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Title: Formation of self-assembled gold nanoparticle supercrystals with facet-dependent surface plasmonic coupling

Abstract

Metallic nanoparticles, such as gold and silver nanoparticles, can self-assemble into highly ordered arrays known as supercrystals for potential applications in areas such as optics, electronics, and sensor platforms. Here we report the formation of self-assembled 3D faceted gold nanoparticle supercrystals with controlled nanoparticle packing and unique facet-dependent optical property by using a binary solvent diffusion method. The nanoparticle packing structures from specific facets of the supercrystals are characterized by small/wide-angle X-ray scattering for detailed reconstruction of nanoparticle translation and shape orientation from mesometric to atomic levels within the supercrystals. We discover that the binary diffusion results in hexagonal close packed supercrystals whose size and quality are determined by initial nanoparticle concentration and diffusion speed. The supercrystal solids display unique facet-dependent surface plasmonic and surface-enhanced Raman characteristics. The ease of the growth of large supercrystal solids facilitates essential correlation between structure and property of nanoparticle solids for practical integrations.

Authors:
 [1]; ORCiD logo [1];  [1];  [1];  [1];  [2];  [3];  [4]
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
  3. Cornell Univ., Ithaca, NY (United States). Cornell High Energy Synchrotron Source (CHESS)
  4. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Univ. of New Mexico, Albuquerque, NM (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1469637
Alternate Identifier(s):
OSTI ID: 1475148
Report Number(s):
SAND-2018-9733J; BNL-209113-2018-JAAM
Journal ID: ISSN 2041-1723; PII: 4801
Grant/Contract Number:  
AC04-94AL85000; SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Bian, Kaifu, Schunk, Hattie, Ye, Dongmei, Hwang, Austin, Luk, Ting Shan, Li, Ruipeng, Wang, Zhongwu, and Fan, Hongyou. Formation of self-assembled gold nanoparticle supercrystals with facet-dependent surface plasmonic coupling. United States: N. p., 2018. Web. doi:10.1038/s41467-018-04801-9.
Bian, Kaifu, Schunk, Hattie, Ye, Dongmei, Hwang, Austin, Luk, Ting Shan, Li, Ruipeng, Wang, Zhongwu, & Fan, Hongyou. Formation of self-assembled gold nanoparticle supercrystals with facet-dependent surface plasmonic coupling. United States. doi:10.1038/s41467-018-04801-9.
Bian, Kaifu, Schunk, Hattie, Ye, Dongmei, Hwang, Austin, Luk, Ting Shan, Li, Ruipeng, Wang, Zhongwu, and Fan, Hongyou. Mon . "Formation of self-assembled gold nanoparticle supercrystals with facet-dependent surface plasmonic coupling". United States. doi:10.1038/s41467-018-04801-9. https://www.osti.gov/servlets/purl/1469637.
@article{osti_1469637,
title = {Formation of self-assembled gold nanoparticle supercrystals with facet-dependent surface plasmonic coupling},
author = {Bian, Kaifu and Schunk, Hattie and Ye, Dongmei and Hwang, Austin and Luk, Ting Shan and Li, Ruipeng and Wang, Zhongwu and Fan, Hongyou},
abstractNote = {Metallic nanoparticles, such as gold and silver nanoparticles, can self-assemble into highly ordered arrays known as supercrystals for potential applications in areas such as optics, electronics, and sensor platforms. Here we report the formation of self-assembled 3D faceted gold nanoparticle supercrystals with controlled nanoparticle packing and unique facet-dependent optical property by using a binary solvent diffusion method. The nanoparticle packing structures from specific facets of the supercrystals are characterized by small/wide-angle X-ray scattering for detailed reconstruction of nanoparticle translation and shape orientation from mesometric to atomic levels within the supercrystals. We discover that the binary diffusion results in hexagonal close packed supercrystals whose size and quality are determined by initial nanoparticle concentration and diffusion speed. The supercrystal solids display unique facet-dependent surface plasmonic and surface-enhanced Raman characteristics. The ease of the growth of large supercrystal solids facilitates essential correlation between structure and property of nanoparticle solids for practical integrations.},
doi = {10.1038/s41467-018-04801-9},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {2018},
month = {6}
}

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Cited by: 8 works
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Works referenced in this record:

Diffusion coefficients in dilute binary liquid mixtures
journal, January 1975

  • Tyn, Myo T.; Calus, Waclaw F.
  • Journal of Chemical & Engineering Data, Vol. 20, Issue 1
  • DOI: 10.1021/je60064a006

Kinetics of the self-assembly of nanocrystal superlattices measured by real-time in situ X-ray scattering
journal, March 2016

  • Weidman, Mark C.; Smilgies, Detlef-M.; Tisdale, William A.
  • Nature Materials, Vol. 15, Issue 7
  • DOI: 10.1038/nmat4600

Nanostructured Gold Architectures Formed through High Pressure-Driven Sintering of Spherical Nanoparticle Arrays
journal, September 2010

  • Wu, Huimeng; Bai, Feng; Sun, Zaicheng
  • Journal of the American Chemical Society, Vol. 132, Issue 37
  • DOI: 10.1021/ja105255d

Entropy difference between crystal phases
journal, July 1997

  • Bolhuis, P. G.; Frenkel, D.; Mau, Siun-Choun
  • Nature, Vol. 388, Issue 6639
  • DOI: 10.1038/40779

Characterization parameters for petroleum fractions
journal, April 1987

  • Riazi, Mohammad R.; Daubert, Thomas E.
  • Industrial & Engineering Chemistry Research, Vol. 26, Issue 4
  • DOI: 10.1021/ie00064a023

Miniband formation in a quantum dot crystal
journal, May 2001

  • Lazarenkova, Olga L.; Balandin, Alexander A.
  • Journal of Applied Physics, Vol. 89, Issue 10
  • DOI: 10.1063/1.1366662

Decoding the Superlattice and Interface Structure of Truncate PbS Nanocrystal-Assembled Supercrystal and Associated Interaction Forces
journal, August 2014

  • Li, Ruipeng; Bian, Kaifu; Hanrath, Tobias
  • Journal of the American Chemical Society, Vol. 136, Issue 34
  • DOI: 10.1021/ja5057032

Controlling Nanocrystal Superlattice Symmetry and Shape-Anisotropic Interactions through Variable Ligand Surface Coverage
journal, March 2011

  • Choi, Joshua J.; Bealing, Clive R.; Bian, Kaifu
  • Journal of the American Chemical Society, Vol. 133, Issue 9
  • DOI: 10.1021/ja110454b

Polymorphic Assembly from Beveled Gold Triangular Nanoprisms
journal, April 2017


Entropy difference between the face-centred cubic and hexagonal close-packed crystal structures
journal, January 1997


Comparing the Structural Stability of PbS Nanocrystals Assembled in fcc and bcc Superlattice Allotropes
journal, June 2012

  • Bian, Kaifu; Wang, Zhongwu; Hanrath, Tobias
  • Journal of the American Chemical Society, Vol. 134, Issue 26
  • DOI: 10.1021/ja304259y

Understanding the forces acting in self-assembly and the implications for constructing three-dimensional (3D) supercrystals
journal, August 2015


Solvent-Mediated Self-Assembly of Nanocube Superlattices
journal, January 2014

  • Quan, Zewei; Xu, Hongwu; Wang, Chenyu
  • Journal of the American Chemical Society, Vol. 136, Issue 4
  • DOI: 10.1021/ja408250q

One-Step One-Phase Synthesis of Monodisperse Noble-Metallic Nanoparticles and Their Colloidal Crystals
journal, May 2006

  • Zheng, Nanfeng; Fan, Jie; Stucky, Galen D.
  • Journal of the American Chemical Society, Vol. 128, Issue 20
  • DOI: 10.1021/ja0604717

Current trends in protein crystallization
journal, July 2016


Stabilizing colloidal crystals by leveraging void distributions
journal, July 2014

  • Mahynski, Nathan A.; Panagiotopoulos, Athanassios Z.; Meng, Dong
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5472

Small is different: energetic, structural, thermal, and mechanical properties of passivated nanocluster assemblies
journal, January 2004

  • Landman, Uzi; Luedtke, W. D.
  • Faraday Discussions, Vol. 125
  • DOI: 10.1039/b312640b

High-Pressure Structural Stability and Elasticity of Supercrystals Self-Assembled from Nanocrystals
journal, February 2011

  • Podsiadlo, Paul; Lee, Byeongdu; Prakapenka, Vitali B.
  • Nano Letters, Vol. 11, Issue 2
  • DOI: 10.1021/nl103587u

Tunable Plasmonic Response from Alkanethiolate-Stabilized Gold Nanoparticle Superlattices:  Evidence of Near-Field Coupling
journal, January 2008

  • Chen, Chi-Fan; Tzeng, Shien-Der; Chen, Hung-Ying
  • Journal of the American Chemical Society, Vol. 130, Issue 3
  • DOI: 10.1021/ja0773610

Interface-Induced Nucleation, Orientational Alignment and Symmetry Transformations in Nanocube Superlattices
journal, January 2012

  • Choi, Joshua J.; Bian, Kaifu; Baumgardner, William J.
  • Nano Letters, Vol. 12, Issue 9
  • DOI: 10.1021/nl3026289

A New Approach to Crystallization of CdSe Nanoparticles into Ordered Three-Dimensional Superlattices
journal, December 2001


Pressure-Driven Assembly of Spherical Nanoparticles and Formation of 1D-Nanostructure Arrays
journal, July 2010

  • Wu, Huimeng; Bai, Feng; Sun, Zaicheng
  • Angewandte Chemie International Edition, Vol. 49, Issue 45, p. 8431-8434
  • DOI: 10.1002/anie.201001581

Correlating Superlattice Polymorphs to Internanoparticle Distance, Packing Density, and Surface Lattice in Assemblies of PbS Nanoparticles
journal, February 2013

  • Wang, Zhongwu; Schliehe, Constanze; Bian, Kaifu
  • Nano Letters, Vol. 13, Issue 3
  • DOI: 10.1021/nl400084k

Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies
journal, August 2000


Size-Dependent Multiple Twinning in Nanocrystal Superlattices
journal, January 2010

  • Rupich, Sara M.; Shevchenko, Elena V.; Bodnarchuk, Maryna I.
  • Journal of the American Chemical Society, Vol. 132, Issue 1
  • DOI: 10.1021/ja9074425

Shape-Anisotropy Driven Symmetry Transformations in Nanocrystal Superlattice Polymorphs
journal, February 2011

  • Bian, Kaifu; Choi, Joshua J.; Kaushik, Ananth
  • ACS Nano, Vol. 5, Issue 4
  • DOI: 10.1021/nn103303q

Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles:  From Theory to Applications
journal, November 2007

  • Ghosh, Sujit Kumar; Pal, Tarasankar
  • Chemical Reviews, Vol. 107, Issue 11
  • DOI: 10.1021/cr0680282

Surfactant-Directed Fabrication of Supercrystals from the Assembly of Polyhedral Au–Pd Core–Shell Nanocrystals and Their Electrical and Optical Properties
journal, February 2015

  • Chiu, Chun-Ya; Chen, Cheng-Kuang; Chang, Cheng-Wei
  • Journal of the American Chemical Society, Vol. 137, Issue 6
  • DOI: 10.1021/ja509044q

Stacking entropy of hard-sphere crystals
journal, April 1999


Reversible Tuning of Silver Quantum Dot Monolayers Through the Metal-Insulator Transition
journal, September 1997


Superlattice Plasmons in Hierarchical Au Nanoparticle Arrays
journal, November 2015


An Obtuse Rhombohedral Superlattice Assembled by Pt Nanocubes
journal, August 2015


Imaging the polymerization of multivalent nanoparticles in solution
journal, October 2017


Stress-induced phase transformation and optical coupling of silver nanoparticle superlattices into mechanically stable nanowires
journal, June 2014

  • Li, Binsong; Wen, Xiaodong; Li, Ruipeng
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5179

    Works referencing / citing this record:

    Hierarchical supercrystalline nanocomposites through the self-assembly of organically-modified ceramic nanoparticles
    journal, March 2019


    Oriented Gold Nanorod Arrays: Self-Assembly and Optoelectronic Applications
    journal, June 2019

    • Wei, Wenbo; Bai, Feng; Fan, Hongyou
    • Angewandte Chemie International Edition, Vol. 58, Issue 35
    • DOI: 10.1002/anie.201902620

    Oriented Gold Nanorod Arrays: Self-Assembly and Optoelectronic Applications
    journal, June 2019

    • Wei, Wenbo; Bai, Feng; Fan, Hongyou
    • Angewandte Chemie International Edition, Vol. 58, Issue 35
    • DOI: 10.1002/anie.201902620

    Hierarchical supercrystalline nanocomposites through the self-assembly of organically-modified ceramic nanoparticles
    text, January 2019

    • Domènech, Berta; Kampferbeck, Michael; Larsson, Emanuel
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
    • DOI: 10.3204/pubdb-2019-01333