-type semiconducting nature and metal-like conductivity Iefanova, Anastasiia; Adhikari, Nirmal; Dubey, Ashish AIP Advances, Vol. 6, Issue 8 https://doi.org/10.1063/1.4961463	journal	August 2016
CH ₃ NH ₃ Sn _x Pb _{(1– x )} I ₃ Perovskite Solar Cells Covering up to 1060 nm Ogomi, Yuhei; Morita, Atsushi; Tsukamoto, Syota The Journal of Physical Chemistry Letters, Vol. 5, Issue 6 https://doi.org/10.1021/jz5002117	journal	March 2014
Binary-Metal Perovskites Toward High-Performance Planar-Heterojunction Hybrid Solar Cells Zuo, Fan; Williams, Spencer T.; Liang, Po-Wei Advanced Materials, Vol. 26, Issue 37 https://doi.org/10.1002/adma.201401641	journal	August 2014
Organic Cation-Dependent Degradation Mechanism of Organotin Halide Perovskites Wang, Feng; Ma, Jiale; Xie, Fangyan Advanced Functional Materials, Vol. 26, Issue 20 https://doi.org/10.1002/adfm.201505127	journal	March 2016
Fabrication of Efficient Formamidinium Tin Iodide Perovskite Solar Cells through SnF ₂ –Pyrazine Complex Lee, Seon Joo; Shin, Seong Sik; Kim, Young Chan Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.6b00142	journal	March 2016
Lead-Free Halide Perovskite Solar Cells with High Photocurrents Realized Through Vacancy Modulation Kumar, Mulmudi Hemant; Dharani, Sabba; Leong, Wei Lin Advanced Materials, Vol. 26, Issue 41 https://doi.org/10.1002/adma.201401991	journal	September 2014
Impact of Anionic Br ^– Substitution on Open Circuit Voltage in Lead Free Perovskite (CsSnI _3-x Br _x ) Solar Cells Sabba, Dharani; Mulmudi, Hemant Kumar; Prabhakar, Rajiv Ramanujam The Journal of Physical Chemistry C, Vol. 119, Issue 4 https://doi.org/10.1021/jp5126624	journal	January 2015
Formamidinium tin-based perovskite with low E _g for photovoltaic applications Koh, Teck Ming; Krishnamoorthy, Thirumal; Yantara, Natalia Journal of Materials Chemistry A, Vol. 3, Issue 29 https://doi.org/10.1039/C5TA00190K	journal	January 2015
All-solid-state dye-sensitized solar cells with high efficiency Chung, In; Lee, Byunghong; He, Jiaqing Nature, Vol. 485, Issue 7399, p. 486-489 https://doi.org/10.1038/nature11067	journal	May 2012
Influence of Defects and Synthesis Conditions on the Photovoltaic Performance of Perovskite Semiconductor CsSnI ₃ Xu, Peng; Chen, Shiyou; Xiang, Hong-Jun Chemistry of Materials, Vol. 26, Issue 20 https://doi.org/10.1021/cm503122j	journal	October 2014
The Origin of Lower Hole Carrier Concentration in Methylammonium Tin Halide Films Grown by a Vapor-Assisted Solution Process Yokoyama, Takamichi; Song, Tze-Bin; Cao, Duyen H. ACS Energy Letters, Vol. 2, Issue 1 https://doi.org/10.1021/acsenergylett.6b00513	journal	December 2016
Importance of Reducing Vapor Atmosphere in the Fabrication of Tin-Based Perovskite Solar Cells Song, Tze-Bin; Yokoyama, Takamichi; Stoumpos, Constantinos C. Journal of the American Chemical Society, Vol. 139, Issue 2 https://doi.org/10.1021/jacs.6b10734	journal	January 2017
Heterojunction-Depleted Lead-Free Perovskite Solar Cells with Coarse-Grained B-γ-CsSnI ₃ Thin Films Wang, Ning; Zhou, Yuanyuan; Ju, Ming-Gang Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201601130	journal	September 2016
Inorganic caesium lead iodide perovskite solar cells Eperon, Giles E.; Paternò, Giuseppe M.; Sutton, Rebecca J. Journal of Materials Chemistry A, Vol. 3, Issue 39 https://doi.org/10.1039/C5TA06398A	journal	January 2015
Solvent Engineering for Ambient-Air-Processed, Phase-Stable CsPbI ₃ in Perovskite Solar Cells Luo, Paifeng; Xia, Wei; Zhou, Shengwen The Journal of Physical Chemistry Letters, Vol. 7, Issue 18 https://doi.org/10.1021/acs.jpclett.6b01576	journal	August 2016
Tin perovskite/fullerene planar layer photovoltaics: improving the efficiency and stability of lead-free devices Marshall, Kenneth P.; Walton, Richard I.; Hatton, Ross A. Journal of Materials Chemistry A, Vol. 3, Issue 21 https://doi.org/10.1039/C5TA02950C	journal	January 2015
TiO ₂ –ZnS Cascade Electron Transport Layer for Efficient Formamidinium Tin Iodide Perovskite Solar Cells Ke, Weijun; Stoumpos, Constantinos C.; Logsdon, Jenna Leigh Journal of the American Chemical Society, Vol. 138, Issue 45 https://doi.org/10.1021/jacs.6b08790	journal	November 2016
Systematic Improvement in Charge Carrier Mobility of Air Stable Triarylamine Copolymers Zhang, Weimin; Smith, Jeremy; Hamilton, Rick Journal of the American Chemical Society, Vol. 131, Issue 31 https://doi.org/10.1021/ja9034818	journal	August 2009
Band offsets of n-type electron-selective contacts on cuprous oxide (Cu2O) for photovoltaics Brandt, Riley E.; Young, Matthew; Park, Helen Hejin Applied Physics Letters, Vol. 105, Issue 26 https://doi.org/10.1063/1.4905180	journal	December 2014
Externally quenched air counter for low‐energy electron emission measurements Kirihata, H.; Uda, M. Review of Scientific Instruments, Vol. 52, Issue 1 https://doi.org/10.1063/1.1136448	journal	January 1981

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Efficient CsSnI ₃ -based inorganic perovskite solar cells based on a mesoscopic metal oxide framework via incorporating a donor element Zhang, Tao; Li, Hao; Ban, Huaxia Journal of Materials Chemistry A, Vol. 8, Issue 7 https://doi.org/10.1039/c9ta11794f	journal	January 2020
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Title: Performance Enhancement of Lead-Free Tin-Based Perovskite Solar Cells with Reducing Atmosphere-Assisted Dispersible Additive

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