Defect-engineered epitaxial VO 2±δ in strain engineering of heterogeneous soft crystals
Abstract
The success of strain engineering has made a step further for the enhancement of material properties and the introduction of new physics, especially with the discovery of the critical roles of strain in the heterogeneous interface between two dissimilar materials (for example, FeSe/SrTiO3). On the other hand, the strain manipulation has been limited to chemical epitaxy and nanocomposites that, to a large extent, limit the possible material systems that can be explored. By defect engineering, we obtained, for the first time, dense three-dimensional strongly correlated VO2±$$\delta$$ epitaxial nanoforest arrays that can be used as a novel "substrate" for dynamic strain engineering, due to its metal-insulator transition. The highly dense nanoforest is promising for the possible realization of bulk strain similar to the effect of nanocomposites. By growing single-crystalline halide perovskite CsPbBr3, a mechanically soft and emerging semiconducting material, onto the VO2±$$\delta$$, a heterogeneous interface is created that can entail a ~1% strain transfer upon the metal-insulator transition of VO2±$$\delta$$. This strain is large enough to trigger a structural phase transition featured by PbX6 octahedral tilting along with a modification of the photoluminescence energy landscape in halide perovskite. Our findings suggest a promising strategy of dynamic strain engineering in a heterogeneous interface carrying soft and strain-sensitive semiconductors that can happen at a larger volumetric value surpassing the conventional critical thickness limit.
- Authors:
-
- Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Materials Science and Engineering
- Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Physics, Applied Physics, and Astronomy
- Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- Rensselaer Polytechnic Institute; Air Force Research Laboratory (AFRL). Air Force Office of Scientific Research (AFOSR); National Science Foundation (NSF); USDOE
- OSTI Identifier:
- 1468627
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 5; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Wang, Yiping, Sun, Xin, Chen, Zhizhong, Cai, Zhonghou, Zhou, Hua, Lu, Toh-Ming, and Shi, Jian. Defect-engineered epitaxial VO 2±δ in strain engineering of heterogeneous soft crystals. United States: N. p., 2018.
Web. doi:10.1126/sciadv.aar3679.
Wang, Yiping, Sun, Xin, Chen, Zhizhong, Cai, Zhonghou, Zhou, Hua, Lu, Toh-Ming, & Shi, Jian. Defect-engineered epitaxial VO 2±δ in strain engineering of heterogeneous soft crystals. United States. https://doi.org/10.1126/sciadv.aar3679
Wang, Yiping, Sun, Xin, Chen, Zhizhong, Cai, Zhonghou, Zhou, Hua, Lu, Toh-Ming, and Shi, Jian. Tue .
"Defect-engineered epitaxial VO 2±δ in strain engineering of heterogeneous soft crystals". United States. https://doi.org/10.1126/sciadv.aar3679. https://www.osti.gov/servlets/purl/1468627.
@article{osti_1468627,
title = {Defect-engineered epitaxial VO 2±δ in strain engineering of heterogeneous soft crystals},
author = {Wang, Yiping and Sun, Xin and Chen, Zhizhong and Cai, Zhonghou and Zhou, Hua and Lu, Toh-Ming and Shi, Jian},
abstractNote = {The success of strain engineering has made a step further for the enhancement of material properties and the introduction of new physics, especially with the discovery of the critical roles of strain in the heterogeneous interface between two dissimilar materials (for example, FeSe/SrTiO3). On the other hand, the strain manipulation has been limited to chemical epitaxy and nanocomposites that, to a large extent, limit the possible material systems that can be explored. By defect engineering, we obtained, for the first time, dense three-dimensional strongly correlated VO2±$\delta$ epitaxial nanoforest arrays that can be used as a novel "substrate" for dynamic strain engineering, due to its metal-insulator transition. The highly dense nanoforest is promising for the possible realization of bulk strain similar to the effect of nanocomposites. By growing single-crystalline halide perovskite CsPbBr3, a mechanically soft and emerging semiconducting material, onto the VO2±$\delta$, a heterogeneous interface is created that can entail a ~1% strain transfer upon the metal-insulator transition of VO2±$\delta$. This strain is large enough to trigger a structural phase transition featured by PbX6 octahedral tilting along with a modification of the photoluminescence energy landscape in halide perovskite. Our findings suggest a promising strategy of dynamic strain engineering in a heterogeneous interface carrying soft and strain-sensitive semiconductors that can happen at a larger volumetric value surpassing the conventional critical thickness limit.},
doi = {10.1126/sciadv.aar3679},
journal = {Science Advances},
number = 5,
volume = 4,
place = {United States},
year = {Tue May 01 00:00:00 EDT 2018},
month = {Tue May 01 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Mechanical properties of thin films
journal, November 1989
- Nix, William D.
- Metallurgical Transactions A, Vol. 20, Issue 11
“Stretching” the energy landscape of oxides—Effects on electrocatalysis and diffusion
journal, February 2014
- Yildiz, Bilge
- MRS Bulletin, Vol. 39, Issue 2
Strain control and spontaneous phase ordering in vertical nanocomposite heteroepitaxial thin films
journal, March 2008
- MacManus-Driscoll, Judith L.; Zerrer, Patrick; Wang, Haiyan
- Nature Materials, Vol. 7, Issue 4
A strong ferroelectric ferromagnet created by means of spin–lattice coupling
journal, July 2011
- Lee, June Hyuk; Fang, Lei; Vlahos, Eftihia
- Nature, Vol. 476, Issue 7358
Interface-induced superconductivity and strain-dependent spin density waves in FeSe/SrTiO3 thin films
journal, May 2013
- Tan, Shiyong; Zhang, Yan; Xia, Miao
- Nature Materials, Vol. 12, Issue 7
Direct Observation of Nanoscale Peltier and Joule Effects at Metal–Insulator Domain Walls in Vanadium Dioxide Nanobeams
journal, April 2014
- Favaloro, Tela; Suh, Joonki; Vermeersch, Bjorn
- Nano Letters, Vol. 14, Issue 5
Strain scaling for CMOS
journal, February 2014
- Bedell, S. W.; Khakifirooz, A.; Sadana, D. K.
- MRS Bulletin, Vol. 39, Issue 2
High-Temperature Ionic Epitaxy of Halide Perovskite Thin Film and the Hidden Carrier Dynamics
journal, July 2017
- Wang, Yiping; Sun, Xin; Chen, Zhizhong
- Advanced Materials, Vol. 29, Issue 35
Mechanical Properties of Thin Films
journal, August 1990
- Alexopoulos, P. S.; O'Sullivan, T. C.
- Annual Review of Materials Science, Vol. 20, Issue 1
Stress-induced domain dynamics and phase transitions in epitaxially grown VO 2 nanowires
journal, April 2012
- Sohn, Jung Inn; Joo, Heung Jin; Kim, Keun Soo
- Nanotechnology, Vol. 23, Issue 20
Single-Crystal Thin Films of Cesium Lead Bromide Perovskite Epitaxially Grown on Metal Oxide Perovskite (SrTiO 3 )
journal, September 2017
- Chen, Jie; Morrow, Darien J.; Fu, Yongping
- Journal of the American Chemical Society, Vol. 139, Issue 38
Elastic strain engineering for unprecedented materials properties
journal, February 2014
- Li, Ju; Shan, Zhiwei; Ma, Evan
- MRS Bulletin, Vol. 39, Issue 2
The emergence of perovskite solar cells
journal, July 2014
- Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
- Nature Photonics, Vol. 8, Issue 7, p. 506-514
Strained-Layer Quantum-Well Lasers
journal, September 2011
- Adams, Alfred R.
- IEEE Journal of Selected Topics in Quantum Electronics, Vol. 17, Issue 5
A Transforming Metal Nanocomposite with Large Elastic Strain, Low Modulus, and High Strength
journal, March 2013
- Hao, Shijie; Cui, Lishan; Jiang, Daqiang
- Science, Vol. 339, Issue 6124, p. 1191-1194
Superconductivity above 100 K in single-layer FeSe films on doped SrTiO3
journal, November 2014
- Ge, Jian-Feng; Liu, Zhi-Long; Liu, Canhua
- Nature Materials, Vol. 14, Issue 3
Axially Engineered Metal–Insulator Phase Transition by Graded Doping VO 2 Nanowires
journal, March 2013
- Lee, Sangwook; Cheng, Chun; Guo, Hua
- Journal of the American Chemical Society, Vol. 135, Issue 12
Unusual M 2 -mediated metal-insulator transition in epitaxial VO 2 thin films on GaN substrates
journal, January 2015
- Yang, Hyoung Woo; Sohn, Jung Inn; Yang, Jae Hoon
- EPL (Europhysics Letters), Vol. 109, Issue 2
Photon Transport in One-Dimensional Incommensurately Epitaxial CsPbX 3 Arrays
journal, November 2016
- Wang, Yiping; Sun, Xin; Shivanna, Ravichandran
- Nano Letters, Vol. 16, Issue 12
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors
journal, April 2015
- Zhu, Haiming; Fu, Yongping; Meng, Fei
- Nature Materials, Vol. 14, Issue 6
Optical switching of au-doped VO2 sol-gel films
journal, January 1999
- Cavanna, E.; Segaud, J. P.; Livage, J.
- Materials Research Bulletin, Vol. 34, Issue 2
High-Pressure Single-Crystal Structures of 3D Lead-Halide Hybrid Perovskites and Pressure Effects on their Electronic and Optical Properties
journal, April 2016
- Jaffe, Adam; Lin, Yu; Beavers, Christine M.
- ACS Central Science, Vol. 2, Issue 4
An analysis of the residual strains in epitaxial tin films
journal, June 1969
- Vincent, R.
- Philosophical Magazine, Vol. 19, Issue 162
Electric Field- and Strain-Induced Rashba Effect in Hybrid Halide Perovskites
journal, September 2016
- Leppert, Linn; Reyes-Lillo, Sebastian E.; Neaton, Jeffrey B.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 18
Bright light-emitting diodes based on organometal halide perovskite
journal, August 2014
- Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling
- Nature Nanotechnology, Vol. 9, Issue 9
Ambipolar solution-processed hybrid perovskite phototransistors
journal, September 2015
- Li, Feng; Ma, Chun; Wang, Hong
- Nature Communications, Vol. 6, Issue 1
Halide Perovskites under Pressure: Accessing New Properties through Lattice Compression
journal, June 2017
- Jaffe, Adam; Lin, Yu; Karunadasa, Hemamala I.
- ACS Energy Letters, Vol. 2, Issue 7
Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals
journal, March 2016
- Wei, Haotong; Fang, Yanjun; Mulligan, Padhraic
- Nature Photonics, Vol. 10, Issue 5
Mechanical properties of A Pb X 3 ( A = Cs or CH 3 NH 3 ; X = I or Br) perovskite single crystals
journal, October 2015
- Rakita, Yevgeny; Cohen, Sidney R.; Kedem, Nir Klein
- MRS Communications, Vol. 5, Issue 4
Role of scaffold network in controlling strain and functionalities of nanocomposite films
journal, June 2016
- Chen, Aiping; Hu, Jia-Mian; Lu, Ping
- Science Advances, Vol. 2, Issue 6
Epitaxial Strain and Superconductivity in Thin Films
journal, August 2002
- Bozovic, I.; Logvenov, G.; Belca, I.
- Physical Review Letters, Vol. 89, Issue 10
Band structure engineering of semiconductor lasers for optical communications
journal, August 1988
- Yablonovitch, E.; Kane, E. O.
- Journal of Lightwave Technology, Vol. 6, Issue 8
Accurate X-ray determination of the lattice parameters and the thermal expansion coefficients of VO 2 near the transition temperature
journal, August 1979
- Kucharczyk, D.; Niklewski, T.
- Journal of Applied Crystallography, Vol. 12, Issue 4
Structure and Metal-to-Insulator Transition of VO2 Nanowires Grown on Sapphire Substrates
journal, August 2010
- Cheng, Yao; Zhang, Ting; Cai, Yuan
- European Journal of Inorganic Chemistry, Vol. 2010, Issue 27
Growth of Metal Oxide Nanowires from Supercooled Liquid Nanodroplets
journal, December 2009
- Kim, Myung Hwa; Lee, Byeongdu; Lee, Sungsik
- Nano Letters, Vol. 9, Issue 12
Theoretical analysis of the vapor-liquid-solid mechanism of nanowire growth during molecular beam epitaxy
journal, February 2006
- Dubrovskii, V. G.; Sibirev, N. V.; Cirlin, G. E.
- Physical Review E, Vol. 73, Issue 2
Metal-insulator transitions
journal, June 1991
- Paesler, Michael
- Journal of Non-Crystalline Solids, Vol. 130, Issue 1
Strain and temperature dependence of the insulating phases of VO near the metal-insulator transition
journal, January 2012
- Atkin, Joanna M.; Berweger, Samuel; Chavez, Emily K.
- Physical Review B, Vol. 85, Issue 2
Strain Tuning of Tin–Halide and Lead–Halide Perovskites: A First-Principles Atomic and Electronic Structure Study
journal, September 2015
- Grote, Christopher; Berger, Robert F.
- The Journal of Physical Chemistry C, Vol. 119, Issue 40
Vanadium oxide nanowire phase and orientation analyzed by Raman spectroscopy
journal, February 2009
- Chou, J. Y.; Lensch-Falk, J. L.; Hemesath, E. R.
- Journal of Applied Physics, Vol. 105, Issue 3
Correlation between stoichiometry, strain, and metal-insulator transitions of NdNiO 3 films
journal, March 2015
- Hauser, Adam J.; Mikheev, Evgeny; Moreno, Nelson E.
- Applied Physics Letters, Vol. 106, Issue 9
Single-Crystalline Vanadium Dioxide Nanowires with Rectangular Cross Sections
journal, January 2005
- Guiton, Beth S.; Gu, Qian; Prieto, Amy L.
- Journal of the American Chemical Society, Vol. 127, Issue 2
Strain-Induced Ferroelectric Topological Insulator
journal, February 2016
- Liu, Shi; Kim, Youngkuk; Tan, Liang Z.
- Nano Letters, Vol. 16, Issue 3
Monolithic integration of hybrid perovskite single crystals with heterogenous substrate for highly sensitive X-ray imaging
journal, April 2017
- Wei, Wei; Zhang, Yang; Xu, Qiang
- Nature Photonics, Vol. 11, Issue 5
Metal-insulator transitions
journal, October 1998
- Imada, Masatoshi; Fujimori, Atsushi; Tokura, Yoshinori
- Reviews of Modern Physics, Vol. 70, Issue 4, p. 1039-1263
High mobility strained germanium quantum well field effect transistor as the p-channel device option for low power (Vcc = 0.5 V) III–V CMOS architecture
conference, December 2010
- Pillarisetty, R.; Chu-Kung, B.; Corcoran, S.
- 2010 IEEE International Electron Devices Meeting (IEDM), 2010 International Electron Devices Meeting
Metal-insulator transitions in VO 2 , Ti 2 O 3 and Ti 2- x V x O 3
journal, August 1974
- Mott, N. F.; Friedman, L.
- Philosophical Magazine, Vol. 30, Issue 2
Red-to-Black Piezochromism in a Compressible Pb–I–SCN Layered Perovskite
journal, May 2016
- Umeyama, Daiki; Lin, Yu; Karunadasa, Hemamala I.
- Chemistry of Materials, Vol. 28, Issue 10
A strong ferroelectric ferromagnet created by means of spin–lattice coupling
journal, August 2010
- Lee, June Hyuk; Fang, Lei; Vlahos, Eftihia
- Nature, Vol. 466, Issue 7309
Tuning the band structure and superconductivity in single-layer FeSe by interface engineering
journal, September 2014
- Peng, R.; Xu, H. C.; Tan, S. Y.
- Nature Communications, Vol. 5, Issue 1
Dimerization of a linear Heisenberg chain in the insulating phases of
journal, September 1974
- Pouget, J. P.; Launois, H.; Rice, T. M.
- Physical Review B, Vol. 10, Issue 5
Measurement of a solid-state triple point at the metal–insulator transition in VO2
journal, August 2013
- Park, Jae Hyung; Coy, Jim M.; Kasirga, T. Serkan
- Nature, Vol. 500, Issue 7463
Towards stable and commercially available perovskite solar cells
journal, October 2016
- Park, Nam-Gyu; Grätzel, Michael; Miyasaka, Tsutomu
- Nature Energy, Vol. 1, Issue 11
The nature of photoinduced phase transition and metastable states in vanadium dioxide
journal, December 2016
- Tao, Zhensheng; Zhou, Faran; Han, Tzong-Ru T.
- Scientific Reports, Vol. 6, Issue 1
Two-Dimensional van der Waals Epitaxy Kinetics in a Three-Dimensional Perovskite Halide
journal, August 2015
- Wang, Yiping; Shi, Yunfeng; Xin, Guoqing
- Crystal Growth & Design, Vol. 15, Issue 10
The study of epitaxy in thin surface films
journal, April 1956
- Pashley, D. W.
- Advances in Physics, Vol. 5, Issue 18
Strain Tuning of Ferroelectric Thin Films
journal, August 2007
- Schlom, Darrell G.; Chen, Long-Qing; Eom, Chang-Beom
- Annual Review of Materials Research, Vol. 37, Issue 1
Mechanics of Ultra-Strength Materials
journal, March 2009
- Zhu, Ting; Li, Ju; Ogata, Shigenobu
- MRS Bulletin, Vol. 34, Issue 3
Measurement of a solid-state triple point at the metal-insulator transition in VO2
text, January 2013
- Park, Jae Hyung; Coy, Jim M.; Kasirga, T. Serkan
- arXiv
Ambipolar Solution-processed Hybrid Perovskite Phototransistors
text, January 2015
- Li, Feng; Ma, Chun; Wang, Hong
- arXiv
Two-Dimensional Van der Waals Epitaxy Kinetics in a Three-Dimensional Perovskite Halide
text, January 2015
- Wang, Yiping; Shi, Yunfeng; Xin, Guoqing
- arXiv
Works referencing / citing this record:
Thickness effects on the epitaxial strain states and phase transformations in (001)-VO 2 /TiO 2 thin films
journal, February 2019
- Yang, Yuanjun; Mao, Xiaoli; Yao, Yingxue
- Journal of Applied Physics, Vol. 125, Issue 8
Epitaxial Liftoff of Wafer‐Scale VO 2 Nanomembranes for Flexible, Ultrasensitive Tactile Sensors
journal, April 2019
- Li, Xingxing; Yin, Zhigang; Zhang, Xingwang
- Advanced Materials Technologies, Vol. 4, Issue 7
Recent advances in fabrication strategies, phase transition modulation, and advanced applications of vanadium dioxide
journal, March 2019
- Shi, Run; Shen, Nan; Wang, Jingwei
- Applied Physics Reviews, Vol. 6, Issue 1
Gate-controlled VO 2 phase transition for high-performance smart windows
journal, March 2019
- Chen, Shi; Wang, Zhaowu; Ren, Hui
- Science Advances, Vol. 5, Issue 3
Gate-Controlled VO2 Phase Transition for High-Performance Smart Window
text, January 2018
- Chen, Shi; Wang, Zhaowu; Ren, Hui
- arXiv