High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials

doi:10.1002/aenm.201702695

Title: High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials

Abstract

Supercapacitors with fast charge/discharge rate and long cycling stability (>50 000 cycles) are attractive for energy storage and mobile power supply. In this paper, a facile strategy is developed to fabricate an Fe ₂O ₃/FeS–decorated N, S–codoped hierarchical porous carbon hybrid. Its microstructure and compositions can be readily controlled through adjusting the hydrothermal reaction between waxberry and iron sulfate. The constructed supercapacitors with the as–prepared carbon materials from this reaction are able to exhibit outstanding capacitive performance with a superfast charge/discharge rate (<1 s), ultralong cycle life (>50 000 cycles, 80 A g ^–1), ultrahigh volumetric capacitance (1320.4 F cm ^–3, 0.1 A g ^–1), and high energy density (100.9 W h kg ^–1, 221.9 W h L ^–1). The outstanding performance makes it one of the best biomass–derived supercapacitors. The superior capacitive behavior is likely to arise from the N and S codoping on the surface/edge/skeleton of the carbon microspheres and nanosheet composites coupled with the fast redox reaction of Fe ₂O ₃/FeS. Altogether, this research presents a new avenue for developing the next generation of sustainable high–performance energy storage device.

Authors:

Dong, Xiaomei ^[1]; Jin, Huile ^[1]; Wang, Rongyue ^[2]; Zhang, Jingjing ^[1]; Feng, Xin ^[1]; Yan, Chengzhan ^[1]; Chen, Suqin ^[1]; Wang, Shun ^[1]; Wang, Jichang ^[3];

^[2]

Wenzhou Univ., Zhejiang (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Wenzhou Univ., Zhejiang (China); Univ. of Windsor, Windsor, ON (Canada)

Publication Date:: 2018-01-19

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: National Natural Science Foundation of China (NNSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

OSTI Identifier:: 1466369

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Energy Materials

Additional Journal Information:: Journal Volume: 8; Journal Issue: 11; Journal ID: ISSN 1614-6832

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; biomass; fast charging/discharging; heteroatom doped; long life; supercapacitors

Citation Formats


                    Dong, Xiaomei, Jin, Huile, Wang, Rongyue, Zhang, Jingjing, Feng, Xin, Yan, Chengzhan, Chen, Suqin, Wang, Shun, Wang, Jichang, and Lu, Jun. High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials.  United States: N. p., 2018. 
        Web.  doi:10.1002/aenm.201702695.

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                    Dong, Xiaomei, Jin, Huile, Wang, Rongyue, Zhang, Jingjing, Feng, Xin, Yan, Chengzhan, Chen, Suqin, Wang, Shun, Wang, Jichang, & Lu, Jun. High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials.  United States.  doi:10.1002/aenm.201702695.

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                    Dong, Xiaomei, Jin, Huile, Wang, Rongyue, Zhang, Jingjing, Feng, Xin, Yan, Chengzhan, Chen, Suqin, Wang, Shun, Wang, Jichang, and Lu, Jun. Fri .  
        "High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials".  United States.  doi:10.1002/aenm.201702695.  https://www.osti.gov/servlets/purl/1466369.

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@article{osti_1466369,

  title        = {High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials},

  author       = {Dong, Xiaomei and Jin, Huile and Wang, Rongyue and Zhang, Jingjing and Feng, Xin and Yan, Chengzhan and Chen, Suqin and Wang, Shun and Wang, Jichang and Lu, Jun},

  abstractNote = {Supercapacitors with fast charge/discharge rate and long cycling stability (>50 000 cycles) are attractive for energy storage and mobile power supply. In this paper, a facile strategy is developed to fabricate an Fe2O3/FeS–decorated N, S–codoped hierarchical porous carbon hybrid. Its microstructure and compositions can be readily controlled through adjusting the hydrothermal reaction between waxberry and iron sulfate. The constructed supercapacitors with the as–prepared carbon materials from this reaction are able to exhibit outstanding capacitive performance with a superfast charge/discharge rate (<1 s), ultralong cycle life (>50 000 cycles, 80 A g–1), ultrahigh volumetric capacitance (1320.4 F cm–3, 0.1 A g–1), and high energy density (100.9 W h kg–1, 221.9 W h L–1). The outstanding performance makes it one of the best biomass–derived supercapacitors. The superior capacitive behavior is likely to arise from the N and S codoping on the surface/edge/skeleton of the carbon microspheres and nanosheet composites coupled with the fast redox reaction of Fe2O3/FeS. Altogether, this research presents a new avenue for developing the next generation of sustainable high–performance energy storage device.},

  doi          = {10.1002/aenm.201702695},

  journal      = {Advanced Energy Materials},

  number       = 11,

  volume       = 8,

  place        = {United States},

  year         = {2018},

  month        = {1}

}

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DOI: 10.1002/aenm.201702695

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Works referenced in this record:

Human hair-derived carbon flakes for electrochemical supercapacitors
journal, January 2014

Qian, Wenjing; Sun, Fengxia; Xu, Yanhui
Energy & Environmental Science, Vol. 7, Issue 1, p. 379-386
DOI: 10.1039/C3EE43111H

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Title: High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials

Abstract

Citation Formats

Human hair-derived carbon flakes for electrochemical supercapacitors journal, January 2014

Human hair-derived carbon flakes for electrochemical supercapacitors
journal, January 2014