Retrosynthesis of multi–component metal-organic frameworks
Abstract
Crystal engineering of metal–organic frameworks (MOFs) has allowed the construction of complex structures at atomic precision, but has yet to reach the same level of sophistication as organic synthesis. The synthesis of complex MOFs with multiple organic and/or inorganic components is ultimately limited by the lack of control over framework assembly in one-pot reactions. Herein, we demonstrate that multi-component MOFs with unprecedented complexity can be constructed in a predictable and stepwise manner under simple kinetic guidance, which conceptually mimics the retrosynthetic approach utilized to construct complicated organic molecules. Four multi-component MOFs were synthesized by the subsequent incorporation of organic linkers and inorganic clusters into the cavity of a mesoporous MOF, each composed of up to three different metals and two different linkers. Furthermore, we demonstrated the utility of such a retrosynthetic design through the construction of a cooperative bimetallic catalytic system with two collaborative metal sites for three-component Strecker reactions.
- Authors:
-
[1];
[2];
[3];
[4]
- Texas A & M Univ., College Station, TX (United States)
- Shandong Univ., Jinan (China)
- King Saud Univ., Riyadh (Saudi Arabia)
- Texas A & M Univ., College Station, TX (United States); King Saud Univ., Riyadh (Saudi Arabia)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC), Washington, D.C. (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1470209
- Grant/Contract Number:
- SC0001015
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; membrane; carbon capture; materials and chemistry by design; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing)
Citation Formats
Yuan, Shuai, Qin, Jun-Sheng, Li, Jialuo, Huang, Lan, Feng, Liang, Fang, Yu, Lollar, Christina, Pang, Jiandong, Zhang, Liangliang, Sun, Di, Alsalme, Ali, Cagin, Tahir, and Zhou, Hong-Cai. Retrosynthesis of multi–component metal-organic frameworks. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-03102-5.
Yuan, Shuai, Qin, Jun-Sheng, Li, Jialuo, Huang, Lan, Feng, Liang, Fang, Yu, Lollar, Christina, Pang, Jiandong, Zhang, Liangliang, Sun, Di, Alsalme, Ali, Cagin, Tahir, & Zhou, Hong-Cai. Retrosynthesis of multi–component metal-organic frameworks. United States. https://doi.org/10.1038/s41467-018-03102-5
Yuan, Shuai, Qin, Jun-Sheng, Li, Jialuo, Huang, Lan, Feng, Liang, Fang, Yu, Lollar, Christina, Pang, Jiandong, Zhang, Liangliang, Sun, Di, Alsalme, Ali, Cagin, Tahir, and Zhou, Hong-Cai. Fri .
"Retrosynthesis of multi–component metal-organic frameworks". United States. https://doi.org/10.1038/s41467-018-03102-5. https://www.osti.gov/servlets/purl/1470209.
@article{osti_1470209,
title = {Retrosynthesis of multi–component metal-organic frameworks},
author = {Yuan, Shuai and Qin, Jun-Sheng and Li, Jialuo and Huang, Lan and Feng, Liang and Fang, Yu and Lollar, Christina and Pang, Jiandong and Zhang, Liangliang and Sun, Di and Alsalme, Ali and Cagin, Tahir and Zhou, Hong-Cai},
abstractNote = {Crystal engineering of metal–organic frameworks (MOFs) has allowed the construction of complex structures at atomic precision, but has yet to reach the same level of sophistication as organic synthesis. The synthesis of complex MOFs with multiple organic and/or inorganic components is ultimately limited by the lack of control over framework assembly in one-pot reactions. Herein, we demonstrate that multi-component MOFs with unprecedented complexity can be constructed in a predictable and stepwise manner under simple kinetic guidance, which conceptually mimics the retrosynthetic approach utilized to construct complicated organic molecules. Four multi-component MOFs were synthesized by the subsequent incorporation of organic linkers and inorganic clusters into the cavity of a mesoporous MOF, each composed of up to three different metals and two different linkers. Furthermore, we demonstrated the utility of such a retrosynthetic design through the construction of a cooperative bimetallic catalytic system with two collaborative metal sites for three-component Strecker reactions.},
doi = {10.1038/s41467-018-03102-5},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {Fri Feb 23 00:00:00 EST 2018},
month = {Fri Feb 23 00:00:00 EST 2018}
}
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A Zn( ii ) metal–organic framework constructed by a mixed-ligand strategy for CO 2 capture and gas separation
journal, January 2019
- Zou, Lifei; Yuan, Jiaqi; Yuan, Yang
- CrystEngComm, Vol. 21, Issue 21
The chemistry of multi-component and hierarchical framework compounds
journal, January 2019
- Feng, Liang; Wang, Kun-Yu; Day, Gregory S.
- Chemical Society Reviews, Vol. 48, Issue 18
Syntheses of mono and bimetallic cyamelurate polymers with reversible chromic behaviour
journal, January 2019
- Mohan, Midhun; Rajak, Sanil; Tremblay, Alexandre A.
- Dalton Transactions, Vol. 48, Issue 20
New linker installation in metal–organic frameworks
journal, January 2019
- Pang, Qingqing; Tu, Binbin; Li, Qiaowei
- Dalton Transactions, Vol. 48, Issue 32
Three stable dinuclear [M 2 (OH) 0.5 (NO 3 ) 0.5 (RCOO) 2 (RN) 4 ] (M = Cu, Ni) based metal–organic frameworks with high CO 2 adsorption and selective separation for O 2 /N 2 and C 3 H 8 /CH 4
journal, January 2020
- Kan, Liang; Li, Lan; Li, Guanghua
- Inorganic Chemistry Frontiers, Vol. 7, Issue 3
A multifunctional Zr( iv )-based metal–organic framework for highly efficient elimination of Cr( vi ) from the aqueous phase
journal, January 2019
- Liu, Junmin; Ye, Yu; Sun, Xiaodong
- Journal of Materials Chemistry A, Vol. 7, Issue 28
Secondary building units as the turning point in the development of the reticular chemistry of MOFs
journal, October 2018
- Kalmutzki, Markus J.; Hanikel, Nikita; Yaghi, Omar M.
- Science Advances, Vol. 4, Issue 10
Migration-Prevention Strategy to Fabricate Single-Atom Fe Implanted N-Doped Porous Carbons for Efficient Oxygen Reduction
journal, August 2019
- Meng, Dong-Li; Chen, Chun-Hui; Yi, Jun-Dong
- Research, Vol. 2019
Desulfurization Efficiency Preserved in a Heterometallic MOF: Synthesis and Thermodynamically Controlled Phase Transition
journal, February 2019
- Han, Yi; Sinnwell, Michael A.; Teat, Simon J.
- Advanced Science, Vol. 6, Issue 7
Hierarchy in Metal–Organic Frameworks
journal, March 2020
- Feng, Liang; Wang, Kun-Yu; Willman, Jeremy
- ACS Central Science, Vol. 6, Issue 3
Uncovering Two Principles of Multivariate Hierarchical Metal–Organic Framework Synthesis via Retrosynthetic Design
journal, December 2018
- Feng, Liang; Yuan, Shuai; Li, Jia-Luo
- ACS Central Science, Vol. 4, Issue 12
Multimetal organic frameworks as drug carriers: aceclofenac as a drug candidate
journal, December 2018
- Al Haydar, Muder; Abid, Hussein Rasool; Sunderland, Bruce
- Drug Design, Development and Therapy, Vol. Volume 13