Electrochemical Lithium Doping Induced Property Changes In Halide Perovskite CsPbBr3 Crystal

Jiang, Qinglong; Zeng, Xiaoqiao; Wang, Ning; Xiao, Zhili; Guo, Zhanhu; Lu, Jun

doi:10.1021/acsenergylett.7b01230

Title: Electrochemical Lithium Doping Induced Property Changes In Halide Perovskite CsPbBr₃ Crystal

Journal Article · 28 December 2017 · ACS Energy Letters

DOI: https://doi.org/10.1021/acsenergylett.7b01230 · OSTI ID:1466317

Jiang, Qinglong ^[1]; Zeng, Xiaoqiao ^[1]; Wang, Ning ^[2];

^[1];

^[3];

^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)
Hainan Univ., Haikou (People's Republic of China); Jiangsu Univ. of Science and Technology, Jiangsu (People's Republic of China)
Univ. of Tennessee, Knoxville, TN (United States)

Electrochemical doping was used to dope lithium into perovskite CsPbBr₃ crystal. Due to the doping, diamagnetic behavior was observed with a transition temperature (T_c) of 7.17 K. Burstein-Moss effect related photoluminescence (PL) blue-shift was observed as long as 15 nm. UV-vis-NIR spectra indicate that the absorption has been enhanced. As a result, the doped CsPbBr₃ crystal generated 8 nA photocurrent, which is higher than the undoped CsPbBr₃ crystal.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1466317

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 1 Vol. 3; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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