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This content will become publicly available on August 24, 2019

Title: Weakly interacting solvation spheres surrounding a calixarene-protected tetrairidium carbonyl cluster: contrasting effects on reactivity of alkane solvent and silica support

A substituted tetrairidium carbonyl cluster on a silica support undergoes hydrogen activation at a rate and with a mechanism different from the cluster in solution.
Authors:
ORCiD logo [1] ;  [2] ; ORCiD logo [3] ; ORCiD logo [2] ; ORCiD logo [4] ; ORCiD logo [5]
  1. Department of Chemical Engineering, University of California, Davis, USA, Department of Chemical and Biomolecular Engineering
  2. Department of Chemistry, The University of Alabama, Tuscaloosa, USA
  3. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, USA
  4. Department of Chemical Engineering, University of California, Davis, USA
  5. Department of Chemical and Biomolecular Engineering, University of California, Berkeley, USA
Publication Date:
Grant/Contract Number:
FG02-04ER15513; FGO2-05ER15696; KC0301050-47319
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 38; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1469718

Palermo, Andrew P., Zhang, Shengjie, Hwang, Son-Jong, Dixon, David A., Gates, Bruce C., and Katz, Alexander. Weakly interacting solvation spheres surrounding a calixarene-protected tetrairidium carbonyl cluster: contrasting effects on reactivity of alkane solvent and silica support. United Kingdom: N. p., Web. doi:10.1039/C8DT01371C.
Palermo, Andrew P., Zhang, Shengjie, Hwang, Son-Jong, Dixon, David A., Gates, Bruce C., & Katz, Alexander. Weakly interacting solvation spheres surrounding a calixarene-protected tetrairidium carbonyl cluster: contrasting effects on reactivity of alkane solvent and silica support. United Kingdom. doi:10.1039/C8DT01371C.
Palermo, Andrew P., Zhang, Shengjie, Hwang, Son-Jong, Dixon, David A., Gates, Bruce C., and Katz, Alexander. 2018. "Weakly interacting solvation spheres surrounding a calixarene-protected tetrairidium carbonyl cluster: contrasting effects on reactivity of alkane solvent and silica support". United Kingdom. doi:10.1039/C8DT01371C.
@article{osti_1469718,
title = {Weakly interacting solvation spheres surrounding a calixarene-protected tetrairidium carbonyl cluster: contrasting effects on reactivity of alkane solvent and silica support},
author = {Palermo, Andrew P. and Zhang, Shengjie and Hwang, Son-Jong and Dixon, David A. and Gates, Bruce C. and Katz, Alexander},
abstractNote = {A substituted tetrairidium carbonyl cluster on a silica support undergoes hydrogen activation at a rate and with a mechanism different from the cluster in solution.},
doi = {10.1039/C8DT01371C},
journal = {Dalton Transactions},
number = 38,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012

Stabilization of coordinatively unsaturated Ir4 clusters with bulky ligands a comparative study of chemical and mechanical effects
journal, January 2012
  • Okrut, Alexander; Gazit, Oz; Silva, Namal de
  • Dalton Transactions, Vol. 41, Issue 7, p. 2091-2099
  • DOI: 10.1039/C1DT11734C