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Title: Alignment, orientation, and Coulomb explosion of difluoroiodobenzene studied with the pixel imaging mass spectrometry (PImMS) camera

Laser-induced adiabatic alignment and mixed-field orientation of 2,6-difluoroiodobenzene (C 6H 3F 2I) molecules are probed by Coulomb explosion imaging following either near-infrared strong-field ionization or extreme-ultraviolet multi-photon inner-shell ionization using free-electron laser pulses. The resulting photoelectrons and fragment ions are captured by a double-sided velocity map imaging spectrometer and projected onto two position-sensitive detectors. The ion side of the spectrometer is equipped with a pixel imaging mass spectrometry camera, a time-stamping pixelated detector that can record the hit positions and arrival times of up to four ions per pixel per acquisition cycle. Thus, the time-of-flight trace and ion momentum distributions for all fragments can be recorded simultaneously. Finally, we show that we can obtain a high degree of one-and three-dimensional alignment and mixed-field orientation and compare the Coulomb explosion process induced at both wavelengths
Authors:
 [1] ; ORCiD logo [2] ;  [1] ;  [1] ;  [1] ;  [3] ;  [4] ;  [2] ;  [2] ; ORCiD logo [5] ;  [6] ;  [2] ;  [2] ;  [2] ;  [7] ; ORCiD logo [8] ;  [9] ;  [4] ; ORCiD logo [9] ;  [10] more »;  [2] ;  [2] ;  [4] ;  [2] ;  [3] ;  [11] ;  [2] ;  [2] ;  [9] ;  [10] ;  [2] ;  [1] ;  [5] ;  [3] ;  [1] ;  [12] « less
  1. Univ. of Oxford, Oxford (United Kingdom)
  2. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
  3. Aarhus Univ., Aarhus (Denmark)
  4. Max-Born-Institut fur Nichtlineare Optik und Kurzzeitspektroskopie, Berlin (Germany)
  5. Kansas State Univ., Manhattan, KS (United States)
  6. Univ. of Connecticut, Storrs, CT (United States)
  7. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Carl von Ossietzky Univ., Oldenburg (Germany)
  8. Lund Univ., Lund (Sweden)
  9. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Univ. Hamburg, Hamburg (Germany)
  10. Technische Univ. Berlin, Berlin (Germany)
  11. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Max Planck Institute for Biophysical Chemistry, Gottingen (Germany); Gottingen Univ., Gottingen (Germany)
  12. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Kansas State Univ., Manhattan, KS (United States)
Publication Date:
Grant/Contract Number:
FG02-86ER13491
Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 147; Journal Issue: 1; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Research Org:
Kansas State Univ., Manhattan, KS (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1465986
Alternate Identifier(s):
OSTI ID: 1361855

Amini, Kasra, Boll, Rebecca, Lauer, Alexandra, Burt, Michael, Lee, Jason W. L., Christensen, Lauge, Brauβe, Felix, Mullins, Terence, Savelyev, Evgeny, Ablikim, Utuq, Berrah, Nora, Bomme, Cedric, Dusterer, Stefan, Erk, Benjamin, Hoppner, Hauke, Johnsson, Per, Kierspel, Thomas, Krecinic, Faruk, Kupper, Jochen, Muller, Maria, Muller, Erland, Redlin, Harald, Rouzee, Arnaud, Schirmel, Nora, Thogersen, Jan, Techert, Simone, Toleikis, Sven, Treusch, Rolf, Trippel, Sebastian, Ulmer, Anatoli, Wiese, Joss, Vallance, Claire, Rudenko, Artem, Stapelfeldt, Henrik, Brouard, Mark, and Rolles, Daniel. Alignment, orientation, and Coulomb explosion of difluoroiodobenzene studied with the pixel imaging mass spectrometry (PImMS) camera. United States: N. p., Web. doi:10.1063/1.4982220.
Amini, Kasra, Boll, Rebecca, Lauer, Alexandra, Burt, Michael, Lee, Jason W. L., Christensen, Lauge, Brauβe, Felix, Mullins, Terence, Savelyev, Evgeny, Ablikim, Utuq, Berrah, Nora, Bomme, Cedric, Dusterer, Stefan, Erk, Benjamin, Hoppner, Hauke, Johnsson, Per, Kierspel, Thomas, Krecinic, Faruk, Kupper, Jochen, Muller, Maria, Muller, Erland, Redlin, Harald, Rouzee, Arnaud, Schirmel, Nora, Thogersen, Jan, Techert, Simone, Toleikis, Sven, Treusch, Rolf, Trippel, Sebastian, Ulmer, Anatoli, Wiese, Joss, Vallance, Claire, Rudenko, Artem, Stapelfeldt, Henrik, Brouard, Mark, & Rolles, Daniel. Alignment, orientation, and Coulomb explosion of difluoroiodobenzene studied with the pixel imaging mass spectrometry (PImMS) camera. United States. doi:10.1063/1.4982220.
Amini, Kasra, Boll, Rebecca, Lauer, Alexandra, Burt, Michael, Lee, Jason W. L., Christensen, Lauge, Brauβe, Felix, Mullins, Terence, Savelyev, Evgeny, Ablikim, Utuq, Berrah, Nora, Bomme, Cedric, Dusterer, Stefan, Erk, Benjamin, Hoppner, Hauke, Johnsson, Per, Kierspel, Thomas, Krecinic, Faruk, Kupper, Jochen, Muller, Maria, Muller, Erland, Redlin, Harald, Rouzee, Arnaud, Schirmel, Nora, Thogersen, Jan, Techert, Simone, Toleikis, Sven, Treusch, Rolf, Trippel, Sebastian, Ulmer, Anatoli, Wiese, Joss, Vallance, Claire, Rudenko, Artem, Stapelfeldt, Henrik, Brouard, Mark, and Rolles, Daniel. 2017. "Alignment, orientation, and Coulomb explosion of difluoroiodobenzene studied with the pixel imaging mass spectrometry (PImMS) camera". United States. doi:10.1063/1.4982220. https://www.osti.gov/servlets/purl/1465986.
@article{osti_1465986,
title = {Alignment, orientation, and Coulomb explosion of difluoroiodobenzene studied with the pixel imaging mass spectrometry (PImMS) camera},
author = {Amini, Kasra and Boll, Rebecca and Lauer, Alexandra and Burt, Michael and Lee, Jason W. L. and Christensen, Lauge and Brauβe, Felix and Mullins, Terence and Savelyev, Evgeny and Ablikim, Utuq and Berrah, Nora and Bomme, Cedric and Dusterer, Stefan and Erk, Benjamin and Hoppner, Hauke and Johnsson, Per and Kierspel, Thomas and Krecinic, Faruk and Kupper, Jochen and Muller, Maria and Muller, Erland and Redlin, Harald and Rouzee, Arnaud and Schirmel, Nora and Thogersen, Jan and Techert, Simone and Toleikis, Sven and Treusch, Rolf and Trippel, Sebastian and Ulmer, Anatoli and Wiese, Joss and Vallance, Claire and Rudenko, Artem and Stapelfeldt, Henrik and Brouard, Mark and Rolles, Daniel},
abstractNote = {Laser-induced adiabatic alignment and mixed-field orientation of 2,6-difluoroiodobenzene (C6H3F2I) molecules are probed by Coulomb explosion imaging following either near-infrared strong-field ionization or extreme-ultraviolet multi-photon inner-shell ionization using free-electron laser pulses. The resulting photoelectrons and fragment ions are captured by a double-sided velocity map imaging spectrometer and projected onto two position-sensitive detectors. The ion side of the spectrometer is equipped with a pixel imaging mass spectrometry camera, a time-stamping pixelated detector that can record the hit positions and arrival times of up to four ions per pixel per acquisition cycle. Thus, the time-of-flight trace and ion momentum distributions for all fragments can be recorded simultaneously. Finally, we show that we can obtain a high degree of one-and three-dimensional alignment and mixed-field orientation and compare the Coulomb explosion process induced at both wavelengths},
doi = {10.1063/1.4982220},
journal = {Journal of Chemical Physics},
number = 1,
volume = 147,
place = {United States},
year = {2017},
month = {5}
}

Works referenced in this record:

Femtochemistry: Atomic-Scale Dynamics of the Chemical Bond Using Ultrafast Lasers (Nobel Lecture)
journal, August 2000