Thermal and mechanical properties of CeO2
Abstract
Abstract The thermal and mechanical properties of cerium dioxide (CeO 2 ) were assessed using a range of experimental techniques. The oxygen potential of CeO 2 was measured by the thermogravimetric technique, and a numerical fit for the oxygen potential of CeO 2 is derived based on defect chemistry. Mechanical properties of CeO 2 were obtained using sound velocity measurement, resonant ultrasound spectroscopy and nanoindentation. The obtained mechanical properties of CeO 2 are then used to evaluate the Debye temperature and Grüneisen constant. The heat capacity and thermal conductivity of CeO 2 were also calculated using the Debye temperature and the Grüneisen constant. Finally, the thermal conductivity was calculated based upon laser flash analysis measurements performed on pellets fabricated using a range of feedstock purities to resolve discrepancies in the existing literature.
- Authors:
-
- Japan Atomic Energy Agency (JAEA), Ibaraki (Japan)
- Inspection Development Company, Ibaraki (Japan)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Office of Nuclear Energy (NE); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1469554
- Alternate Identifier(s):
- OSTI ID: 1472144
- Report Number(s):
- LA-UR-18-23161
Journal ID: ISSN 0002-7820
- Grant/Contract Number:
- AC52-06NA25396; DE‐AC52‐06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Ceramic Society
- Additional Journal Information:
- Journal Volume: 102; Journal Issue: 4; Journal ID: ISSN 0002-7820
- Publisher:
- American Ceramic Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; CeO2; Nuclear materials; Oxygen potential; Elastic properties; Heat capacity; Thermal conductivity
Citation Formats
Suzuki, Kiichi, Kato, Masato, Sunaoshi, Takeo, Uno, Hiroki, Carvajal-Nunez, Ursula, Nelson, Andrew T., and McClellan, Kenneth J. Thermal and mechanical properties of CeO2. United States: N. p., 2018.
Web. doi:10.1111/jace.16055.
Suzuki, Kiichi, Kato, Masato, Sunaoshi, Takeo, Uno, Hiroki, Carvajal-Nunez, Ursula, Nelson, Andrew T., & McClellan, Kenneth J. Thermal and mechanical properties of CeO2. United States. https://doi.org/10.1111/jace.16055
Suzuki, Kiichi, Kato, Masato, Sunaoshi, Takeo, Uno, Hiroki, Carvajal-Nunez, Ursula, Nelson, Andrew T., and McClellan, Kenneth J. Thu .
"Thermal and mechanical properties of CeO2". United States. https://doi.org/10.1111/jace.16055. https://www.osti.gov/servlets/purl/1469554.
@article{osti_1469554,
title = {Thermal and mechanical properties of CeO2},
author = {Suzuki, Kiichi and Kato, Masato and Sunaoshi, Takeo and Uno, Hiroki and Carvajal-Nunez, Ursula and Nelson, Andrew T. and McClellan, Kenneth J.},
abstractNote = {Abstract The thermal and mechanical properties of cerium dioxide (CeO 2 ) were assessed using a range of experimental techniques. The oxygen potential of CeO 2 was measured by the thermogravimetric technique, and a numerical fit for the oxygen potential of CeO 2 is derived based on defect chemistry. Mechanical properties of CeO 2 were obtained using sound velocity measurement, resonant ultrasound spectroscopy and nanoindentation. The obtained mechanical properties of CeO 2 are then used to evaluate the Debye temperature and Grüneisen constant. The heat capacity and thermal conductivity of CeO 2 were also calculated using the Debye temperature and the Grüneisen constant. Finally, the thermal conductivity was calculated based upon laser flash analysis measurements performed on pellets fabricated using a range of feedstock purities to resolve discrepancies in the existing literature.},
doi = {10.1111/jace.16055},
journal = {Journal of the American Ceramic Society},
number = 4,
volume = 102,
place = {United States},
year = {Thu Sep 06 00:00:00 EDT 2018},
month = {Thu Sep 06 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Thermal expansion measurement and heat capacity evaluation of hypo-stoichiometric PuO2.00
journal, August 2014
- Kato, Masato; Uchida, Teppei; Matsumoto, Taku
- Journal of Nuclear Materials, Vol. 451, Issue 1-3
Thermal conductivities of (U, Pu, Am)O2 solid solutions
journal, March 2008
- Morimoto, Kyoichi; Kato, Masato; Ogasawara, Masahiro
- Journal of Alloys and Compounds, Vol. 452, Issue 1
Thermal Conductivity in Nanocrystalline Ceria Thin Films
journal, December 2013
- Khafizov, Marat; Park, In-Wook; Chernatynskiy, Aleksandr
- Journal of the American Ceramic Society, Vol. 97, Issue 2
Etude par diffraction des rayons X A haute temperature en atmosphere controlee du systeme Ce-O
journal, October 1981
- Touzelin, B.
- Journal of Nuclear Materials, Vol. 101, Issue 1-2
Thermal expansion of PuO2
journal, September 2014
- Uchida, Teppei; Sunaoshi, Takeo; Konashi, Kenji
- Journal of Nuclear Materials, Vol. 452, Issue 1-3
Sound speeds in and mechanical properties of (U,Pu)O 2− x
journal, November 2017
- Hirooka, Shun; Kato, Masato
- Journal of Nuclear Science and Technology, Vol. 55, Issue 3
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Oxygen potentials of PuO 2-x
journal, January 2012
- Komeno, Akira; Kato, Masato; Hirooka, Shun
- MRS Proceedings, Vol. 1444
Effect of sintering aids on the electrical properties of Ce0.9Nd0.1O2−δ
journal, July 2012
- Xia, Yanjie; Bai, Yijia; Wu, Xiaojie
- Solid State Sciences, Vol. 14, Issue 7
Study of the formation of UO2-PuO2 solid solution by means of UO2-CeO2 simulate
journal, August 1986
- Dörr, W.; Hellmann, S.; Mages, G.
- Journal of Nuclear Materials, Vol. 140, Issue 1
Oxygen potentials of mixed oxide fuels for fast reactors
journal, March 2009
- Kato, M.; Tamura, T.; Konashi, K.
- Journal of Nuclear Materials, Vol. 385, Issue 2
Thermal conductivity of ThO2 and Th0.98U0.02O2
journal, January 2000
- Pillai, C. G. S.; Raj, P.
- Journal of Nuclear Materials, Vol. 277, Issue 1
Analysis of oxygen potential of (U0.7Pu0.3)O2±x and (U0.8Pu0.2)O2±x based on point defect chemistry
journal, May 2009
- Kato, Masato; Konashi, Kenji; Nakae, Nobuo
- Journal of Nuclear Materials, Vol. 389, Issue 1
Oxygen potentials of plutonium and uranium mixed oxide
journal, September 2005
- Kato, Masato; Tamura, Tetsuya; Konashi, Kenji
- Journal of Nuclear Materials, Vol. 344, Issue 1-3
Gallium Removal from Weapons-Grade Plutonium and Cerium Oxide Surrogate by a Thermal Technique
journal, January 1999
- Park, YoungSoo; Kolman, David G.; Ziraffe, Hisham
- MRS Proceedings, Vol. 556
An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments
journal, June 1992
- Oliver, W. C.; Pharr, G. M.
- Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583
Powder diffraction analysis of cerium dioxide at high pressure
journal, June 1993
- Gerward, L.; Olsen, J. Staun
- Powder Diffraction, Vol. 8, Issue 2
Über die oxyde des cers—V
journal, November 1960
- Brauer, G.; Gingerich, K. A.
- Journal of Inorganic and Nuclear Chemistry, Vol. 16, Issue 1-2
Etude thermodynamique de l'oxyde CeO2−x pour
journal, January 1978
- Campserveux, J.; Gerdanian, P.
- Journal of Solid State Chemistry, Vol. 23, Issue 1-2
Bulk modulus of CeO2 and PrO2—An experimental and theoretical study
journal, September 2005
- Gerward, L.; Staun Olsen, J.; Petit, L.
- Journal of Alloys and Compounds, Vol. 400, Issue 1-2
Some elastic constant data on minerals relevant to geophysics
journal, January 1968
- Anderson, Orson L.; Schreiber, Edward; Liebermann, Robert C.
- Reviews of Geophysics, Vol. 6, Issue 4
A high temperature lattice parameter and dilatometer study of the defect structure of nonstoichiometric cerium dioxide
journal, October 1993
- Chiang, H.; Blumenthal, R.; Fournelle, R.
- Solid State Ionics, Vol. 66, Issue 1-2
Applicability of CeO2 as a surrogate for PuO2 in a MOX fuel development
journal, August 2008
- Kim, Han Soo; Joung, Chang Yong; Lee, Byung Ho
- Journal of Nuclear Materials, Vol. 378, Issue 1
Resonant ultrasound spectroscopic techniques for measurement of the elastic moduli of solids
journal, January 1993
- Migliori, A.; Sarrao, J. L.; Visscher, William M.
- Physica B: Condensed Matter, Vol. 183, Issue 1-2
An Evaluation of the Thermophysical Properties of Stoichiometric CeO 2 in Comparison to UO 2 and PuO 2
journal, August 2014
- Nelson, Andrew T.; Rittman, Dylan R.; White, Joshua T.
- Journal of the American Ceramic Society, Vol. 97, Issue 11
Thermally induced gallium removal from plutonium dioxide for MOX fuel production
journal, December 2000
- Kolman, D. G.; Griego, M. E.; James, C. A.
- Journal of Nuclear Materials, Vol. 282, Issue 2-3
Thermal diffusivity measurement of (U, Pu)O2−x at high temperatures up to 2190K
journal, November 2013
- Morimoto, Kyoichi; Kato, Masato; Ogasawara, Masahiro
- Journal of Nuclear Materials, Vol. 443, Issue 1-3
The Thermal Conductivity of Nonmetallic Crystals
book, January 1979
- Slack, Glen A.
- Solid State Physics
Thermodynamic assessment of the oxygen rich U–Ce–O system
journal, December 2015
- McMurray, J. W.; Hirooka, S.; Murakami, T.
- Journal of Nuclear Materials, Vol. 467
Thermal expansion measurement of (U,Pu)O2-x in oxygen partial pressure-controlled atmosphere
journal, February 2016
- Kato, Masato; Ikusawa, Yoshihisa; Sunaoshi, Takeo
- Journal of Nuclear Materials, Vol. 469
A review of the thermophysical properties of MOX and UO2 fuels
journal, December 2001
- Carbajo, Juan J.; Yoder, Gradyon L.; Popov, Sergey G.
- Journal of Nuclear Materials, Vol. 299, Issue 3
Thermal conductivity of UO2+x and U4O9−y
journal, November 2013
- White, J. T.; Nelson, A. T.
- Journal of Nuclear Materials, Vol. 443, Issue 1-3
Phase equilibria in the CeO and CeFeO systems
journal, January 1985
- Kitayama, Kenzo; Nojiri, Kiyoshi; Sugihara, Tadashi
- Journal of Solid State Chemistry, Vol. 56, Issue 1
The chemical thermodynamics of nuclear materials. VII. the high-temperature enthalpy of plutonium dioxide
journal, February 1982
- Oetting, Franklin L.
- Journal of Nuclear Materials, Vol. 105, Issue 2-3
1000oC Phase Relations and Superconductivity in the (Nd-Ce-Cu)-O Ternary System
journal, July 1990
- Pieczulewski, Charles N.; Kirkpatrick, Kelly S.; Mason, Thomas O.
- Journal of the American Ceramic Society, Vol. 73, Issue 7
Physical, chemical and electrochemical properties of pure and doped ceria
journal, April 2000
- Mogensen, M.
- Solid State Ionics, Vol. 129, Issue 1-4
Defect Chemistry and Basic Properties of Non-Stoichiometric PuO<sub>2</sub>
journal, May 2017
- Kato, Masato; Nakamura, Hiroki; Watanabe, Masashi
- Defect and Diffusion Forum, Vol. 375
First-Principles Calculation of Phonon and Schottky Heat Capacities of Plutonium Dioxide
journal, May 2015
- Nakamura, Hiroki; Machida, Masahiko; Kato, Masato
- Journal of the Physical Society of Japan, Vol. 84, Issue 5
Some elastic constant data on minerals relevant to geophysics
book, January 1988
- Anderson, Orson L.; Schreiber, Edward; Liebermann, Robert C.
- Elastic Properties and Equations of State
Works referencing / citing this record:
A comprehensive assessment of the low-temperature thermal properties and thermodynamic functions of CeO 2
journal, July 2019
- Morrison, Tyler D.; Wood, Elizabeth Sooby; Weck, Phillippe F.
- The Journal of Chemical Physics, Vol. 151, Issue 4
Impact of irradiation induced dislocation loops on thermal conductivity in ceramics
journal, June 2019
- Khafizov, Marat; Pakarinen, Janne; He, Lingfeng
- Journal of the American Ceramic Society, Vol. 102, Issue 12
Figures / Tables found in this record: