Insights into CO2 adsorption and chemical fixation properties of VPI-100 metal–organic frameworks

Zhu, Jie; Liu, Jianzhao; Machain, Yered; Bonnett, Brittany; Lin, Shaoyang; Cai, Meng; Kessinger, Matthew C.; Usov, Pavel M.; Xu, Wenqian; Senanayake, Sanjaya D.; Troya, Diego; Esker, Alan R.; Morris, Amanda J.

doi:10.1039/C8TA06383D

Title: Insights into CO₂ adsorption and chemical fixation properties of VPI-100 metal–organic frameworks

Abstract

The mechanism of CO₂utilization by a metallocyclam-based metal–organic framework catalyst, termed VPI-100, is studied.

Authors:

^[1]; Liu, Jianzhao ^[1]; Machain, Yered ^[1]; Bonnett, Brittany ^[1]; Lin, Shaoyang ^[1]; Cai, Meng ^[1]; Kessinger, Matthew C. ^[1]; Usov, Pavel M. ^[1];

^[2];

^[3];

^[1]; Esker, Alan R. ^[1];

^[1]

Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Publication Date:: Wed Aug 29 00:00:00 EDT 2018

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1493738

Alternate Identifier(s):: OSTI ID: 1469235; OSTI ID: 1498866

Report Number(s):: BNL-211361-2019-JAAM
Journal ID: ISSN 2050-7488; JMCAET; 146984

Grant/Contract Number:: AC02-06CH11357; SC0012445; SC0012704

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. A

Additional Journal Information:: Journal Volume: 6; Journal Issue: 44; Journal ID: ISSN 2050-7488

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zhu, Jie, Liu, Jianzhao, Machain, Yered, Bonnett, Brittany, Lin, Shaoyang, Cai, Meng, Kessinger, Matthew C., Usov, Pavel M., Xu, Wenqian, Senanayake, Sanjaya D., Troya, Diego, Esker, Alan R., and Morris, Amanda J. Insights into CO2 adsorption and chemical fixation properties of VPI-100 metal–organic frameworks.  United States: N. p., 2018. 
Web.  doi:10.1039/C8TA06383D.

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                    Zhu, Jie, Liu, Jianzhao, Machain, Yered, Bonnett, Brittany, Lin, Shaoyang, Cai, Meng, Kessinger, Matthew C., Usov, Pavel M., Xu, Wenqian, Senanayake, Sanjaya D., Troya, Diego, Esker, Alan R., & Morris, Amanda J. Insights into CO2 adsorption and chemical fixation properties of VPI-100 metal–organic frameworks.  United States.  https://doi.org/10.1039/C8TA06383D

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                    Zhu, Jie, Liu, Jianzhao, Machain, Yered, Bonnett, Brittany, Lin, Shaoyang, Cai, Meng, Kessinger, Matthew C., Usov, Pavel M., Xu, Wenqian, Senanayake, Sanjaya D., Troya, Diego, Esker, Alan R., and Morris, Amanda J. Wed .  
"Insights into CO2 adsorption and chemical fixation properties of VPI-100 metal–organic frameworks".  United States.  https://doi.org/10.1039/C8TA06383D.  https://www.osti.gov/servlets/purl/1493738.

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@article{osti_1493738,

  title        = {Insights into CO2 adsorption and chemical fixation properties of VPI-100 metal–organic frameworks},

  author       = {Zhu, Jie and Liu, Jianzhao and Machain, Yered and Bonnett, Brittany and Lin, Shaoyang and Cai, Meng and Kessinger, Matthew C. and Usov, Pavel M. and Xu, Wenqian and Senanayake, Sanjaya D. and Troya, Diego and Esker, Alan R. and Morris, Amanda J.},

  abstractNote = {The mechanism of CO2utilization by a metallocyclam-based metal–organic framework catalyst, termed VPI-100, is studied.},

  doi          = {10.1039/C8TA06383D},

  journal      = {Journal of Materials Chemistry. A},

  number       = 44,

  volume       = 6,

  place        = {United States},

  year         = {Wed Aug 29 00:00:00 EDT 2018},

  month        = {Wed Aug 29 00:00:00 EDT 2018}

}

Copy to clipboard

Journal Article:

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https://doi.org/10.1039/C8TA06383D

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Cited by: 16 works

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Figures / Tables:

Fig. 1: Proposed mechanism for the acid-catalysed (A) cyclic carbonate synthesis from epoxides and CO₂ in the presence of a tetraalkylammonium halide (bromide).

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Title: Insights into CO2 adsorption and chemical fixation properties of VPI-100 metal–organic frameworks

Abstract

Citation Formats

Figures / Tables:

Benzene, Toluene, and Xylene Transport through UiO-66: Diffusion Rates, Energetics, and the Role of Hydrogen Bonding journal, June 2018

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy journal, January 2005

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The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion journal, July 2017

Ionic liquid tethered post functionalized ZIF-90 framework for the cycloaddition of propylene oxide and CO 2 journal, January 2016

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Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels journal, December 2009

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Title: Insights into CO₂ adsorption and chemical fixation properties of VPI-100 metal–organic frameworks

Benzene, Toluene, and Xylene Transport through UiO-66: Diffusion Rates, Energetics, and the Role of Hydrogen Bonding
journal, June 2018

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
journal, January 2005

Warming caused by cumulative carbon emissions towards the trillionth tonne
journal, April 2009

Direct Synthesis of Hierarchically Porous Metal–Organic Frameworks with High Stability and Strong Brønsted Acidity: The Decisive Role of Hafnium in Efficient and Selective Fructose Dehydration
journal, April 2016

Interaction parameters for the uptake of sulfur mustard mimics into polyurethane films
journal, June 2017

Interpenetrating Metal–Metalloporphyrin Framework for Selective CO ₂ Uptake and Chemical Transformation of CO ₂
journal, June 2016

Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals
journal, May 2011

Adsorption and diffusion in thin films of nanoporous metal–organic frameworks: ferrocene in SURMOF Cu2(ndc)2(dabco)
journal, January 2013

Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?
journal, August 2011

Molecular approaches to the electrochemical reduction of carbon dioxide
journal, January 2012

Metal organic framework based catalysts for CO ₂ conversion
journal, January 2017

Liquid- and Gas-Phase Diffusion of Ferrocene in Thin Films of Metal-Organic Frameworks
journal, June 2015

Metal-Organic Frameworks for CO ₂ Chemical Transformations
journal, October 2016

The role of reticular chemistry in the design of CO2 reduction catalysts
journal, February 2018

Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
journal, October 2013

Metalloporphyrin-based organic polymers for carbon dioxide fixation to cyclic carbonate
journal, January 2015

A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions
journal, November 2006

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013

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journal, January 2018

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

Metal–Organic Frameworks (MOFs)
journal, January 2014

An alkaline-resistant Ag( i )-anchored pyrazolate-based metal–organic framework for chemical fixation of CO ₂
journal, January 2018

A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO₂ Fixation and Regioselective and Enantioretentive Epoxide Activation
journal, October 2014

Honeycomb Metal–Organic Framework with Lewis Acidic and Basic Bifunctional Sites: Selective Adsorption and CO ₂ Catalytic Fixation
journal, March 2018

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journal, June 2014

Structure activity relationships in metal–organic framework catalysts for the continuous flow synthesis of propylene carbonate from CO ₂ and propylene oxide
journal, January 2018

A novel method to measure diffusion coefficients in porous metal–organic frameworks
journal, January 2010

Investigation of the molecular transport of aliphatic and aromatic esters into engineering polymer membranes
journal, May 1994

A versatile sample-environment cell for non-ambient X-ray scattering experiments
journal, July 2008

Anthropogenic ocean acidification over the twenty-first century and its impact on calcifying organisms
journal, September 2005

The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
journal, July 2017

Ionic liquid tethered post functionalized ZIF-90 framework for the cycloaddition of propylene oxide and CO ₂
journal, January 2016

The surface barrier phenomenon at the loading of metal-organic frameworks
journal, July 2014

Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
journal, December 2009

Verwendung von Schwingquarzen zur W�gung d�nner Schichten und zur Mikrow�gung
journal, April 1959

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

Liquid- and Gas-Phase Diffusion of Ferrocene in Thin Films of Metal-Organic Frameworks
text, January 2015

Anthropogenic ocean acidification over the twenty-first century and its impact on calcifying organisms
text, January 2005

Metal–organic frameworks (MOFs)
journal, March 2015