Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions

Tikekar, Mukul D.; Archer, Lynden A.; Koch, Donald L.

doi:10.1126/sciadv.1600320

Title: Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions

Journal Article · 15 July 2016 · Science Advances

DOI: https://doi.org/10.1126/sciadv.1600320 · OSTI ID:1466573

Tikekar, Mukul D. ^[1]; Archer, Lynden A. ^[2]; Koch, Donald L. ^[2]

Cornell Univ., Ithaca, NY (United States). Sibley School of Mechanical and Aerospace Engineering; Cornell University
Cornell Univ., Ithaca, NY (United States). Robert Frederick Smith School of Chemical and Biomolecular Engineering

Ion transport–driven instabilities in electrodeposition of metals that lead to morphological instabilities and dendrites are receiving renewed attention because mitigation strategies are needed for improving rechargeability and safety of lithium batteries. The growth rate of these morphological instabilities can be slowed by immobilizing a fraction of anions within the electrolyte to reduce the electric field at the metal electrode. We analyze the role of elastic deformation of the solid electrolyte with immobilized anions and present theory combining the roles of separator elasticity and modified transport to evaluate the factors affecting the stability of planar deposition over a wide range of current densities. Lastly, we find that stable electrodeposition can be easily achieved even at relatively high current densities in electrolytes/separators with moderate polymer-like mechanical moduli, provided a small fraction of anions are immobilized in the separator.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Materials Center at Cornell (EMC2); Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001086

OSTI ID:: 1466573

Journal Information:: Science Advances, Journal Name: Science Advances Journal Issue: 7 Vol. 2; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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Designer interphases for the lithium-oxygen electrochemical cell Choudhury, Snehashis; Wan, Charles Tai-Chieh; Al Sadat, Wajdi I. Science Advances, Vol. 3, Issue 4 https://doi.org/10.1126/sciadv.1602809	journal	April 2017
Stabilizing electrochemical interfaces in viscoelastic liquid electrolytes Wei, Shuya; Cheng, Zhu; Nath, Pooja Science Advances, Vol. 4, Issue 3 https://doi.org/10.1126/sciadv.aao6243	journal	March 2018
A “cation-anion regulation” synergistic anode host for dendrite-free lithium metal batteries Zhang, Weidong; Zhuang, Houlong L.; Fan, Lei Science Advances, Vol. 4, Issue 2 https://doi.org/10.1126/sciadv.aar4410	journal	February 2018
Upgrading traditional liquid electrolyte via in situ gelation for future lithium metal batteries Liu, Feng-Quan; Wang, Wen-Peng; Yin, Ya-Xia Science Advances, Vol. 4, Issue 10 https://doi.org/10.1126/sciadv.aat5383	journal	October 2018
Enabling reversible redox reactions in electrochemical cells using protected LiAl intermetallics as lithium metal anodes Kim, Mun Sek; Lee, Seung Hun Science Advances, Vol. 5, Issue 10 https://doi.org/10.1126/sciadv.aax5587	journal	October 2019
Metal Electrode Surfaces Can Roughen Despite the Constraint of a Stiff Electrolyte McMeeking, Robert M.; Ganser, Markus; Klinsmann, Markus Journal of The Electrochemical Society, Vol. 166, Issue 6 https://doi.org/10.1149/2.0221906jes	journal	January 2019
Electroconvection and Morphological Instabilities in Potentiostatic Electrodeposition across Liquid Electrolytes with Polymer Additives Tikekar, Mukul D.; Li, Gaojin; Archer, Lynden A. Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0271816jes	journal	January 2018
Linear Stability Analysis of Transient Electrodeposition in Charged Porous Media: Suppression of Dendritic Growth by Surface Conduction Khoo, Edwin; Zhao, Hongbo; Bazant, Martin Z. Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.1521910jes	journal	January 2019
Linear stability analysis of transient electrodeposition in charged porous media: suppression of dendritic growth by surface conduction Khoo, Edwin; Zhao, Hongbo; Bazant, Martin Z. arXiv https://doi.org/10.48550/arxiv.1901.05033	text	January 2019

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