para -Xylene Ultra-selective Zeolite MFI Membranes Fabricated from Nanosheet Monolayers at the Air-Water Interface

Kim, Donghun; Jeon, Mi Young; Stottrup, Benjamin L.; Tsapatsis, Michael

doi:10.1002/anie.201708835

Title: para -Xylene Ultra-selective Zeolite MFI Membranes Fabricated from Nanosheet Monolayers at the Air-Water Interface

Journal Article · 29 November 2017 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201708835 · OSTI ID:1470070

^[1]; Jeon, Mi Young ^[1]; Stottrup, Benjamin L. ^[2];

^[1]

Univ. of Minnesota, Minneapolis, MN (United States). Dept. of Chemical Engineering and Materials Science
Augsburg Univ., Minneapolis, MN (United States). Dept. of Physics

The control of membrane morphology and microstructure is crucial to improve the separation performance of molecular-sieve membranes. This can be enabled by making thin, dense, and uniform seed-crystal coatings, which are then intergrown into continuous membranes. Herein, we show a novel and simple floating particle coating method can give closely packed monolayers of zeolite nanosheets on nonporous or porous supports. The zeolite nanosheet monolayer is formed at the air–water interface in a conical Teflon trough. As the water in the trough is drained, the monolayer is deposited on a support placed below. Membranes prepared by gel-free secondary growth of the nanosheets deposited by this method show unprecedented ultra-selective performance for separation of para- from ortho-xylene (separation factor >10,000).

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0001015

OSTI ID:: 1470070

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 2 Vol. 57; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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