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Title: High selectivity of CO 2 hydrogenation to CO by controlling the valence state of nickel using perovskite

Abstract

The selectivity of CO 2 hydrogenation can be significantly tuned by controlling the valence state of nickel using lanthanum-iron-nickel perovskites. Nickel with higher valence states weakens the binding of CO and increases the activation barrier for further CO hydrogenation, leading to a higher CO selectivity than the metallic nickel.

Authors:
 [1];  [1];  [2];  [3]; ORCiD logo [3]; ORCiD logo [4];  [5]; ORCiD logo [3];  [5]; ORCiD logo [6]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States); Tsinghua Univ., Beijing (China)
  2. Columbia Univ., New York, NY (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States)
  4. Stony Brook Univ., NY (United States)
  5. Tsinghua Univ., Beijing (China)
  6. Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1466617
Alternate Identifier(s):
OSTI ID: 1454637
Report Number(s):
BNL-207967-2018-JAAM
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:  
SC0012704; AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 53; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats

Zhao, Baohuai, Yan, Binhang, Jiang, Zhao, Yao, Siyu, Liu, Zongyuan, Wu, Qiyuan, Ran, Rui, Senanayake, Sanjaya D., Weng, Duan, and Chen, Jingguang G. High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite. United States: N. p., 2018. Web. doi:10.1039/C8CC03829E.
Zhao, Baohuai, Yan, Binhang, Jiang, Zhao, Yao, Siyu, Liu, Zongyuan, Wu, Qiyuan, Ran, Rui, Senanayake, Sanjaya D., Weng, Duan, & Chen, Jingguang G. High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite. United States. doi:10.1039/C8CC03829E.
Zhao, Baohuai, Yan, Binhang, Jiang, Zhao, Yao, Siyu, Liu, Zongyuan, Wu, Qiyuan, Ran, Rui, Senanayake, Sanjaya D., Weng, Duan, and Chen, Jingguang G. Mon . "High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite". United States. doi:10.1039/C8CC03829E. https://www.osti.gov/servlets/purl/1466617.
@article{osti_1466617,
title = {High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite},
author = {Zhao, Baohuai and Yan, Binhang and Jiang, Zhao and Yao, Siyu and Liu, Zongyuan and Wu, Qiyuan and Ran, Rui and Senanayake, Sanjaya D. and Weng, Duan and Chen, Jingguang G.},
abstractNote = {The selectivity of CO2 hydrogenation can be significantly tuned by controlling the valence state of nickel using lanthanum-iron-nickel perovskites. Nickel with higher valence states weakens the binding of CO and increases the activation barrier for further CO hydrogenation, leading to a higher CO selectivity than the metallic nickel.},
doi = {10.1039/C8CC03829E},
journal = {ChemComm},
number = 53,
volume = 54,
place = {United States},
year = {2018},
month = {6}
}

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