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Title: Above-Band Gap Photoinduced Stabilization of Engineered Ferroelectric Domains

Abstract

The effect of above-band gap photons on the domains of the BiFeO3 (BFO) thin film was investigated via piezoresponse force microscopy and Kelvin probe force microscopy. It is found that under above-band gap illumination, the relaxation time of the polarization state was significantly extended, while the effective polarizing voltage for the pristine domains was reduced. We propose that this photoinduced domain stabilization can be attributed to the interaction between photogenerated surface charges and domains. Importantly, a similar phenomenon is observed in other ferroelectric (FE) materials with an internal electric field once they are illuminated by above-band gap light, indicating that this photoinduced stabilization is potentially universal rather than specific to BFO. Furthermore, this study will not only contribute to the knowledge of photovoltaic (PV) phenomena but also provide a new route to promote the stability of PV and FE materials.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [2];  [3];  [3];  [4];  [1];  [1];  [2]; ORCiD logo [1]
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  1. The Australian National Univ., Canberra ACT (Australia)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Chinese Academy of Sciences, Shanghai (People's Republic of China)
  4. Australian National Univ., Canberra ACT (Australia)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
Australian Research Council; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
OSTI Identifier:
1466402
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
ACS Applied Materials and Interfaces
Additional Journal Information:
Journal Volume: 10; Journal Issue: 15; Journal ID: ISSN 1944-8244
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; KPFM; PFM; above-bandgap illumination; domain; ferroelectrics; relaxation time; surface

Citation Formats

Mai, Haoxin, Lu, Teng, Li, Qian, Liu, Zhifu, Li, Yongxiang, Kremer, Felipe, Li, Li, Withers, Ray L., Wen, Haidan, and Liu, Yun. Above-Band Gap Photoinduced Stabilization of Engineered Ferroelectric Domains. United States: N. p., 2018. Web. doi:10.1021/acsami.8b00254.
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Mai, Haoxin, Lu, Teng, Li, Qian, Liu, Zhifu, Li, Yongxiang, Kremer, Felipe, Li, Li, Withers, Ray L., Wen, Haidan, & Liu, Yun. Above-Band Gap Photoinduced Stabilization of Engineered Ferroelectric Domains. United States. https://doi.org/10.1021/acsami.8b00254
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Mai, Haoxin, Lu, Teng, Li, Qian, Liu, Zhifu, Li, Yongxiang, Kremer, Felipe, Li, Li, Withers, Ray L., Wen, Haidan, and Liu, Yun. Fri . "Above-Band Gap Photoinduced Stabilization of Engineered Ferroelectric Domains". United States. https://doi.org/10.1021/acsami.8b00254. https://www.osti.gov/servlets/purl/1466402.
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@article{osti_1466402,
title = {Above-Band Gap Photoinduced Stabilization of Engineered Ferroelectric Domains},
author = {Mai, Haoxin and Lu, Teng and Li, Qian and Liu, Zhifu and Li, Yongxiang and Kremer, Felipe and Li, Li and Withers, Ray L. and Wen, Haidan and Liu, Yun},
abstractNote = {The effect of above-band gap photons on the domains of the BiFeO3 (BFO) thin film was investigated via piezoresponse force microscopy and Kelvin probe force microscopy. It is found that under above-band gap illumination, the relaxation time of the polarization state was significantly extended, while the effective polarizing voltage for the pristine domains was reduced. We propose that this photoinduced domain stabilization can be attributed to the interaction between photogenerated surface charges and domains. Importantly, a similar phenomenon is observed in other ferroelectric (FE) materials with an internal electric field once they are illuminated by above-band gap light, indicating that this photoinduced stabilization is potentially universal rather than specific to BFO. Furthermore, this study will not only contribute to the knowledge of photovoltaic (PV) phenomena but also provide a new route to promote the stability of PV and FE materials.},
doi = {10.1021/acsami.8b00254},
journal = {ACS Applied Materials and Interfaces},
number = 15,
volume = 10,
place = {United States},
year = {Fri Mar 09 00:00:00 EST 2018},
month = {Fri Mar 09 00:00:00 EST 2018}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acsami.8b00254
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Cited by: 22 works
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Figures / Tables:

Figure 1 Figure 1: Characterization of as-prepared BFO thin films. (a) Specular scan XRD pattern (b) rocking curve scan around the BFO 110C reflection along with the Gaussian peak fit (FWHM ~ 1.54°) , ; inset is a scanning X-ray diffraction map based on the BFO 110C reflection measured at the rockingmore » angle ω = 10.5° (Scale bar = 5 μm). (c) Cross-section TEM image of the BFO thin film. (d) AFM image of the BFO thin film in a region of 1.5 × 1.5 μm2. (e) Calculated band gap of the BFO thin films with the tangent of the linear part as dotted line (Inset is the raw UV–vis absorption spectrum).« less
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Works referenced in this record:

Photovoltaics with Ferroelectrics: Current Status and Beyond
journal, May 2016

  • Paillard, Charles; Bai, Xiaofei; Infante, Ingrid C.
  • Advanced Materials, Vol. 28, Issue 26
  • DOI: 10.1002/adma.201505215

Thin-film ferroelectric materials and their applications
journal, November 2016

Switchable Ferroelectric Diode and Photovoltaic Effect in BiFeO 3
journal, February 2009

Above-bandgap voltages from ferroelectric photovoltaic devices
journal, January 2010

Photoelectric Effects in Single Domain BiFeO 3 Crystals
journal, July 2012

  • Moubah, Reda; Rousseau, Olivier; Colson, Dorothée
  • Advanced Functional Materials, Vol. 22, Issue 22
  • DOI: 10.1002/adfm.201201150

Role of domain walls in the abnormal photovoltaic effect in BiFeO3
journal, November 2013

  • Bhatnagar, Akash; Roy Chaudhuri, Ayan; Heon Kim, Young
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3835

Enhancement of Local Photovoltaic Current at Ferroelectric Domain Walls in BiFeO3
journal, February 2017

  • Yang, Ming-Min; Bhatnagar, Akash; Luo, Zheng-Dong
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/srep43070

Perovskite oxides for visible-light-absorbing ferroelectric and photovoltaic materials
journal, November 2013

  • Grinberg, Ilya; West, D. Vincent; Torres, Maria
  • Nature, Vol. 503, Issue 7477, p. 509-512
  • DOI: 10.1038/nature12622

Enlarging photovoltaic effect: combination of classic photoelectric and ferroelectric photovoltaic effects
journal, July 2013

  • Zhang, Jingjiao; Su, Xiaodong; Shen, Mingrong
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02109

Bandgap tuning of multiferroic oxide solar cells
journal, November 2014

Controllable Photovoltaic Effect of Microarray Derived from Epitaxial Tetragonal BiFeO 3 Films
journal, August 2017

  • Lu, Zengxing; Li, Peilian; Wan, Jian-guo
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 32
  • DOI: 10.1021/acsami.7b06535

Giant ultrafast photo-induced shear strain in ferroelectric BiFeO3
journal, July 2014

  • Lejman, Mariusz; Vaudel, Gwenaelle; Infante, Ingrid C.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5301

Photovoltaic and photo-capacitance effects in ferroelectric BiFeO 3 thin film
journal, May 2017

  • Biswas, Pranab Parimal; Chinthakuntla, Thirmal; Duraisamy, Dhayanithi
  • Applied Physics Letters, Vol. 110, Issue 19
  • DOI: 10.1063/1.4983378

Optically controlled electroresistance and electrically controlled photovoltage in ferroelectric tunnel junctions
journal, February 2016

  • Jin Hu, Wei; Wang, Zhihong; Yu, Weili
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10808

Highly (001)-Textured Tetragonal BiFeO 3 Film and Its Photoelectrochemical Behaviors Tuned by Magnetic Field
journal, August 2017

  • Xu, Haomin; Lin, Yuanhua; Harumoto, Takashi
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 35
  • DOI: 10.1021/acsami.7b07644

Large photoinduced ferroelectric coercive field increase and photodefined domain pattern in lithium‐tantalate crystal
journal, December 1996

  • Chao, Shiuh; Hung, Chien‐Chung
  • Applied Physics Letters, Vol. 69, Issue 25
  • DOI: 10.1063/1.117110

Influence of heat and UV light on the coercive field of lithium niobate crystals
journal, September 2010

Impact of ultraviolet light on coercive field, poling dynamics and poling quality of various lithium niobate crystals from different sources
journal, September 2004

  • Wengler, M. C.; Fassbender, B.; Soergel, E.
  • Journal of Applied Physics, Vol. 96, Issue 5
  • DOI: 10.1063/1.1776324

Surface potential of ferroelectric thin films investigated by scanning probe microscopy
journal, January 1999

  • Chen, X. Q.; Yamada, H.; Horiuchi, T.
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 17, Issue 5
  • DOI: 10.1116/1.590851

Free-Carrier-Compensated Charged Domain Walls Produced with Super-Bandgap Illumination in Insulating Ferroelectrics
journal, September 2016

  • Bednyakov, Petr; Sluka, Tomas; Tagantsev, Alexander
  • Advanced Materials, Vol. 28, Issue 43
  • DOI: 10.1002/adma.201602874

Dynamics of Photogenerated Surface Charge on BiFeO 3 Films
journal, February 2012

A new non-destructive readout by using photo-recovered surface potential contrast
journal, November 2014

  • Wang, Le; Jin, Kui-juan; Gu, Jun-xing
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06980

Long-time relaxation of photo-induced influence on BiFeO 3 thin films
journal, November 2015

  • Gu, Jun-xing; Jin, Kui-juan; Wang, Le
  • Journal of Applied Physics, Vol. 118, Issue 20
  • DOI: 10.1063/1.4936306

Mixed electrochemical–ferroelectric states in nanoscale ferroelectrics
journal, May 2017

  • Yang, Sang Mo; Morozovska, Anna N.; Kumar, Rajeev
  • Nature Physics, Vol. 13, Issue 8
  • DOI: 10.1038/nphys4103

Nanoscale Bandgap Tuning across an Inhomogeneous Ferroelectric Interface
journal, July 2017

  • Wang, Jing; Huang, Houbing; He, Wangqiang
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 29
  • DOI: 10.1021/acsami.7b05138

Persistent Photoconductivity in Strained Epitaxial BiFeO 3 Thin Films
journal, August 2014

  • Bhatnagar, Akash; Kim, Young Heon; Hesse, Dietrich
  • Nano Letters, Vol. 14, Issue 9
  • DOI: 10.1021/nl502183j

Above-Bandgap Photovoltages in Antiferroelectrics
journal, September 2016

  • Pérez-Tomás, Amador; Lira-Cantú, Monica; Catalan, Gustau
  • Advanced Materials, Vol. 28, Issue 43
  • DOI: 10.1002/adma.201603176

Physics and Applications of Bismuth Ferrite
journal, June 2009

Photoconductivity in BiFeO3 thin films
journal, March 2008

  • Basu, S. R.; Martin, L. W.; Chu, Y. H.
  • Applied Physics Letters, Vol. 92, Issue 9
  • DOI: 10.1063/1.2887908

Ferroelectric BiFeO 3 as an Oxide Dye in Highly Tunable Mesoporous All-Oxide Photovoltaic Heterojunctions
journal, October 2016

Growth by laser ablation of Y2O3 and Tm∶Y2O3 thin films for optical applications
journal, January 2000

  • Huignard, Arnaud; Aron, Astrid; Aschehoug, Patrick
  • Journal of Materials Chemistry, Vol. 10, Issue 2
  • DOI: 10.1039/a904710g

Critical radii of ferroelectric domains for different decay processes in LiNbO3 crystals
journal, September 2007

  • Kan, Yi; Lu, Xiaomei; Bo, Huifeng
  • Applied Physics Letters, Vol. 91, Issue 13
  • DOI: 10.1063/1.2790475

Local polarization dynamics in ferroelectric materials
journal, April 2010

  • Kalinin, Sergei V.; Morozovska, Anna N.; Chen, Long Qing
  • Reports on Progress in Physics, Vol. 73, Issue 5, Article No. 056502
  • DOI: 10.1088/0034-4885/73/5/056502

Bulk Photovoltaic Effect at Visible Wavelength in Epitaxial Ferroelectric BiFeO 3 Thin Films
journal, April 2010

Non-volatile memory based on the ferroelectric photovoltaic effect
journal, June 2013

  • Guo, Rui; You, Lu; Zhou, Yang
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2990

Spatial Separation of Photochemical Oxidation and Reduction Reactions on the Surface of Ferroelectric BaTiO 3
journal, September 2001

  • Giocondi, Jennifer L.; Rohrer, Gregory S.
  • The Journal of Physical Chemistry B, Vol. 105, Issue 35
  • DOI: 10.1021/jp011804j

Photochemistry on a polarisable semi-conductor: what do we understand today?
journal, October 2009

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    Works referencing / citing this record:

    Progress in BiFeO 3 -based heterostructures: materials, properties and applications
    journal, January 2020

    High performance bulk photovoltaics in narrow-bandgap centrosymmetric ultrathin films
    journal, January 2020

    • Mai, Haoxin; Lu, Teng; Sun, Qingbo
    • Materials Horizons, Vol. 7, Issue 3
    • DOI: 10.1039/c9mh01744e
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