Title: Ultrafast interligand electron transfer in cis -[Ru(4,4′-dicarboxylate-2,2′-bipyridine) 2 (NCS) 2 ] 4− and implications for electron injection limitations in dye sensitized solar cells

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/C8SC00274F · OSTI ID:1467930
 [1]; ORCiD logo [1];  [1]; ORCiD logo [2];  [1];  [3];  [3]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry – Ångström Laboratory, Uppsala University, SE75120 Uppsala, Sweden
  2. Department of Chemistry – Ångström Laboratory, Uppsala University, SE75120 Uppsala, Sweden, Department of Biotechnology
  3. Department of Chemistry, Argonne-Northwestern Solar Energy Research (ANSER) Center, Northwestern University, Evanston, USA
+ Show Author Affiliations

Using IR absorption anisotropy, interligand energy transfer in N712 is shown to occur on a sub-ps time scale, and is thus unlikely to limit injection in DSSCs.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Light Energy Activated Redox Processes (LEAP); Northwestern University, Evanston, IL (United States)
Sponsoring Organization:
Knut and Alice Wallenberg Foundation; Swedish Energy Agency; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0001059
OSTI ID:
1467930
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 41 Vol. 9; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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  • Youngblood, W. Justin; Lee, Seung-Hyun Anna; Kobayashi, Yoji
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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
bio-inspired
catalysis (heterogeneous)
catalysis (homogeneous)
charge transport
hydrogen and fuel cells
magnetism and spin physics
materials and chemistry by design
mesostructured materials
optics
phonons
photosynthesis (natural and artificial)
solar (fuels)
solar (photovoltaic)
synthesis (novel materials)
synthesis (scalable processing)
synthesis (self-assembly)