Recent Advances of Structurally Ordered Intermetallic Nanoparticles for Electrocatalysis

Xiao, Weiping; Lei, Wen; Gong, Mingxing; Xin, Huolin L.; Wang, Deli

doi:10.1021/acscatal.7b04420

Title: Recent Advances of Structurally Ordered Intermetallic Nanoparticles for Electrocatalysis

Journal Article · 05 March 2018 · ACS Catalysis

DOI: https://doi.org/10.1021/acscatal.7b04420 · OSTI ID:1466614

Xiao, Weiping ^[1];

^[1]; Gong, Mingxing ^[1]; Xin, Huolin L. ^[2];

^[1]

Huazhong Univ. of Science and Technology, Wuhan (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Structurally ordered intermetallic phases have exhibited higher and higher electrocatalytic activity and stability than disordered alloys in reactions such as the oxygen reduction reaction (ORR) and the catalytic oxidation of fuels (hydrogen, formic acid, or ethanol). The enhanced electrocatalytic activity could be derived from the definite composition and predictable control over structural, geometric, and electronic effects. This review, based on the understanding of the catalytic mechanism of structurally ordered intermetallic nanoparticles, provides a comprehensive acknowledgement of how the particle size and morphology affect the catalytic performance. The strategy for reducing particle size and the impact of particle size on electrocatalysis will be firstly introduced. Then, recent developments in the synthesis and design of morphology-controlled catalysts are summarized. The structure-activity relationship between the catalytic activity and morphology including core-shell/hollow and porosity will be highlighted. Finally, the current challenges and future developments are provided. On the basis of this review, intermetallic compound shed light on the future development of electrocatalysts for fuel cells and metal-air batteries.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1466614

Report Number(s):: BNL--207960-2018-JAAM

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 4 Vol. 8; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Pt ²⁺ -Exchanged ZIF-8 nanocube as a solid-state precursor for L1 ₀ -PtZn intermetallic nanoparticles embedded in a hollow carbon nanocage Kwon, Taehyun; Lim, Sunghyun; Jun, Minki Nanoscale, Vol. 12, Issue 2 https://doi.org/10.1039/c9nr09318d	journal	January 2020
Intermetallic Pd ₃ Pb nanocubes with high selectivity for the 4-electron oxygen reduction reaction pathway Gamler, Jocelyn T. L.; Shin, Kihyun; Ashberry, Hannah M. Nanoscale, Vol. 12, Issue 4 https://doi.org/10.1039/c9nr09759g	journal	January 2020
Conversion of the greenhouse gas CO ₂ to methanol over supported intermetallic Ga–Ni catalysts at atmospheric pressure: thermodynamic modeling and experimental study Ahmad, Kaisar; Upadhyayula, Sreedevi Sustainable Energy & Fuels, Vol. 3, Issue 9 https://doi.org/10.1039/c9se00165d	journal	January 2019
Tunable synthesis of multiply twinned intermetallic Pd ₃ Pb nanowire networks toward efficient N ₂ to NH ₃ conversion Guo, Jingchun; Wang, Hui; Xue, Fei Journal of Materials Chemistry A, Vol. 7, Issue 35 https://doi.org/10.1039/c9ta07519d	journal	January 2019
Intermetallic compound catalysts: synthetic scheme, structure characterization and catalytic application Yang, Yusen; Wei, Min Journal of Materials Chemistry A, Vol. 8, Issue 5 https://doi.org/10.1039/c9ta09448b	journal	January 2020
High-performance alcohol electrooxidation on Pt ₃ Sn–SnO ₂ nanocatalysts synthesized through the transformation of Pt–Sn nanoparticles Wang, Liang; Wu, Wei; Lei, Zhao Journal of Materials Chemistry A, Vol. 8, Issue 2 https://doi.org/10.1039/c9ta10886f	journal	January 2020
Addressing the Stability of Bulk Electrode Materials in the Electrochemical Methanol Oxidation Zerdoumi, Ridha; Rößner, Leonard; Armbrüster, Marc Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0631914jes	journal	January 2019

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