skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice

Abstract

Results of magnetization and neutron diffraction measurements of the manganese vanadate system Mn5(VO4)2(OH)4 are reported. The crystal structure of this compound contains triangular [Mn3O13] building blocks that produce two-dimensional Mn2+ magnetic networks with striped triangular topologies. The Mn sheets are connected through the nonmagnetic vanadate tetrahedra extending along the a-axis. Magnetization measurements performed on single crystals reveal the onset of a long-range antiferromagnetic order below approximately 45 K. The magnetic structure is Néel-type with nearest-neighbor Mn atoms coupled via three or four antiferromagnetic bonds. The magnetic moments are confined within the layers and are oriented parallel to the b direction. In conclusion, the magnitudes of ordered moments are reduced, presumably by geometrical frustration and the low-dimensionality of the lattice structure.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [1]; ORCiD logo [1];  [4]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Division
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Clemson Univ., SC (United States). Dept. of Chemistry and Center for Optical Materials Science and Engineering Technologies (COMSET)
  4. Clemson Univ., SC (United States). Dept. of Chemistry and Center for Optical Materials Science and Engineering Technologies (COMSET)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1468015
Alternate Identifier(s):
OSTI ID: 1467766
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 8; Journal Issue: 10; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Garlea, Vasile O., McGuire, Michael A., Sanjeewa, Liurukara D., Pajerowski, Daniel M., Ye, Feng, and Kolis, Joseph W. The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice. United States: N. p., 2018. Web. doi:10.1063/1.5043124.
Garlea, Vasile O., McGuire, Michael A., Sanjeewa, Liurukara D., Pajerowski, Daniel M., Ye, Feng, & Kolis, Joseph W. The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice. United States. doi:https://doi.org/10.1063/1.5043124
Garlea, Vasile O., McGuire, Michael A., Sanjeewa, Liurukara D., Pajerowski, Daniel M., Ye, Feng, and Kolis, Joseph W. Thu . "The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice". United States. doi:https://doi.org/10.1063/1.5043124. https://www.osti.gov/servlets/purl/1468015.
@article{osti_1468015,
title = {The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice},
author = {Garlea, Vasile O. and McGuire, Michael A. and Sanjeewa, Liurukara D. and Pajerowski, Daniel M. and Ye, Feng and Kolis, Joseph W.},
abstractNote = {Results of magnetization and neutron diffraction measurements of the manganese vanadate system Mn5(VO4)2(OH)4 are reported. The crystal structure of this compound contains triangular [Mn3O13] building blocks that produce two-dimensional Mn2+ magnetic networks with striped triangular topologies. The Mn sheets are connected through the nonmagnetic vanadate tetrahedra extending along the a-axis. Magnetization measurements performed on single crystals reveal the onset of a long-range antiferromagnetic order below approximately 45 K. The magnetic structure is Néel-type with nearest-neighbor Mn atoms coupled via three or four antiferromagnetic bonds. The magnetic moments are confined within the layers and are oriented parallel to the b direction. In conclusion, the magnitudes of ordered moments are reduced, presumably by geometrical frustration and the low-dimensionality of the lattice structure.},
doi = {10.1063/1.5043124},
journal = {AIP Advances},
number = 10,
volume = 8,
place = {United States},
year = {2018},
month = {8}
}

Works referenced in this record:

An investigation of the quantum J 1 - J 2 - J 3 model on the honeycomb lattice
journal, March 2001

  • Fouet, J. B.; Sindzingre, P.; Lhuillier, C.
  • The European Physical Journal B, Vol. 20, Issue 2
  • DOI: 10.1007/s100510170273

Implementation of cross correlation for energy discrimination on the time-of-flight spectrometer CORELLI
journal, March 2018


Expanding Lorentz and spectrum corrections to large volumes of reciprocal space for single-crystal time-of-flight neutron diffraction
journal, March 2016

  • Michels-Clark, Tara M.; Savici, Andrei T.; Lynch, Vickie E.
  • Journal of Applied Crystallography, Vol. 49, Issue 2
  • DOI: 10.1107/s1600576716001369

Honeycomb-like S = 5/2 Spin–Lattices in Manganese(II) Vanadates
journal, August 2016


A frustrated ferrimagnet Cu 5 (VO4) 2 (OH) 4 with a 1/5 magnetization plateau on a new spin-lattice of alternating triangular and honeycomb strips
journal, January 2015

  • Zhang, Su-Yun; Guo, Wen-Bin; Yang, Ming
  • Dalton Transactions, Vol. 44, Issue 47
  • DOI: 10.1039/c5dt03534a

Review / Synthèse : Triangular antiferromagnets
journal, September 1997

  • Collins, M. F.; Petrenko, O. A.
  • Canadian Journal of Physics, Vol. 75, Issue 9
  • DOI: 10.1139/p97-007

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993


Non-simple magnetic order for simple Hamiltonians
journal, July 1979


Successive spin-flop transitions of a Néel-type antiferromagnet Li 2 MnO 3 single crystal with a honeycomb lattice
journal, September 2014


Magnetization and universal sub-critical behaviour in two-dimensional XY magnets
journal, January 1993


Unusual ordered phases of highly frustrated magnets: a review
journal, April 2015


    Works referencing / citing this record:

    Single crystal neutron and magnetic measurements of Rb 2 Mn 3 (VO 4 ) 2 CO 3 and K 2 Co 3 (VO 4 ) 2 CO 3 with mixed honeycomb and triangular magnetic lattices
    journal, January 2020

    • Smith Pellizzeri, Tiffany M.; Sanjeewa, Liurukara D.; Pellizzeri, Steven
    • Dalton Transactions, Vol. 49, Issue 14
    • DOI: 10.1039/c9dt03389k