A series of dithiocarbamates for americium, curium, and californium
Abstract
Here, characterizing how actinide properties change across the f-element series is critical for improving predictive capabilities and solving many nuclear problems facing our society. Unfortunately, it is difficult to make direct comparisons across the 5f-element series because so little is known about trans-plutonium elements. Results described herein help to address this issue through isolation of An(S2CNEt2)3(N2C12H8) (Am, Cm, and Cf). These findings included the first single crystal X-ray diffraction measurements of Cm–S (mean of 2.86 ± 0.04 Å) and Cf–S (mean of 2.84 ± 0.04 Å) bond distances. Furthermore, they highlight the potential of An(S2CNEt2)3(N2C12H8) for providing a test bed for comparative analyses of actinide versus lanthanide bonding interactions.
- Authors:
-
[1];
[1];
[2];
[1];
[1];
[1];
[1];
[1];
[1]
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Florida State Univ., Tallahassee, FL (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1480028
- Alternate Identifier(s):
- OSTI ID: 1467932
- Report Number(s):
- LA-UR-18-22699
Journal ID: ISSN 1477-9226; ICHBD9
- Grant/Contract Number:
- AC52-06NA25396; FG02-13ER16414; SC0016568; NA
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Volume: 47; Journal Issue: 41; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Cary, Samantha K., Su, Jing, Galley, Shane S., Albrecht-Schmitt, Thomas E., Batista, Enrique Ricardo, Ferrier, Maryline Ghislaine, Kozimor, Stosh Anthony, Mocko, Veronika, Scott, Brian Lindley, Van Alstine, Cayla E., White, Frankie D., and Yang, Ping. A series of dithiocarbamates for americium, curium, and californium. United States: N. p., 2018.
Web. doi:10.1039/C8DT02658K.
Cary, Samantha K., Su, Jing, Galley, Shane S., Albrecht-Schmitt, Thomas E., Batista, Enrique Ricardo, Ferrier, Maryline Ghislaine, Kozimor, Stosh Anthony, Mocko, Veronika, Scott, Brian Lindley, Van Alstine, Cayla E., White, Frankie D., & Yang, Ping. A series of dithiocarbamates for americium, curium, and californium. United States. https://doi.org/10.1039/C8DT02658K
Cary, Samantha K., Su, Jing, Galley, Shane S., Albrecht-Schmitt, Thomas E., Batista, Enrique Ricardo, Ferrier, Maryline Ghislaine, Kozimor, Stosh Anthony, Mocko, Veronika, Scott, Brian Lindley, Van Alstine, Cayla E., White, Frankie D., and Yang, Ping. Fri .
"A series of dithiocarbamates for americium, curium, and californium". United States. https://doi.org/10.1039/C8DT02658K. https://www.osti.gov/servlets/purl/1480028.
@article{osti_1480028,
title = {A series of dithiocarbamates for americium, curium, and californium},
author = {Cary, Samantha K. and Su, Jing and Galley, Shane S. and Albrecht-Schmitt, Thomas E. and Batista, Enrique Ricardo and Ferrier, Maryline Ghislaine and Kozimor, Stosh Anthony and Mocko, Veronika and Scott, Brian Lindley and Van Alstine, Cayla E. and White, Frankie D. and Yang, Ping},
abstractNote = {Here, characterizing how actinide properties change across the f-element series is critical for improving predictive capabilities and solving many nuclear problems facing our society. Unfortunately, it is difficult to make direct comparisons across the 5f-element series because so little is known about trans-plutonium elements. Results described herein help to address this issue through isolation of An(S2CNEt2)3(N2C12H8) (Am, Cm, and Cf). These findings included the first single crystal X-ray diffraction measurements of Cm–S (mean of 2.86 ± 0.04 Å) and Cf–S (mean of 2.84 ± 0.04 Å) bond distances. Furthermore, they highlight the potential of An(S2CNEt2)3(N2C12H8) for providing a test bed for comparative analyses of actinide versus lanthanide bonding interactions.},
doi = {10.1039/C8DT02658K},
journal = {Dalton Transactions},
number = 41,
volume = 47,
place = {United States},
year = {Fri Aug 31 00:00:00 EDT 2018},
month = {Fri Aug 31 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 31 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Syntheses, Structures, and Spectroscopic Properties of Plutonium and Americium Phosphites and the Redetermination of the Ionic Radii of Pu(III) and Am(III)
journal, July 2012
- Cross, Justin N.; Villa, Eric M.; Wang, Shuao
- Inorganic Chemistry, Vol. 51, Issue 15
Comparison of the solution chemistry of the actinides and lanthanides
journal, September 1983
- Choppin, Gregory R.
- Journal of the Less Common Metals, Vol. 93, Issue 2
UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations
journal, December 1992
- Rappe, A. K.; Casewit, C. J.; Colwell, K. S.
- Journal of the American Chemical Society, Vol. 114, Issue 25, p. 10024-10035
Synthesis and Magnetic Properties of Gd Doped EuS Nanocrystals with Enhanced Curie Temperatures
journal, November 2010
- Selinsky, Rachel S.; Han, Jae Hyo; Morales Pérez, Elvin A.
- Journal of the American Chemical Society, Vol. 132, Issue 45
The absorption spectrum of aqueous curium (III)
journal, June 1958
- Carnall, W. T.; Fields, P. R.; Stewart, D. C.
- Journal of Inorganic and Nuclear Chemistry, Vol. 6, Issue 3
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Tris( N -benzyl- N -methyldithiocarbamato-κ 2 S , S ′)(1,10-phenanthroline-κ 2 N , N ′)europium(III)
journal, October 2009
- Baba, Ibrahim; Raya, Indah; Yamin, Bohari M.
- Acta Crystallographica Section E Structure Reports Online, Vol. 65, Issue 11
Lanthanide( iii ) morpholine 4-dithiocarbamate complexes: Pr( iii ) derivative shows first example of polymeric lanthanide( iii ) dithiocarbamate
journal, January 2015
- Mahato, Mamata; Jana, Partha P.; Harms, Klaus
- RSC Advances, Vol. 5, Issue 76
Advancing Understanding of the +4 Metal Extractant Thenoyltrifluoroacetonate (TTA – ); Synthesis and Structure of M IV TTA 4 (M IV = Zr, Hf, Ce, Th, U, Np, Pu) and M III (TTA) 4 – (M III = Ce, Nd, Sm, Yb)
journal, December 2017
- Cary, Samantha K.; Livshits, Maksim; Cross, Justin N.
- Inorganic Chemistry, Vol. 57, Issue 7
Chemistry with ADF
journal, January 2001
- te Velde, G.; Bickelhaupt, F. M.; Baerends, E. J.
- Journal of Computational Chemistry, Vol. 22, Issue 9, p. 931-967
Absorption spectrum of CfCl 3
journal, March 1973
- Carnall, William T.; Fried, Sherman; Wagner, Frank
- The Journal of Chemical Physics, Vol. 58, Issue 5
Emergence of californium as the second transitional element in the actinide series
journal, April 2015
- Cary, Samantha K.; Vasiliu, Monica; Baumbach, Ryan E.
- Nature Communications, Vol. 6, Issue 1
Electrostatic Energy Matrices of the f 7 Configuration
journal, March 1962
- Runciman, W. A.
- The Journal of Chemical Physics, Vol. 36, Issue 6
Luminescence of Ln(III) Dithiocarbamate Complexes (Ln = La, Pr, Sm, Eu, Gd, Tb, Dy)
journal, March 2008
- Regulacio, Michelle D.; Pablico, Michele H.; Vasquez, Joan Acay
- Inorganic Chemistry, Vol. 47, Issue 5
Synthesis, properties and structure of lanthanide complexes with N,N-diethyldithiocarbamate and 2,2′-bipyridyl
journal, January 1996
- Chengyong Su,
- Polyhedron, Vol. 15, Issue 2
Eight-coordination
journal, September 1978
- Burdett, Jeremy K.; Hoffmann, Roald; Fay, Robert C.
- Inorganic Chemistry, Vol. 17, Issue 9
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium
journal, September 2016
- Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A.
- Angewandte Chemie International Edition, Vol. 55, Issue 41
Cerium( iii ) dialkyl dithiocarbamates from [Ce{N(SiMe 3 ) 2 } 3 ] and tetraalkylthiuram disulfides, and [Ce(κ 2 -S 2 CNEt 2 ) 4 ] from the Ce III precursor; Tb III and Nd III analogues
journal, January 2004
- Hitchcock, Peter B.; Hulkes, Alexander G.; Lappert, Michael F.
- Dalton Trans., Issue 1
Synthesis, spectral characterization, crystal structures and catalytic activity of a series of lanthanide(III) azepane dithiocarbamate complexes
journal, April 2013
- Pitchaimani, Ponnuchamy; Lo, Kong Mun; Elango, Kuppanagounder P.
- Polyhedron, Vol. 54
Synthesis, spectral characterization, crystal structures of lanthanide(III) pyrrolidine dithiocarbamate complexes and their catalytic activity
journal, April 2015
- Pitchaimani, Ponnuchamy; Lo, Kong Mun; Elango, Kuppanagounder P.
- Journal of Coordination Chemistry, Vol. 68, Issue 12
Dithiocarramate Complexes of Trivalent Lanthanides and X-Ray Crystal Structutris(N,N-Dhsopropyldithiocakhamato)(1,10-Phenanthroline)Neodymium(III)
journal, January 1999
- Su, Cheng-Yong; Tan, Min-Yu; Zhang, Ze-Fu
- Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Vol. 29, Issue 1
Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes1
journal, September 2000
- Xu, Jide; Radkov, Emil; Ziegler, Marco
- Inorganic Chemistry, Vol. 39, Issue 18, p. 4156-4164
Contracted Gaussian basis sets for molecular calculations. I. Second row atoms, Z=11–18
journal, May 1980
- McLean, A. D.; Chandler, G. S.
- The Journal of Chemical Physics, Vol. 72, Issue 10, p. 5639-5648
Electronic energy level and intensity correlations in the spectra of the trivalent actinide aquo ions. III. Bk 3 +
journal, March 1984
- Carnall, W. T.; Beitz, J. V.; Crosswhite, H.
- The Journal of Chemical Physics, Vol. 80, Issue 6
Absorption Spectrum of Americium Tricyclopentadienide
journal, July 1969
- Pappalardo, R.; Carnall, W. T.; Fields, P. R.
- The Journal of Chemical Physics, Vol. 51, Issue 2
Relativistic regular two‐component Hamiltonians
journal, September 1993
- Lenthe, E. van; Baerends, E. J.; Snijders, J. G.
- The Journal of Chemical Physics, Vol. 99, Issue 6
Metastable charge-transfer state of californium( iii ) compounds
journal, January 2015
- Liu, Guokui; Cary, Samantha K.; Albrecht-Schmitt, Thomas E.
- Physical Chemistry Chemical Physics, Vol. 17, Issue 24
Valence basis sets for relativistic energy-consistent small-core actinide pseudopotentials
journal, January 2003
- Cao, Xiaoyan; Dolg, Michael; Stoll, Hermann
- The Journal of Chemical Physics, Vol. 118, Issue 2
Segmented contraction scheme for small-core actinide pseudopotential basis sets
journal, March 2004
- Cao, Xiaoyan; Dolg, Michael
- Journal of Molecular Structure: THEOCHEM, Vol. 673, Issue 1-3
Review Article: A Review of the Development and Operational Characteristics of the TALSPEAK Process
journal, October 2007
- Nilsson, Mikael; Nash, Kenneth L.
- Solvent Extraction and Ion Exchange, Vol. 25, Issue 6
Energies, structures, and electronic properties of molecules in solution with the C-PCM solvation model
journal, April 2003
- Cossi, Maurizio; Rega, Nadia; Scalmani, Giovanni
- Journal of Computational Chemistry, Vol. 24, Issue 6
Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates
journal, January 2012
- Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V.
- Angewandte Chemie International Edition, Vol. 51, Issue 8
The molecular surface package
journal, June 1993
- Connolly, Michael L.
- Journal of Molecular Graphics, Vol. 11, Issue 2
Optical Spectra of Tripositive Curium−244 in Lanthanum Trichloride
journal, September 1966
- Gruber, John B.; Cochran, William R.; Conway, John G.
- The Journal of Chemical Physics, Vol. 45, Issue 5
Self‐consistent molecular orbital methods. XX. A basis set for correlated wave functions
journal, January 1980
- Krishnan, R.; Binkley, J. S.; Seeger, R.
- The Journal of Chemical Physics, Vol. 72, Issue 1
Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state
journal, August 2016
- Silver, M. A.; Cary, S. K.; Johnson, J. A.
- Science, Vol. 353, Issue 6302
Dithiocarbamate Precursors for Rare-Earth Sulfides
journal, June 2005
- Regulacio, Michelle D.; Tomson, Neil; Stoll, Sarah L.
- Chemistry of Materials, Vol. 17, Issue 12
Bonding Changes in Plutonium(III) and Americium(III) Borates
journal, August 2011
- Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V.
- Angewandte Chemie International Edition, Vol. 50, Issue 38
A Combined Charge and Energy Decomposition Scheme for Bond Analysis
journal, March 2009
- Mitoraj, Mariusz P.; Michalak, Artur; Ziegler, Tom
- Journal of Chemical Theory and Computation, Vol. 5, Issue 4
Unusual structure, bonding and properties in a californium borate
journal, March 2014
- Polinski, Matthew J.; Garner, Edward B.; Maurice, Rémi
- Nature Chemistry, Vol. 6, Issue 5
Advances in containment methods and plutonium recovery strategies that led to the structural characterization of plutonium(IV) tetrachloride tris-diphenylsulfoxide, PuCl4(OSPh2)3
journal, April 2017
- Cary, Samantha K.; Boland, Kevin S.; Cross, Justin N.
- Polyhedron, Vol. 126
Rational Design of Sequestering Agents for Plutonium and Other Actinides
journal, November 2003
- Gorden, Anne E. V.; Xu, Jide; Raymond, Kenneth N.
- Chemical Reviews, Vol. 103, Issue 11
Toward reliable density functional methods without adjustable parameters: The PBE0 model
journal, April 1999
- Adamo, Carlo; Barone, Vincenzo
- The Journal of Chemical Physics, Vol. 110, Issue 13
Optimized Slater-type basis sets for the elements 1-118
journal, May 2003
- Van Lenthe, E.; Baerends, E. J.
- Journal of Computational Chemistry, Vol. 24, Issue 9
A distinct magnetic anisotropy enhancement in mononuclear dysprosium–sulfur complexes by controlling the Dy-ligand bond length
journal, January 2016
- Liu, Shan-Shan; Lang, Ke; Zhang, Yi-Quan
- Dalton Transactions, Vol. 45, Issue 19
Single-crystal structure validation with the program PLATON
journal, January 2003
- Spek, A. L.
- Journal of Applied Crystallography, Vol. 36, Issue 1, p. 7-13
Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes
journal, November 2015
- Cary, Samantha K.; Silver, Mark A.; Liu, Guokui
- Inorganic Chemistry, Vol. 54, Issue 23
Energy decomposition analysis: Energy decomposition analysis
journal, June 2011
- Hopffgarten, Moritz von; Frenking, Gernot
- Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 2, Issue 1
Chirality and Polarity in the f-Block Borates M 4 [B 16 O 26 (OH) 4 (H 2 O) 3 Cl 4 ] (M=Sm, Eu, Gd, Pu, Am, Cm, and Cf)
journal, July 2014
- Polinski, Matthew J.; Pace, Kristen A.; Stritzinger, Jared. T.
- Chemistry - A European Journal, Vol. 20, Issue 32
Reactions of a cerium( iii ) amide with heteroallenes: insertion, silyl-migration and de-insertion
journal, January 2016
- Yin, Haolin; Carroll, Patrick J.; Schelter, Eric J.
- Chemical Communications, Vol. 52, Issue 63
Low‐Lying Energy Levels of Trivalent Curium
journal, March 1964
- Wybourne, B. G.
- The Journal of Chemical Physics, Vol. 40, Issue 5
Energy‐adjusted a b i n i t i o pseudopotentials for the rare earth elements
journal, February 1989
- Dolg, M.; Stoll, H.; Preuss, H.
- The Journal of Chemical Physics, Vol. 90, Issue 3
Comparison of Covalency in the Complexes of Trivalent Actinide and Lanthanide Cations
journal, August 2002
- Jensen, Mark P.; Bond, Andrew H.
- Journal of the American Chemical Society, Vol. 124, Issue 33
Praseodymium complexes of 2,2′-bipyridine; the crystal and molecular structures of Pr(bipy)3(NCS)3, Pr(bipy)2(NO3)3, Pr(bipy)2Cl3(OH2)·EtOH and Pr(bipy)(S2CNEt2)3
journal, January 2003
- Bower, John F.; Cotton, Simon A.; Fawcett, John
- Polyhedron, Vol. 22, Issue 2
Crystal structure of trans-dibromidobis(4-phenylpyridine-κN) platinum(II), PtBr2(C11H9N)2, C22H18Br2N2Pt
journal, October 2013
- Ha, Kwang
- Zeitschrift für Kristallographie - New Crystal Structures, Vol. 228, Issue 3
Bonding Changes in Plutonium(III) and Americium(III) Borates
journal, August 2011
- Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V.
- Angewandte Chemie, Vol. 123, Issue 38
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium
journal, September 2016
- Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A.
- Angewandte Chemie, Vol. 128, Issue 41
Rational Design of Sequestering Agents for Plutonium and Other Actinides
journal, February 2004
- Gorden, Anne E. V.; Xu, Jide; Raymond, Kenneth N.
- ChemInform, Vol. 35, Issue 5
Manipulating anion intercalation enables a high-voltage aqueous dual ion battery
journal, May 2021
- Huang, Zhaodong; Hou, Yue; Wang, Tairan
- Nature Communications, Vol. 12, Issue 1
Synthesis, spectral characterization, crystal structures of lanthanide(III) pyrrolidine dithiocarbamate complexes and their catalytic activity
text, January 2015
- Pitchaimani, Ponnuchamy; Lo, Kong Mun; Elango, Kuppanagounder P.
- Taylor & Francis
Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates
journal, January 2012
- Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V.
- Angewandte Chemie, Vol. 124, Issue 8
Synthesis, spectral characterization, crystal structures of lanthanide(III) pyrrolidine dithiocarbamate complexes and their catalytic activity
text, January 2015
- Pitchaimani, Ponnuchamy; Lo, Kong Mun; Elango, Kuppanagounder P.
- Taylor & Francis
Synthesis, spectral characterization, crystal structures of lanthanide(III) pyrrolidine dithiocarbamate complexes and their catalytic activity
text, January 2015
- Pitchaimani, Ponnuchamy; Lo, Kong Mun; Elango, Kuppanagounder P.
- Taylor & Francis
Synthesis, spectral characterization, crystal structures of lanthanide(III) pyrrolidine dithiocarbamate complexes and their catalytic activity
text, January 2015
- Pitchaimani, Ponnuchamy; Lo, Kong Mun; Elango, Kuppanagounder P.
- Taylor & Francis
Works referencing / citing this record:
An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements
journal, September 2019
- Ridenour, J. August; Surbella, Robert G.; Gelis, Artem V.
- Angewandte Chemie, Vol. 131, Issue 46
[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex
journal, July 2019
- Goodwin, Conrad A. P.; Su, Jing; Albrecht-Schmitt, Thomas E.
- Angewandte Chemie International Edition, Vol. 58, Issue 34
Contemporary Chemistry of Berkelium and Californium
journal, June 2019
- White, Frankie D.; Dan, David; Albrecht‐Schmitt, Thomas E.
- Chemistry – A European Journal, Vol. 25, Issue 44
Soft-donor dipicolinamide derivatives for selective actinide( iii )/lanthanide( iii ) separation: the role of S- vs. O-donor sites
journal, January 2019
- Lehman-Andino, Ingrid; Su, Jing; Papathanasiou, Konstantinos E.
- Chemical Communications, Vol. 55, Issue 17
[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex
journal, July 2019
- Goodwin, Conrad A. P.; Su, Jing; Albrecht‐Schmitt, Thomas E.
- Angewandte Chemie, Vol. 131, Issue 34
An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements
journal, November 2019
- Ridenour, J. August; Surbella, Robert G.; Gelis, Artem V.
- Angewandte Chemie International Edition, Vol. 58, Issue 46