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Title: Mn III -Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity

The new tetradentate L 7 BQ ligand (L 7 BQ = 1,4-di(quinoline-8-yl)-1,4-diazepane) has been synthesized and shown to support Mn II and Mn III -peroxo complexes.
Authors:
 [1] ; ORCiD logo [1] ;  [1] ;  [1] ;  [1] ; ORCiD logo [1]
  1. The University of Kansas, Department of Chemistry and Center for Environmentally Beneficial Catalysis, Lawrence, USA
Publication Date:
Grant/Contract Number:
AC02-76SF00515
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 38; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1468666

Denler, Melissa C., Wijeratne, Gayan B., Rice, Derek B., Colmer, Hannah E., Day, Victor W., and Jackson, Timothy A.. Mn III -Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity. United Kingdom: N. p., Web. doi:10.1039/C8DT02300J.
Denler, Melissa C., Wijeratne, Gayan B., Rice, Derek B., Colmer, Hannah E., Day, Victor W., & Jackson, Timothy A.. Mn III -Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity. United Kingdom. doi:10.1039/C8DT02300J.
Denler, Melissa C., Wijeratne, Gayan B., Rice, Derek B., Colmer, Hannah E., Day, Victor W., and Jackson, Timothy A.. 2018. "Mn III -Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity". United Kingdom. doi:10.1039/C8DT02300J.
@article{osti_1468666,
title = {Mn III -Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity},
author = {Denler, Melissa C. and Wijeratne, Gayan B. and Rice, Derek B. and Colmer, Hannah E. and Day, Victor W. and Jackson, Timothy A.},
abstractNote = {The new tetradentate L 7 BQ ligand (L 7 BQ = 1,4-di(quinoline-8-yl)-1,4-diazepane) has been synthesized and shown to support Mn II and Mn III -peroxo complexes.},
doi = {10.1039/C8DT02300J},
journal = {Dalton Transactions},
number = 38,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}

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