skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: A molecular basis to rare earth separations for recycling: tuning the TriNOx ligand properties for improved performance

Abstract

A methoxy-substituted tripodal hydroxylamine ligand, H 3 TriNOx OMe , was synthesized and coordinated to rare earth cations for separation purposes.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [1]
  1. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1466425
Grant/Contract Number:  
SC0017259
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 54 Journal Issue: 73; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Cole, Bren E., Falcones, Ingemar B., Cheisson, Thibault, Manor, Brian C., Carroll, Patrick J., and Schelter, Eric J. A molecular basis to rare earth separations for recycling: tuning the TriNOx ligand properties for improved performance. United Kingdom: N. p., 2018. Web. doi:10.1039/C8CC04409K.
Cole, Bren E., Falcones, Ingemar B., Cheisson, Thibault, Manor, Brian C., Carroll, Patrick J., & Schelter, Eric J. A molecular basis to rare earth separations for recycling: tuning the TriNOx ligand properties for improved performance. United Kingdom. doi:10.1039/C8CC04409K.
Cole, Bren E., Falcones, Ingemar B., Cheisson, Thibault, Manor, Brian C., Carroll, Patrick J., and Schelter, Eric J. Mon . "A molecular basis to rare earth separations for recycling: tuning the TriNOx ligand properties for improved performance". United Kingdom. doi:10.1039/C8CC04409K.
@article{osti_1466425,
title = {A molecular basis to rare earth separations for recycling: tuning the TriNOx ligand properties for improved performance},
author = {Cole, Bren E. and Falcones, Ingemar B. and Cheisson, Thibault and Manor, Brian C. and Carroll, Patrick J. and Schelter, Eric J.},
abstractNote = {A methoxy-substituted tripodal hydroxylamine ligand, H 3 TriNOx OMe , was synthesized and coordinated to rare earth cations for separation purposes.},
doi = {10.1039/C8CC04409K},
journal = {Chemical Communications},
number = 73,
volume = 54,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8CC04409K

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Rare-Earth Separation Using Bacteria
journal, March 2016


The Exchange Adsorption of Ions from Aqueous Solutions by Organic Zeolites. IV. The Separation of the Yttrium Group Rare Earths 1
journal, November 1947

  • Ketelle, B. H.; Boyd, G. E.
  • Journal of the American Chemical Society, Vol. 69, Issue 11
  • DOI: 10.1021/ja01203a062

A Ligand Field Series for the 4f-Block from Experimental and DFT Computed Ce(IV/III) Electrochemical Potentials
journal, February 2015

  • Bogart, Justin A.; Lewis, Andrew J.; Boreen, Michael A.
  • Inorganic Chemistry, Vol. 54, Issue 6
  • DOI: 10.1021/ic503000z

A survey of solvent selection guides
journal, January 2014

  • Prat, Denis; Hayler, John; Wells, Andy
  • Green Chem., Vol. 16, Issue 10
  • DOI: 10.1039/C4GC01149J

Photochemical recovery of europium from non-aqueous solutions
journal, January 2016

  • Van den Bogaert, Bart; Gheeraert, Lore; Leblebici, Mumin Enis
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 43
  • DOI: 10.1039/C6CP06329B

Replacement of benzene as a solvent for aflatoxin standards
journal, December 1981

  • Velasco, J.
  • Journal of the American Oil Chemists' Society, Vol. 58, Issue 12
  • DOI: 10.1007/BF02679294

Lutetium and Ytterbium Separation by Ion-Exchange Chromatography
journal, April 2017


Synthesis and structural studies of tris-2-chlorobenzylamine and tris-2-bromobenzylamine
journal, March 2005

  • Chen, Qing; Buss, Carrie E.; Young, Victor G.
  • Journal of Chemical Crystallography, Vol. 35, Issue 3
  • DOI: 10.1007/s10870-005-2954-5

CHEM21 selection guide of classical- and less classical-solvents
journal, January 2016

  • Prat, Denis; Wells, Andy; Hayler, John
  • Green Chemistry, Vol. 18, Issue 1
  • DOI: 10.1039/C5GC01008J

Rare earth separations by selective borate crystallization
journal, March 2017

  • Yin, Xuemiao; Wang, Yaxing; Bai, Xiaojing
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14438

Photochemical recycling of europium from Eu/Y mixtures in red lamp phosphor waste streams
journal, January 2015

  • Van den Bogaert, Bart; Havaux, Daphné; Binnemans, Koen
  • Green Chemistry, Vol. 17, Issue 4
  • DOI: 10.1039/C4GC02140A

Preparation of Enhanced Extraction Resin by BPO for the Separation of Rare Earth Elements (Gd, Tb, Dy, Ho)
journal, June 2013


Electro-kinetic Separation of Rare Earth Elements Using a Redox-Active Ligand
journal, September 2017

  • Fang, Huayi; Cole, Bren E.; Qiao, Yusen
  • Angewandte Chemie International Edition, Vol. 56, Issue 43
  • DOI: 10.1002/anie.201706894

A critical review on solvent extraction of rare earths from aqueous solutions
journal, February 2014


Samb V ca: A Web Application for the Calculation of the Buried Volume of N-Heterocyclic Carbene Ligands
journal, May 2009

  • Poater, Albert; Cosenza, Biagio; Correa, Andrea
  • European Journal of Inorganic Chemistry, Vol. 2009, Issue 13
  • DOI: 10.1002/ejic.200801160

Assessing Safety, Health, and Environmental Impact Early during Process Development
journal, April 2000

  • Koller, Guntram; Fischer, Ulrich; Hungerbühler, Konrad
  • Industrial & Engineering Chemistry Research, Vol. 39, Issue 4
  • DOI: 10.1021/ie990669i

Adsorption and chromatographic separation of rare earths with EDTA- and DTPA-functionalized chitosan biopolymers
journal, January 2014

  • Roosen, Joris; Binnemans, Koen
  • J. Mater. Chem. A, Vol. 2, Issue 5
  • DOI: 10.1039/C3TA14622G

An Operationally Simple Method for Separating the Rare-Earth Elements Neodymium and Dysprosium
journal, May 2015

  • Bogart, Justin A.; Lippincott, Connor A.; Carroll, Patrick J.
  • Angewandte Chemie International Edition, Vol. 54, Issue 28
  • DOI: 10.1002/anie.201501659

Rationally designed mineralization for selective recovery of the rare earth elements
journal, May 2017

  • Hatanaka, Takaaki; Matsugami, Akimasa; Nonaka, Takamasa
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15670

Nanostructured Hybrid Materials for the Selective Recovery and Enrichment of Rare Earth Elements
journal, January 2014

  • Florek, Justyna; Chalifour, François; Bilodeau, François
  • Advanced Functional Materials, Vol. 24, Issue 18
  • DOI: 10.1002/adfm.201303602

Bioadsorption of Rare Earth Elements through Cell Surface Display of Lanthanide Binding Tags
journal, February 2016

  • Park, Dan M.; Reed, David W.; Yung, Mimi C.
  • Environmental Science & Technology, Vol. 50, Issue 5
  • DOI: 10.1021/acs.est.5b06129

Size-Selective Crystallization of Homochiral Camphorate Metal–Organic Frameworks for Lanthanide Separation
journal, August 2014

  • Zhao, Xiang; Wong, Matthew; Mao, Chengyu
  • Journal of the American Chemical Society, Vol. 136, Issue 36
  • DOI: 10.1021/ja5067306

Green chemistry tools to influence a medicinal chemistry and research chemistry based organisation
journal, January 2008

  • Alfonsi, Kim; Colberg, Juan; Dunn, Peter J.
  • Green Chem., Vol. 10, Issue 1
  • DOI: 10.1039/B711717E

Accomplishing simple, solubility-based separations of rare earth elements with complexes bearing size-sensitive molecular apertures
journal, December 2016

  • Bogart, Justin A.; Cole, Bren E.; Boreen, Michael A.
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 52
  • DOI: 10.1073/pnas.1612628113

The Separation of Rare Earths by Ion Exchange. V. Investigations with One-tenth Per Cent. Citric Acid-Ammonium Citrate Solutions 1
journal, June 1950

  • Spedding, F. H.; Fulmer, E. I.; Powell, J. E.
  • Journal of the American Chemical Society, Vol. 72, Issue 6
  • DOI: 10.1021/ja01162a004

What is a green solvent? A comprehensive framework for the environmental assessment of solvents
journal, January 2007

  • Capello, Christian; Fischer, Ulrich; Hungerbühler, Konrad
  • Green Chemistry, Vol. 9, Issue 9
  • DOI: 10.1039/b617536h