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Title: Ultrafast interligand electron transfer in cis -[Ru(4,4′-dicarboxylate-2,2′-bipyridine) 2 (NCS) 2 ] 4− and implications for electron injection limitations in dye sensitized solar cells

Using IR absorption anisotropy, interligand energy transfer in N712 is shown to occur on a sub-ps time scale, and is thus unlikely to limit injection in DSSCs.
Authors:
 [1] ; ORCiD logo [1] ;  [1] ; ORCiD logo [2] ;  [1] ;  [3] ;  [3] ; ORCiD logo [3] ; ORCiD logo [1]
  1. Department of Chemistry – Ångström Laboratory, Uppsala University, SE75120 Uppsala, Sweden
  2. Department of Chemistry – Ångström Laboratory, Uppsala University, SE75120 Uppsala, Sweden, Department of Biotechnology
  3. Department of Chemistry, Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, Evanston, USA
Publication Date:
Grant/Contract Number:
SC0001059
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 41; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1467930

Pettersson Rimgard, Belinda, Föhlinger, Jens, Petersson, Jonas, Lundberg, Marcus, Zietz, Burkhard, Woys, Ann Marie, Miller, Stephen A., Wasielewski, Michael R., and Hammarström, Leif. Ultrafast interligand electron transfer in cis -[Ru(4,4′-dicarboxylate-2,2′-bipyridine) 2 (NCS) 2 ] 4− and implications for electron injection limitations in dye sensitized solar cells. United Kingdom: N. p., Web. doi:10.1039/C8SC00274F.
Pettersson Rimgard, Belinda, Föhlinger, Jens, Petersson, Jonas, Lundberg, Marcus, Zietz, Burkhard, Woys, Ann Marie, Miller, Stephen A., Wasielewski, Michael R., & Hammarström, Leif. Ultrafast interligand electron transfer in cis -[Ru(4,4′-dicarboxylate-2,2′-bipyridine) 2 (NCS) 2 ] 4− and implications for electron injection limitations in dye sensitized solar cells. United Kingdom. doi:10.1039/C8SC00274F.
Pettersson Rimgard, Belinda, Föhlinger, Jens, Petersson, Jonas, Lundberg, Marcus, Zietz, Burkhard, Woys, Ann Marie, Miller, Stephen A., Wasielewski, Michael R., and Hammarström, Leif. 2018. "Ultrafast interligand electron transfer in cis -[Ru(4,4′-dicarboxylate-2,2′-bipyridine) 2 (NCS) 2 ] 4− and implications for electron injection limitations in dye sensitized solar cells". United Kingdom. doi:10.1039/C8SC00274F.
@article{osti_1467930,
title = {Ultrafast interligand electron transfer in cis -[Ru(4,4′-dicarboxylate-2,2′-bipyridine) 2 (NCS) 2 ] 4− and implications for electron injection limitations in dye sensitized solar cells},
author = {Pettersson Rimgard, Belinda and Föhlinger, Jens and Petersson, Jonas and Lundberg, Marcus and Zietz, Burkhard and Woys, Ann Marie and Miller, Stephen A. and Wasielewski, Michael R. and Hammarström, Leif},
abstractNote = {Using IR absorption anisotropy, interligand energy transfer in N712 is shown to occur on a sub-ps time scale, and is thus unlikely to limit injection in DSSCs.},
doi = {10.1039/C8SC00274F},
journal = {Chemical Science},
number = 41,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {10}
}

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