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This content will become publicly available on June 19, 2019

Title: Compositional and structural insights into the nature of the H-cluster precursor on HydF

Spectroscopic and computational characterization of loaded HydF reveals that the 2Fe subcluster is a coordinatively saturated Fe( i )–Fe( i ) species that contains 4 CO and 2 CN ligands, and is anchored to HydF via coordination to a [4Fe–4S] cluster.
Authors:
 [1] ; ORCiD logo [1] ;  [2] ;  [2] ;  [1] ; ORCiD logo [2] ;  [1] ;  [1] ; ORCiD logo [1]
  1. Montana State Univ., Bozeman, MT (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Report Number(s):
NREL/JA-2700-71169
Journal ID: ISSN 1477-9226; ICHBD9
Grant/Contract Number:
AC36-08GO28308; AC36-08-GO28308; SC0005404
Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 47; Journal Issue: 28; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Research Org:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS; [FeFe]-hydrogenases; spectroscopy
OSTI Identifier:
1466185
Alternate Identifier(s):
OSTI ID: 1458586