Scalable slot-die coating of high performance perovskite solar cells

Whitaker, James B.; Kim, Dong Hoe; Larson, Bryon W.; Zhang, Fei; Berry, Joseph J.; van Hest, Maikel F. A. M.; Zhu, Kai

doi:10.1039/C8SE00368H

Title: Scalable slot-die coating of high performance perovskite solar cells

Journal Article · 03 August 2018 · Sustainable Energy & Fuels

DOI: https://doi.org/10.1039/C8SE00368H · OSTI ID:1468738

Whitaker, James B. ^[1]; Kim, Dong Hoe ^[1]; Larson, Bryon W. ^[1];

^[1];

^[1]; van Hest, Maikel F. A. M. ^[1];

^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)

Perovskite based photovoltaic devices hold the promise to greatly reduce the cost of solar energy production; however, this potential depends greatly on the ability to deposit perovskite active layers using large scale deposition methods such as slot-die coating without sacrificing efficiency. Using a perovskite precursor ink with long wet-film processing window, we demonstrate efficient perovskite solar cells based on slot-die coated perovskite layer. We found almost no difference in the photophysical and structural details of perovskite films that were deposited by spin coating to films deposited by slot-die coating. Furthermore, we explored various slot-die coating parameters to determine their effect on the performance of the device metrics. In addition to slot-die coating, we demonstrate the versatility of this wide wet-film processing window by fabricating perovskite solar cells with active layers deposited by spin coating, blade coating, and spray coating that all exhibited similar performance.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE National Renewable Energy Laboratory (NREL), Laboratory Directed Research and Development (LDRD) Program; USDOE

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1468738

Alternate ID(s):: OSTI ID: 1464568

Report Number(s):: NREL/JA-5900-71764; SEFUA7

Journal Information:: Sustainable Energy & Fuels, Vol. 2; ISSN 2398-4902

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 134 works

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Humidity‐Tolerant Roll‐to‐Roll Fabrication of Perovskite Solar Cells via Polymer‐Additive‐Assisted Hot Slot Die Deposition Kim, Jueng‐Eun; Kim, Seok‐Soon; Zuo, Chuantian Advanced Functional Materials, Vol. 29, Issue 26 https://doi.org/10.1002/adfm.201809194	journal	March 2019
Coated and Printed Perovskites for Photovoltaic Applications Howard, Ian A.; Abzieher, Tobias; Hossain, Ihteaz M. Advanced Materials, Vol. 31, Issue 26 https://doi.org/10.1002/adma.201806702	journal	April 2019
Drying Dynamics of Solution‐Processed Perovskite Thin‐Film Photovoltaics: In Situ Characterization, Modeling, and Process Control Ternes, Simon; Börnhorst, Tobias; Schwenzer, Jonas A. Advanced Energy Materials, Vol. 9, Issue 39 https://doi.org/10.1002/aenm.201901581	journal	August 2019
Inkjet‐Printed Micrometer‐Thick Perovskite Solar Cells with Large Columnar Grains Eggers, Helge; Schackmar, Fabian; Abzieher, Tobias Advanced Energy Materials, Vol. 10, Issue 6 https://doi.org/10.1002/aenm.201903184	journal	December 2019
Scalable Deposition Methods for Large‐area Production of Perovskite Thin Films Swartwout, Richard; Hoerantner, Maximilian T.; Bulović, V. ENERGY & ENVIRONMENTAL MATERIALS, Vol. 2, Issue 2 https://doi.org/10.1002/eem2.12043	journal	June 2019
Acetonitrile based single step slot-die compatible perovskite ink for flexible photovoltaics Burkitt, Daniel; Swartwout, Richard; McGettrick, James RSC Advances, Vol. 9, Issue 64 https://doi.org/10.1039/c9ra06631d	journal	January 2019
Recent progress towards roll-to-roll manufacturing of perovskite solar cells using slot-die processing Li, Hengyue; Zuo, Chuantian; Scully, Andrew D. Flexible and Printed Electronics, Vol. 5, Issue 1 https://doi.org/10.1088/2058-8585/ab639e	journal	January 2020
Meniscus fabrication of halide perovskite thin films at high throughput for large area and low-cost solar panels Dai, Xuezeng; Deng, Yehao; Van Brackle, Charles H. International Journal of Extreme Manufacturing, Vol. 1, Issue 2 https://doi.org/10.1088/2631-7990/ab263e	journal	June 2019
Editors' Choice—Stability of Unstable Perovskites: Recent Strategies for Making Stable Perovskite Solar Cells Mali, Sawanta S.; Patil, Jyoti V.; Arandiyan, Hamidreza ECS Journal of Solid State Science and Technology, Vol. 8, Issue 6 https://doi.org/10.1149/2.0201906jss	journal	January 2019
Coated and Printed Perovskites for Photovoltaic Applications Howard, Ian A.; Abzieher, Tobias; Hossain, Ihteaz M. Wiley https://doi.org/10.5445/ir/1000093372	text	January 2019
Inkjet‐Printed Micrometer‐Thick Perovskite Solar Cells with Large Columnar Grains Eggers, Helge; Schackmar, Fabian; Abzieher, Tobias Wiley-VCH Verlag https://doi.org/10.5445/ir/1000105473	text	January 2020
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14 SOLAR ENERGY
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