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Title: Two-dimensional vibrational-electronic spectroscopy

Abstract

Two-dimensional vibrational-electronic (2D VE) spectroscopy is a femtosecond Fourier transform (FT) third-order nonlinear technique that creates a link between existing 2D FT spectroscopies in the vibrational and electronic regions of the spectrum. 2D VE spectroscopy enables a direct measurement of infrared (IR) and electronic dipole moment cross terms by utilizing mid-IR pump and optical probe fields that are resonant with vibrational and electronic transitions, respectively, in a sample of interest. We detail this newly developed 2D VE spectroscopy experiment and outline the information contained in a 2D VE spectrum. We then use this technique and its single-pump counterpart (1D VE) to probe the vibrational-electronic couplings between high frequency cyanide stretching vibrations (ν CN) and either a ligand-to-metal charge transfer transition ([Fe III(CN) 6] 3- dissolved in formamide) or a metal-to-metal charge transfer (MMCT) transition ([(CN) 5Fe IICNRu III(NH 3) 5]- dissolved in formamide). The 2D VE spectra of both molecules reveal peaks resulting from coupled high- and low-frequency vibrational modes to the charge transfer transition. The time-evolving amplitudes and positions of the peaks in the 2D VE spectra report on coherent and incoherent vibrational energy transfer dynamics among the coupled vibrational modes and the charge transfer transition. The selectivity ofmore » 2D VE spectroscopy to vibronic processes is evidenced from the selective coupling of specific ν CN modes to the MMCT transition in the mixed valence complex. The lineshapes in 2D VE spectra report on the correlation of the frequency fluctuations between the coupled vibrational and electronic frequencies in the mixed valence complex which has a time scale of 1 ps. Lastly, the details and results of this study confirm the versatility of 2D VE spectroscopy and its applicability to probe how vibrations modulate charge and energy transfer in a wide range of complex molecular, material, and biological systems.« less

Authors:
 [1];  [1];  [1];  [1]
  1. Univ. of Washington, Seattle, WA (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Univ. of Washington, Seattle, WA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1469485
Alternate Identifier(s):
OSTI ID: 1224223
Grant/Contract Number:  
SC0012450; SC0002190
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 143; Journal Issue: 15; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Courtney, Trevor L., Fox, Zachary W., Slenkamp, Karla M., and Khalil, Munira. Two-dimensional vibrational-electronic spectroscopy. United States: N. p., 2015. Web. doi:10.1063/1.4932983.
Courtney, Trevor L., Fox, Zachary W., Slenkamp, Karla M., & Khalil, Munira. Two-dimensional vibrational-electronic spectroscopy. United States. doi:10.1063/1.4932983.
Courtney, Trevor L., Fox, Zachary W., Slenkamp, Karla M., and Khalil, Munira. Wed . "Two-dimensional vibrational-electronic spectroscopy". United States. doi:10.1063/1.4932983. https://www.osti.gov/servlets/purl/1469485.
@article{osti_1469485,
title = {Two-dimensional vibrational-electronic spectroscopy},
author = {Courtney, Trevor L. and Fox, Zachary W. and Slenkamp, Karla M. and Khalil, Munira},
abstractNote = {Two-dimensional vibrational-electronic (2D VE) spectroscopy is a femtosecond Fourier transform (FT) third-order nonlinear technique that creates a link between existing 2D FT spectroscopies in the vibrational and electronic regions of the spectrum. 2D VE spectroscopy enables a direct measurement of infrared (IR) and electronic dipole moment cross terms by utilizing mid-IR pump and optical probe fields that are resonant with vibrational and electronic transitions, respectively, in a sample of interest. We detail this newly developed 2D VE spectroscopy experiment and outline the information contained in a 2D VE spectrum. We then use this technique and its single-pump counterpart (1D VE) to probe the vibrational-electronic couplings between high frequency cyanide stretching vibrations (νCN) and either a ligand-to-metal charge transfer transition ([FeIII(CN)6]3- dissolved in formamide) or a metal-to-metal charge transfer (MMCT) transition ([(CN)5FeIICNRuIII(NH3)5]- dissolved in formamide). The 2D VE spectra of both molecules reveal peaks resulting from coupled high- and low-frequency vibrational modes to the charge transfer transition. The time-evolving amplitudes and positions of the peaks in the 2D VE spectra report on coherent and incoherent vibrational energy transfer dynamics among the coupled vibrational modes and the charge transfer transition. The selectivity of 2D VE spectroscopy to vibronic processes is evidenced from the selective coupling of specific νCN modes to the MMCT transition in the mixed valence complex. The lineshapes in 2D VE spectra report on the correlation of the frequency fluctuations between the coupled vibrational and electronic frequencies in the mixed valence complex which has a time scale of 1 ps. Lastly, the details and results of this study confirm the versatility of 2D VE spectroscopy and its applicability to probe how vibrations modulate charge and energy transfer in a wide range of complex molecular, material, and biological systems.},
doi = {10.1063/1.4932983},
journal = {Journal of Chemical Physics},
number = 15,
volume = 143,
place = {United States},
year = {2015},
month = {10}
}

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Works referenced in this record:

Isotropic and anisotropic Raman scattering from molecular liquids measured by spatially masked optical Kerr effect spectroscopy
journal, July 2002

  • Fecko, C. J.; Eaves, J. D.; Tokmakoff, A.
  • The Journal of Chemical Physics, Vol. 117, Issue 3
  • DOI: 10.1063/1.1485070

Vibrational Population Relaxation and Dephasing Dynamics of Fe(CN) 6 4- in D 2 O with Third-Order Nonlinear Infrared Spectroscopy
journal, February 2004

  • Ohta, Kaoru; Maekawa, Hiroaki; Tominaga, Keisuke
  • The Journal of Physical Chemistry A, Vol. 108, Issue 8
  • DOI: 10.1021/jp0369847

Labeling Vibrations by Light:  Ultrafast Transient 2D-IR Spectroscopy Tracks Vibrational Modes during Photoinduced Charge Transfer
journal, February 2004

  • Bredenbeck, Jens; Helbing, Jan; Hamm, Peter
  • Journal of the American Chemical Society, Vol. 126, Issue 4
  • DOI: 10.1021/ja0380190

Coherent Fifth-Order Visible–Infrared Spectroscopies: Ultrafast Nonequilibrium Vibrational Dynamics in Solution
journal, June 2012

  • Lynch, Michael S.; Slenkamp, Karla M.; Cheng, Mark
  • The Journal of Physical Chemistry A, Vol. 116, Issue 26
  • DOI: 10.1021/jp303701b

Vibrational Mode Coupling to Ultrafast Electron Transfer in [(CN) 5 OsCNRu(NH 3 ) 5 ] - Studied by Femtosecond Infrared Spectroscopy
journal, October 2003

  • Tivanski, Alexei V.; Wang, Chengfei; Walker, Gilbert C.
  • The Journal of Physical Chemistry A, Vol. 107, Issue 43
  • DOI: 10.1021/jp034274v

Mixed IR/Vis Two-Dimensional Spectroscopy: Chemical Exchange beyond the Vibrational Lifetime and Sub-ensemble Selective Photochemistry
journal, January 2014

  • van Wilderen, Luuk J. G. W.; Messmer, Andreas T.; Bredenbeck, Jens
  • Angewandte Chemie International Edition, Vol. 53, Issue 10
  • DOI: 10.1002/anie.201305950

Phase-locked pulses for two-dimensional spectroscopy by a birefringent delay line
journal, January 2012

  • Brida, Daniele; Manzoni, Cristian; Cerullo, Giulio
  • Optics Letters, Vol. 37, Issue 15
  • DOI: 10.1364/OL.37.003027

Femtosecond Phase-Coherent Two-Dimensional Spectroscopy
journal, June 2003

  • Tian, Peifang; Keusters, Dorine; Suzaki, Yoshifumi
  • Science, Vol. 300, Issue 5625, p. 1553-1555
  • DOI: 10.1126/science.1083433

A unified treatment of ultrafast optical heterodyne detected and Z-scan spectroscopies
journal, February 2001

  • Gardecki, J. A.; Yu, G.; Constantine, S.
  • The Journal of Chemical Physics, Vol. 114, Issue 8
  • DOI: 10.1063/1.1342015

Two-color two-dimensional Fourier transform electronic spectroscopy with a pulse-shaper
journal, January 2008

  • Myers, Jeffrey A.; Lewis, Kristin L.; Tekavec, Patrick F.
  • Optics Express, Vol. 16, Issue 22
  • DOI: 10.1364/OE.16.017420

Structural Rearrangements in Water Viewed Through Two-Dimensional Infrared Spectroscopy
journal, September 2009

  • Roberts, Sean T.; Ramasesha, Krupa; Tokmakoff, Andrei
  • Accounts of Chemical Research, Vol. 42, Issue 9
  • DOI: 10.1021/ar900088g

Optical two-dimensional Fourier transform spectroscopy of semiconductors
journal, December 2005


Novel Surface Vibrational Spectroscopy: Infrared-Infrared-Visible Sum-Frequency Generation
journal, February 2001


Probing the Photoinduced Metal−Nitrosyl Linkage Isomerism of Sodium Nitroprusside in Solution Using Transient Infrared Spectroscopy
journal, April 2011

  • Lynch, Michael S.; Cheng, Mark; Van Kuiken, Benjamin E.
  • Journal of the American Chemical Society, Vol. 133, Issue 14
  • DOI: 10.1021/ja110881n

Ultrafast nonequilibrium Fourier-transform two-dimensional infrared spectroscopy
journal, January 2008

  • Baiz, Carlos R.; Nee, Matthew J.; McCanne, Robert
  • Optics Letters, Vol. 33, Issue 21
  • DOI: 10.1364/OL.33.002533

Taking apart the two-dimensional infrared vibrational echo spectra: More information and elimination of distortions
journal, May 2008

  • Kwak, Kyungwon; Rosenfeld, Daniel E.; Fayer, M. D.
  • The Journal of Chemical Physics, Vol. 128, Issue 20
  • DOI: 10.1063/1.2927906

Vibrational Frequency Fluctuation of Ions in Aqueous Solutions Studied by Three-Pulse Infrared Photon Echo Method
journal, March 2012

  • Ohta, Kaoru; Tayama, Jumpei; Saito, Shinji
  • Accounts of Chemical Research, Vol. 45, Issue 11
  • DOI: 10.1021/ar300017h

Enhanced interferometric detection in two-dimensional spectroscopy with a Sagnac interferometer
journal, January 2014

  • Courtney, Trevor L.; Park, Samuel D.; Hill, Robert J.
  • Optics Letters, Vol. 39, Issue 3
  • DOI: 10.1364/OL.39.000513

Frequency-frequency correlation functions and apodization in two-dimensional infrared vibrational echo spectroscopy: A new approach
journal, September 2007

  • Kwak, Kyungwon; Park, Sungnam; Finkelstein, Ilya J.
  • The Journal of Chemical Physics, Vol. 127, Issue 12
  • DOI: 10.1063/1.2772269

Two-dimensional spectroscopy using diffractive optics based phased-locked photon echoes
journal, March 2004


T WO -D IMENSIONAL F EMTOSECOND S PECTROSCOPY
journal, October 2003


Two-dimensional Fourier transform spectroscopy in the ultraviolet with sub-20 fs pump pulses and 250–720 nm supercontinuum probe
journal, August 2013


From Ultrafast Structure Determination to Steering Reactions: Mixed IR/Non-IR Multidimensional Vibrational Spectroscopies
journal, August 2015

  • van Wilderen, Luuk J. G. W.; Bredenbeck, Jens
  • Angewandte Chemie International Edition, Vol. 54, Issue 40
  • DOI: 10.1002/anie.201503155

Measuring Coherently Coupled Intramolecular Vibrational and Charge-Transfer Dynamics with Two-Dimensional Vibrational–Electronic Spectroscopy
journal, March 2015

  • Courtney, Trevor L.; Fox, Zachary W.; Estergreen, Laura
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 7
  • DOI: 10.1021/acs.jpclett.5b00356

Femtosecond Multicolor Pump−Probe Study of Ultrafast Electron Transfer of [(NH 3 ) 5 Ru III NCRu II (CN) 5 ] - in Aqueous Solution
journal, May 2002

  • Son, Dong Hee; Kambhampati, Patanjali; Kee, Tak W.
  • The Journal of Physical Chemistry A, Vol. 106, Issue 18
  • DOI: 10.1021/jp014151f

Determining the static electronic and vibrational energy correlations via two-dimensional electronic-vibrational spectroscopy
journal, May 2015

  • Dong, Hui; Lewis, Nicholas H. C.; Oliver, Thomas A. A.
  • The Journal of Chemical Physics, Vol. 142, Issue 17
  • DOI: 10.1063/1.4919684

Experimental distinction between phase shifts and time delays: Implications for femtosecond spectroscopy and coherent control of chemical reactions
journal, December 1999

  • Albrecht, Allison W.; Hybl, John D.; Gallagher Faeder, Sarah M.
  • The Journal of Chemical Physics, Vol. 111, Issue 24, p. 10934-10956
  • DOI: 10.1063/1.480457

Frequency-resolved pump–probe characterization of femtosecond infrared pulses
journal, January 2002

  • Yeremenko, Sergey; Baltuška, Andrius; de Haan, F.
  • Optics Letters, Vol. 27, Issue 13, p. 1171-1173
  • DOI: 10.1364/OL.27.001171

Femtosecond experiments and absolute rate calculations on intervalence electron transfer of mixed‐valence compounds
journal, January 1993

  • Tominaga, Keisuke; Kliner, Dahv A. V.; Johnson, Alan E.
  • The Journal of Chemical Physics, Vol. 98, Issue 2
  • DOI: 10.1063/1.464344

Measuring correlated electronic and vibrational spectral dynamics using line shapes in two-dimensional electronic-vibrational spectroscopy
journal, May 2015

  • Lewis, Nicholas H. C.; Dong, Hui; Oliver, Thomas A. A.
  • The Journal of Chemical Physics, Vol. 142, Issue 17
  • DOI: 10.1063/1.4919686

Tunable two-dimensional femtosecond spectroscopy
journal, January 2004

  • Brixner, T.; Stiopkin, I. V.; Fleming, G. R.
  • Optics Letters, Vol. 29, Issue 8
  • DOI: 10.1364/OL.29.000884

Two-Dimensional Ultrafast Fourier Transform Spectroscopy in the Deep Ultraviolet
journal, January 2009

  • Tseng, Chien-hung; Matsika, Spiridoula; Weinacht, Thomas C.
  • Optics Express, Vol. 17, Issue 21
  • DOI: 10.1364/OE.17.018788

Optical coherence and theoretical study of the excitation dynamics of a highly symmetric cyclophane-linked oligophenylenevinylene dimer
journal, May 2006

  • Moran, Andrew M.; Maddox, Jeremy B.; Hong, Janice W.
  • The Journal of Chemical Physics, Vol. 124, Issue 19
  • DOI: 10.1063/1.2196041

Dual-frequency 2D IR photon echo of a hydrogen bond
journal, February 2005


Ultrafast Infrared Spectroscopy of Vibrational States Prepared by Photoinduced Electron Transfer in (CN) 5 FeCNRu(NH 3 ) 5 -
journal, May 2000

  • Wang, Chengfei; Mohney, Brian K.; Akhremitchev, Boris B.
  • The Journal of Physical Chemistry A, Vol. 104, Issue 18
  • DOI: 10.1021/jp993927y

Correlating the motion of electrons and nuclei with two-dimensional electronic-vibrational spectroscopy
journal, June 2014

  • Oliver, T. A. A.; Lewis, N. H. C.; Fleming, G. R.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 28
  • DOI: 10.1073/pnas.1409207111

Two-dimensional electronic-vibrational spectra: modeling correlated electronic and nuclear motion
journal, January 2015

  • Terenziani, F.; Painelli, A.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 19
  • DOI: 10.1039/C5CP01485A

Ultrafast 2D IR Vibrational Echo Spectroscopy
journal, January 2007

  • Zheng, Junrong; Kwak, Kyungwon; Fayer, M. D.
  • Accounts of Chemical Research, Vol. 40, Issue 1
  • DOI: 10.1021/ar068010d

Coherently Controlled Ultrafast Four-Wave Mixing Spectroscopy
journal, June 2007

  • Vaughan, Joshua C.; Hornung, T.; Stone, K. W.
  • The Journal of Physical Chemistry A, Vol. 111, Issue 23
  • DOI: 10.1021/jp0662911

Complete Determination of Intermolecular Spectral Densities of Liquids Using Position-Sensitive Kerr Lens Spectroscopy
journal, January 1996

  • Cong, Peijun; Chang, Yong Joon; Simon, John D.
  • The Journal of Physical Chemistry, Vol. 100, Issue 21
  • DOI: 10.1021/jp9602437

Contemporary Issues in Electron Transfer Research
journal, January 1996

  • Barbara, Paul F.; Meyer, Thomas J.; Ratner, Mark A.
  • The Journal of Physical Chemistry, Vol. 100, Issue 31
  • DOI: 10.1021/jp9605663

Investigating vibrational anharmonic couplings in cyanide-bridged transition metal mixed valence complexes using two-dimensional infrared spectroscopy
journal, February 2014

  • Slenkamp, Karla M.; Lynch, Michael S.; Van Kuiken, Benjamin E.
  • The Journal of Chemical Physics, Vol. 140, Issue 8
  • DOI: 10.1063/1.4866294

Solvent Control of Vibronic Coupling upon Intervalence Charge Transfer Excitation of (CN) 5 FeCNRu(NH 3 ) 5 - as Revealed by Resonance Raman and Near-Infrared Absorption Spectroscopies
journal, June 1998

  • Wang, Chengfei; Mohney, Brian K.; Williams, Robert D.
  • Journal of the American Chemical Society, Vol. 120, Issue 23
  • DOI: 10.1021/ja9736931

Two-Dimensional Electronic Correlation and Relaxation Spectra:  Theory and Model Calculations
journal, December 1999

  • Gallagher Faeder, Sarah M.; Jonas, David M.
  • The Journal of Physical Chemistry A, Vol. 103, Issue 49
  • DOI: 10.1021/jp9925738

Two-Dimensional Infrared Spectroscopy of Intermolecular Hydrogen Bonds in the Condensed Phase
journal, September 2009

  • Elsaesser, Thomas
  • Accounts of Chemical Research, Vol. 42, Issue 9
  • DOI: 10.1021/ar900006u

Hydrophobic Solvation: A 2D IR Spectroscopic Inquest
journal, September 2009

  • Bakulin, Artem A.; Liang, Chungwen; la Cour Jansen, Thomas
  • Accounts of Chemical Research, Vol. 42, Issue 9
  • DOI: 10.1021/ar9000247

Dynamics of Solvent-Mediated Electron Localization in Electronically Excited Hexacyanoferrate(III)
journal, January 2012

  • Zhang, Wenkai; Ji, Minbiao; Sun, Zheng
  • Journal of the American Chemical Society, Vol. 134, Issue 5
  • DOI: 10.1021/ja207306t

Structural Dynamics of Hydrated Phospholipid Surfaces Probed by Ultrafast 2D Spectroscopy of Phosphate Vibrations
journal, January 2014

  • Costard, Rene; Heisler, Ismael A.; Elsaesser, Thomas
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 3
  • DOI: 10.1021/jz402493b

Communication: Probing non-equilibrium vibrational relaxation pathways of highly excited C≡N stretching modes following ultrafast back-electron transfer
journal, June 2012

  • Lynch, Michael S.; Slenkamp, Karla M.; Khalil, Munira
  • The Journal of Chemical Physics, Vol. 136, Issue 24
  • DOI: 10.1063/1.4731882

Coherent two-dimensional ultraviolet spectroscopy in fully noncollinear geometry
journal, January 2010

  • Selig, Ulrike; Schleussner, Carl-Friedrich; Foerster, Michael
  • Optics Letters, Vol. 35, Issue 24
  • DOI: 10.1364/OL.35.004178

Two-dimensional Raman-terahertz spectroscopy of water
journal, December 2013

  • Savolainen, J.; Ahmed, S.; Hamm, P.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 51
  • DOI: 10.1073/pnas.1317459110

Doubly Vibrationally Enhanced Four Wave Mixing: The Optical Analog to 2D NMR
journal, February 2000


Two-dimensional infrared spectroscopy of peptides by phase-controlled femtosecond vibrational photon echoes
journal, July 2000

  • Asplund, M. C.; Zanni, M. T.; Hochstrasser, R. M.
  • Proceedings of the National Academy of Sciences, Vol. 97, Issue 15
  • DOI: 10.1073/pnas.140227997

Fully automated dual-frequency three-pulse-echo 2DIR spectrometer accessing spectral range from 800 to 4000 wavenumbers
journal, August 2014

  • Leger, Joel D.; Nyby, Clara M.; Varner, Clyde
  • Review of Scientific Instruments, Vol. 85, Issue 8
  • DOI: 10.1063/1.4892480

Coherent 2D IR Spectroscopy:  Molecular Structure and Dynamics in Solution
journal, July 2003

  • Khalil, M.; Demirdöven, N.; Tokmakoff, A.
  • The Journal of Physical Chemistry A, Vol. 107, Issue 27
  • DOI: 10.1021/jp0219247

Erratum: “Experimental distinction between phase shifts and time delays: Implications for femtosecond spectroscopy and coherent control of chemical reactions” [J. Chem. Phys. 111 , 10934 (1999)]
journal, September 2001

  • Albrecht Ferro, Allison W.; Hybl, John D.; Gallagher Faeder, Sarah M.
  • The Journal of Chemical Physics, Vol. 115, Issue 12
  • DOI: 10.1063/1.1398312

Facile collection of two-dimensional electronic spectra using femtosecond pulse-shaping Technology
journal, January 2007

  • Grumstrup, Erik M.; Shim, Sang-Hee; Montgomery, Matthew A.
  • Optics Express, Vol. 15, Issue 25
  • DOI: 10.1364/OE.15.016681

Energy transfer pathways in semiconducting carbon nanotubes revealed using two-dimensional white-light spectroscopy
journal, April 2015

  • Mehlenbacher, Randy D.; McDonough, Thomas J.; Grechko, Maksim
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7732

Mapping the Vibronic Structure of a Molecule by Few-Cycle Continuum Two-Dimensional Spectroscopy in a Single Pulse
journal, August 2014

  • Spokoyny, Boris; Harel, Elad
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 16
  • DOI: 10.1021/jz5012302

A relaxation-assisted 2D IR spectroscopy method
journal, June 2007

  • Kurochkin, D. V.; Naraharisetty, S. R. G.; Rubtsov, I. V.
  • Proceedings of the National Academy of Sciences, Vol. 104, Issue 36
  • DOI: 10.1073/pnas.0700560104

ULTRAFAST CHEMISTRY: Using Time-Resolved Vibrational Spectroscopy for Interrogation of Structural Dynamics
journal, May 2005


Ultrafast electron transfer and coupled vibrational dynamics in cyanide bridged mixed-valence transition-metal dimers
journal, July 1993

  • Doorn, Stephen K.; Dyer, R. Brian; Stoutland, Page O.
  • Journal of the American Chemical Society, Vol. 115, Issue 14
  • DOI: 10.1021/ja00067a065

Automated 2D IR spectroscopy using a mid-IR pulse shaper and application of this technology to the human islet amyloid polypeptide
journal, May 2007

  • Shim, S.-H.; Strasfeld, D. B.; Ling, Y. L.
  • Proceedings of the National Academy of Sciences, Vol. 104, Issue 36, p. 14197-14202
  • DOI: 10.1073/pnas.0700804104

On the Role of High-Frequency Intramolecular Vibrations in Ultrafast Back-Electron Transfer Reactions
journal, August 2011

  • Lynch, Michael S.; Van Kuiken, Benjamin E.; Daifuku, Stephanie L.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 17
  • DOI: 10.1021/jz200930h

Optical heterodyne detected spectrograms of ultrafast nonresonant electronic responses
journal, January 2000

  • Gardecki, J. A.; Constantine, S.; Zhou, Y.
  • Journal of the Optical Society of America B, Vol. 17, Issue 4
  • DOI: 10.1364/JOSAB.17.000652

Vibrational and rotational dynamics of cyanoferrates in solution
journal, August 2004

  • Sando, Gerald M.; Zhong, Q.; Owrutsky, J. C.
  • The Journal of Chemical Physics, Vol. 121, Issue 5
  • DOI: 10.1063/1.1767072

Visible–infrared two-dimensional Fourier-transform spectroscopy
journal, January 2002


Two-dimensional electronic spectroscopy with a continuum probe
journal, January 2009

  • Tekavec, Patrick F.; Myers, Jeffrey A.; Lewis, Kristin L. M.
  • Optics Letters, Vol. 34, Issue 9
  • DOI: 10.1364/OL.34.001390

Collective vibrations of water-solvated hydroxide ions investigated with broadband 2DIR spectroscopy
journal, May 2014

  • Mandal, Aritra; Ramasesha, Krupa; De Marco, Luigi
  • The Journal of Chemical Physics, Vol. 140, Issue 20
  • DOI: 10.1063/1.4878490

High-sensitivity, single-beam n_2 measurements
journal, January 1989

  • Sheik-bahae, M.; Said, A. A.; Van Stryland, E. W.
  • Optics Letters, Vol. 14, Issue 17
  • DOI: 10.1364/OL.14.000955

M ULTIDIMENSIONAL F EMTOSECOND C ORRELATION S PECTROSCOPIES OF E LECTRONIC AND V IBRATIONAL E XCITATIONS
journal, October 2000


Raman-Induced Kerr Effect
journal, January 1976


Transient 2D IR Spectroscopy of Charge Injection in Dye-Sensitized Nanocrystalline Thin Films
journal, December 2009

  • Xiong, Wei; Laaser, Jennifer E.; Paoprasert, Peerasak
  • Journal of the American Chemical Society, Vol. 131, Issue 50
  • DOI: 10.1021/ja908479r

Exciton Superposition States in CdSe Nanocrystals Measured Using Broadband Two-Dimensional Electronic Spectroscopy
journal, January 2012

  • Turner, Daniel B.; Hassan, Yasser; Scholes, Gregory D.
  • Nano Letters, Vol. 12, Issue 2
  • DOI: 10.1021/nl2039502

Two-dimensional Fourier transform spectroscopy in the pump-probe geometry
journal, January 2007

  • DeFlores, Lauren P.; Nicodemus, Rebecca A.; Tokmakoff, Andrei
  • Optics Letters, Vol. 32, Issue 20
  • DOI: 10.1364/OL.32.002966

Two-Dimensional Electronic Spectroscopy in the Ultraviolet Wavelength Range
journal, August 2012

  • West, Brantley A.; Moran, Andrew M.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 18
  • DOI: 10.1021/jz301048n

Effect of Solvent Polarity on the Vibrational Dephasing Dynamics of the Nitrosyl Stretch in an Fe II Complex Revealed by 2D IR Spectroscopy
journal, March 2013

  • Brookes, Jennifer F.; Slenkamp, Karla M.; Lynch, Michael S.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 29
  • DOI: 10.1021/jp4005345

Two-dimensional electronic spectroscopy
journal, November 1998

  • Hybl, John D.; Albrecht, Allison W.; Gallagher Faeder, Sarah M.
  • Chemical Physics Letters, Vol. 297, Issue 3-4
  • DOI: 10.1016/S0009-2614(98)01140-3

Photosubstitution of pentaamminechlororuthenium(III) hexacyanoruthenate(II) following outer-sphere intervalence excitation
journal, April 1982

  • Vogler, Arnd; Kisslinger, Josef
  • Journal of the American Chemical Society, Vol. 104, Issue 8
  • DOI: 10.1021/ja00372a035

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