Enhancement of Raman scattering from molecules placed near metal nanoparticles
Abstract
Large Raman scattering cross sections from molecules on surfaces of metallic nanoparticles are described within a renormalization-group theory. In this approach the valence electrons of the molecules are embedded in an effective medium described by a dielectric function, which integrates out the effect of the plasmonic excitations of the metallic nanoparticles. The source of the enhanced photon inelastic scattering is produced by the resonant excitation of surface plasmons at the metallic nanoparticles. A similar theory has been successfully used to explain the resonant x-ray inelastic scattering and the behavior of nonlinear susceptibilities at the x-ray edges.
- Authors:
-
- Northeastern Univ., Boston, MA (United States). Dept. of Physics
- Publication Date:
- Research Org.:
- Northeastern Univ., Boston, MA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1466806
- Alternate Identifier(s):
- OSTI ID: 1497722
- Grant/Contract Number:
- FG02-07ER46352; AC02-05CH11231; SC0012575
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Low Temperature Physics
- Additional Journal Information:
- Journal Volume: 43; Journal Issue: 1; Journal ID: ISSN 1063-777X
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS
Citation Formats
Barbiellini, B. Enhancement of Raman scattering from molecules placed near metal nanoparticles. United States: N. p., 2017.
Web. doi:10.1063/1.4974193.
Barbiellini, B. Enhancement of Raman scattering from molecules placed near metal nanoparticles. United States. https://doi.org/10.1063/1.4974193
Barbiellini, B. Fri .
"Enhancement of Raman scattering from molecules placed near metal nanoparticles". United States. https://doi.org/10.1063/1.4974193. https://www.osti.gov/servlets/purl/1466806.
@article{osti_1466806,
title = {Enhancement of Raman scattering from molecules placed near metal nanoparticles},
author = {Barbiellini, B.},
abstractNote = {Large Raman scattering cross sections from molecules on surfaces of metallic nanoparticles are described within a renormalization-group theory. In this approach the valence electrons of the molecules are embedded in an effective medium described by a dielectric function, which integrates out the effect of the plasmonic excitations of the metallic nanoparticles. The source of the enhanced photon inelastic scattering is produced by the resonant excitation of surface plasmons at the metallic nanoparticles. A similar theory has been successfully used to explain the resonant x-ray inelastic scattering and the behavior of nonlinear susceptibilities at the x-ray edges.},
doi = {10.1063/1.4974193},
journal = {Low Temperature Physics},
number = 1,
volume = 43,
place = {United States},
year = {2017},
month = {2}
}
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Figure-1: Cross section enhancement g as a function of the ratio e1=e0.
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