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Title: Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol

A low-temperature CH 3 OH synthesis was achieved at 120–170 °C using tertiary amine and alcohol in the presence of a Cu/ZnO/Al 2 O 3 catalyst by CO 2 hydrogenation.
Authors:
ORCiD logo [1] ;  [1] ;  [1] ;  [1] ;  [2] ;  [2] ; ORCiD logo [2] ; ORCiD logo [1]
  1. Energy Processes and Materials Division, Pacific Northwest National Laboratory, Richland, USA
  2. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, USA
Publication Date:
Grant/Contract Number:
FWP 67038
Type:
Publisher's Accepted Manuscript
Journal Name:
Catalysis Science & Technology
Additional Journal Information:
Journal Name: Catalysis Science & Technology Journal Volume: 8 Journal Issue: 19; Journal ID: ISSN 2044-4753
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1469435

Kothandaraman, Jotheeswari, Dagle, Robert A., Dagle, Vanessa Labarbier, Davidson, Stephen D., Walter, Eric D., Burton, Sarah D., Hoyt, David W., and Heldebrant, David J.. Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol. United Kingdom: N. p., Web. doi:10.1039/C8CY00997J.
Kothandaraman, Jotheeswari, Dagle, Robert A., Dagle, Vanessa Labarbier, Davidson, Stephen D., Walter, Eric D., Burton, Sarah D., Hoyt, David W., & Heldebrant, David J.. Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol. United Kingdom. doi:10.1039/C8CY00997J.
Kothandaraman, Jotheeswari, Dagle, Robert A., Dagle, Vanessa Labarbier, Davidson, Stephen D., Walter, Eric D., Burton, Sarah D., Hoyt, David W., and Heldebrant, David J.. 2018. "Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol". United Kingdom. doi:10.1039/C8CY00997J.
@article{osti_1469435,
title = {Condensed-phase low temperature heterogeneous hydrogenation of CO 2 to methanol},
author = {Kothandaraman, Jotheeswari and Dagle, Robert A. and Dagle, Vanessa Labarbier and Davidson, Stephen D. and Walter, Eric D. and Burton, Sarah D. and Hoyt, David W. and Heldebrant, David J.},
abstractNote = {A low-temperature CH 3 OH synthesis was achieved at 120–170 °C using tertiary amine and alcohol in the presence of a Cu/ZnO/Al 2 O 3 catalyst by CO 2 hydrogenation.},
doi = {10.1039/C8CY00997J},
journal = {Catalysis Science & Technology},
number = 19,
volume = 8,
place = {United Kingdom},
year = {2018},
month = {1}
}

Works referenced in this record:

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons
journal, January 2009
  • Olah, George A.; Goeppert, Alain; Prakash, G. K. Surya
  • The Journal of Organic Chemistry, Vol. 74, Issue 2, p. 487-498
  • DOI: 10.1021/jo801260f

The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012