Rare earth separations by selective borate crystallization

Yin, Xuemiao; Wang, Yaxing; Bai, Xiaojing; Wang, Yumin; Chen, Lanhua; Xiao, Chengliang; Diwu, Juan; Du, Shiyu; Chai, Zhifang; Albrecht-Schmitt, Thomas E.; Wang, Shuao

doi:10.1038/ncomms14438

Title: Rare earth separations by selective borate crystallization

Journal Article · 14 March 2017 · Nature Communications

DOI: https://doi.org/10.1038/ncomms14438 · OSTI ID:1465711

Yin, Xuemiao ^[1]; Wang, Yaxing ^[2]; Bai, Xiaojing ^[3]; Wang, Yumin ^[2]; Chen, Lanhua ^[2]; Xiao, Chengliang ^[2]; Diwu, Juan ^[2]; Du, Shiyu ^[3]; Chai, Zhifang ^[2]; Albrecht-Schmitt, Thomas E. ^[4]; Wang, Shuao ^[2]

Soochow Univ. and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Suzhou (China). School for Radiological and Interdisciplinary Sciences; Chinese Academy of Sciences, Zhejiang (China)
Soochow Univ. and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Suzhou (China). School for Radiological and Interdisciplinary Sciences
Chinese Academy of Sciences (CAS), Beijing (China). Engineering Lab. of Specialty Fibers and Nuclear Energy Materials
Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry

Lanthanides possess similar chemical properties rendering their separation from one another a challenge of fundamental chemical and global importance given their incorporation into many advanced technologies. New separation strategies combining green chemistry with low cost and high efficiency remain highly desirable. We demonstrate that the subtle bonding differences among trivalent lanthanides can be amplified during the crystallization of borates, providing chemical recognition of specific lanthanides that originates from Ln³⁺ coordination alterations, borate polymerization diversity and soft ligand coordination selectivity. Six distinct phases are obtained under identical reaction conditions across lanthanide series, further leading to an efficient and cost-effective separation strategy via selective crystallization. As proof of concept, Nd/Sm and Nd/Dy are used as binary models to demonstrate solid/aqueous and solid/solid separation processes. Controlling the reaction kinetics gives rise to enhanced separation efficiency of Nd/Sm system and a one-step quantitative separation of Nd/Dy with the aid of selective density-based flotation.

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Research Organization:: Florida State Univ., Tallahassee, FL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0010677; SC0010677

OSTI ID:: 1465711

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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