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Title: High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials

Abstract

Supercapacitors with fast charge/discharge rate and long cycling stability (>50 000 cycles) are attractive for energy storage and mobile power supply. In this paper, a facile strategy is developed to fabricate an Fe2O3/FeS–decorated N, S–codoped hierarchical porous carbon hybrid. Its microstructure and compositions can be readily controlled through adjusting the hydrothermal reaction between waxberry and iron sulfate. The constructed supercapacitors with the as–prepared carbon materials from this reaction are able to exhibit outstanding capacitive performance with a superfast charge/discharge rate (<1 s), ultralong cycle life (>50 000 cycles, 80 A g–1), ultrahigh volumetric capacitance (1320.4 F cm–3, 0.1 A g–1), and high energy density (100.9 W h kg–1, 221.9 W h L–1). The outstanding performance makes it one of the best biomass–derived supercapacitors. The superior capacitive behavior is likely to arise from the N and S codoping on the surface/edge/skeleton of the carbon microspheres and nanosheet composites coupled with the fast redox reaction of Fe2O3/FeS. Altogether, this research presents a new avenue for developing the next generation of sustainable high–performance energy storage device.

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [1];  [1];  [3]; ORCiD logo [2]
  1. Wenzhou Univ., Zhejiang (China)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Wenzhou Univ., Zhejiang (China); Univ. of Windsor, Windsor, ON (Canada)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Natural Science Foundation of China (NNSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
OSTI Identifier:
1466369
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 8; Journal Issue: 11; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; biomass; fast charging/discharging; heteroatom doped; long life; supercapacitors

Citation Formats

Dong, Xiaomei, Jin, Huile, Wang, Rongyue, Zhang, Jingjing, Feng, Xin, Yan, Chengzhan, Chen, Suqin, Wang, Shun, Wang, Jichang, and Lu, Jun. High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials. United States: N. p., 2018. Web. doi:10.1002/aenm.201702695.
Dong, Xiaomei, Jin, Huile, Wang, Rongyue, Zhang, Jingjing, Feng, Xin, Yan, Chengzhan, Chen, Suqin, Wang, Shun, Wang, Jichang, & Lu, Jun. High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials. United States. doi:10.1002/aenm.201702695.
Dong, Xiaomei, Jin, Huile, Wang, Rongyue, Zhang, Jingjing, Feng, Xin, Yan, Chengzhan, Chen, Suqin, Wang, Shun, Wang, Jichang, and Lu, Jun. Fri . "High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials". United States. doi:10.1002/aenm.201702695. https://www.osti.gov/servlets/purl/1466369.
@article{osti_1466369,
title = {High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials},
author = {Dong, Xiaomei and Jin, Huile and Wang, Rongyue and Zhang, Jingjing and Feng, Xin and Yan, Chengzhan and Chen, Suqin and Wang, Shun and Wang, Jichang and Lu, Jun},
abstractNote = {Supercapacitors with fast charge/discharge rate and long cycling stability (>50 000 cycles) are attractive for energy storage and mobile power supply. In this paper, a facile strategy is developed to fabricate an Fe2O3/FeS–decorated N, S–codoped hierarchical porous carbon hybrid. Its microstructure and compositions can be readily controlled through adjusting the hydrothermal reaction between waxberry and iron sulfate. The constructed supercapacitors with the as–prepared carbon materials from this reaction are able to exhibit outstanding capacitive performance with a superfast charge/discharge rate (<1 s), ultralong cycle life (>50 000 cycles, 80 A g–1), ultrahigh volumetric capacitance (1320.4 F cm–3, 0.1 A g–1), and high energy density (100.9 W h kg–1, 221.9 W h L–1). The outstanding performance makes it one of the best biomass–derived supercapacitors. The superior capacitive behavior is likely to arise from the N and S codoping on the surface/edge/skeleton of the carbon microspheres and nanosheet composites coupled with the fast redox reaction of Fe2O3/FeS. Altogether, this research presents a new avenue for developing the next generation of sustainable high–performance energy storage device.},
doi = {10.1002/aenm.201702695},
journal = {Advanced Energy Materials},
number = 11,
volume = 8,
place = {United States},
year = {2018},
month = {1}
}

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