Crystal Chemistry of RE6MgxCd23-xPb [0.6(1) ≤ x ≤ 3.2(1); RE = La and Ce]. New Mixed-Metal Derivatives of the RE6Cd23T Phases (T = Group 14/15/16 Element)

Desroches, Griffen; Ovchinnikov, Alexander; Bobev, Svilen

doi:10.1002/zaac.201800317

Title: Crystal Chemistry of RE₆Mg_xCd_23-xPb [0.6(1) ≤ x ≤ 3.2(1); RE = La and Ce]. New Mixed-Metal Derivatives of the RE₆Cd₂₃T Phases (T = Group 14/15/16 Element)

Abstract

Synthesis and crystal structure determinations are reported for six quaternary phases with the general formula RE ₆ Mg _x Cd _{23– x} Pb [ RE = La, Ce; 0.6(1) ≤ x ≤ 3.2(1)]. These compounds were prepared by high temperature reactions of the elements in sealed Nb tubes. As revealed by powder and single‐crystal X‐ray diffraction, their crystal structures are of the cubic Zr ₆ Zn ₂₃ Si system ( cF 120, Fm 3 m, Z = 4), itself an interstitially filled variant of the Th ₆ Mn ₂₃ structure type. Rather than distributing equally across the entire Cd ₂₃ sub‐structure, Mg displayed a tendency to accumulate at specific sites (most notably 4 a ); charge differences between sites within the sub‐structure, as revealed by computational methods, are the likeliest explanation.

Authors:

Desroches, Griffen ^[1]; Ovchinnikov, Alexander ^[2]; Bobev, Svilen ^[2]

Univ. of Delaware, Newark, DE (United States); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Univ. of Delaware, Newark, DE (United States)

Publication Date:: Tue Sep 11 00:00:00 EDT 2018

Research Org.:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1595054

Alternate Identifier(s):: OSTI ID: 1469407

Grant/Contract Number:: SC0008885

Resource Type:: Accepted Manuscript

Journal Name:: Zeitschrift fuer Anorganische und Allgemeine Chemie

Additional Journal Information:: Journal Volume: 644; Journal Issue: 24; Journal ID: ISSN 0044-2313

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Intermetallic phases; Solid-state structures; Electronic structure; Lanthanides; Cadmium

Citation Formats


                    Desroches, Griffen, Ovchinnikov, Alexander, and Bobev, Svilen. Crystal Chemistry of RE6MgxCd23-xPb [0.6(1) ≤ x ≤ 3.2(1); RE = La and Ce]. New Mixed-Metal Derivatives of the RE6Cd23T Phases (T = Group 14/15/16 Element).  United States: N. p., 2018. 
Web.  doi:10.1002/zaac.201800317.

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                    Desroches, Griffen, Ovchinnikov, Alexander, & Bobev, Svilen. Crystal Chemistry of RE6MgxCd23-xPb [0.6(1) ≤ x ≤ 3.2(1); RE = La and Ce]. New Mixed-Metal Derivatives of the RE6Cd23T Phases (T = Group 14/15/16 Element).  United States.  https://doi.org/10.1002/zaac.201800317

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                    Desroches, Griffen, Ovchinnikov, Alexander, and Bobev, Svilen. Tue .  
"Crystal Chemistry of RE6MgxCd23-xPb [0.6(1) ≤ x ≤ 3.2(1); RE = La and Ce]. New Mixed-Metal Derivatives of the RE6Cd23T Phases (T = Group 14/15/16 Element)".  United States.  https://doi.org/10.1002/zaac.201800317.  https://www.osti.gov/servlets/purl/1595054.

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@article{osti_1595054,

  title        = {Crystal Chemistry of RE6MgxCd23-xPb [0.6(1) ≤ x ≤ 3.2(1); RE = La and Ce]. New Mixed-Metal Derivatives of the RE6Cd23T Phases (T = Group 14/15/16 Element)},

  author       = {Desroches, Griffen and Ovchinnikov, Alexander and Bobev, Svilen},

  abstractNote = {Synthesis and crystal structure determinations are reported for six quaternary phases with the general formula RE 6 Mg x Cd 23– x Pb [ RE = La, Ce; 0.6(1) ≤ x ≤ 3.2(1)]. These compounds were prepared by high temperature reactions of the elements in sealed Nb tubes. As revealed by powder and single‐crystal X‐ray diffraction, their crystal structures are of the cubic Zr 6 Zn 23 Si system ( cF 120, Fm 3 m, Z = 4), itself an interstitially filled variant of the Th 6 Mn 23 structure type. Rather than distributing equally across the entire Cd 23 sub‐structure, Mg displayed a tendency to accumulate at specific sites (most notably 4 a ); charge differences between sites within the sub‐structure, as revealed by computational methods, are the likeliest explanation.},

  doi          = {10.1002/zaac.201800317},

  journal      = {Zeitschrift fuer Anorganische und Allgemeine Chemie},

  number       = 24,

  volume       = 644,

  place        = {United States},

  year         = {Tue Sep 11 00:00:00 EDT 2018},

  month        = {Tue Sep 11 00:00:00 EDT 2018}

}

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Citation Formats

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Title: Crystal Chemistry of RE₆Mg_xCd_23-xPb [0.6(1) ≤ x ≤ 3.2(1); RE = La and Ce]. New Mixed-Metal Derivatives of the RE₆Cd₂₃T Phases (T = Group 14/15/16 Element)

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Crystal structures and hydrogen-induced decomposition of La(Mg1−xAlx)3 alloys
journal, June 2006

Crystal structure and electronic properties of the new compounds, U6Fe16Si7 and its interstitial carbide U6Fe16Si7C
journal, October 2007

Crystal Structures and Hydrogen-Induced Decomposition of La(Mg1-xAlx)3 Alloys.
journal, September 2006