Transmission in situ and operando high temperature X-ray powder diffraction in variable gaseous environments
Abstract
In this paper, we describe a device for time-resolved synchrotron-based in situ and operando X-ray powder diffraction measurements at elevated temperatures under controllable gaseous environments. The respective gaseous sample environment is realized via a gas-tight capillary-in-capillary design, where the gas flow is achieved through an open-end 0.5 mm capillary located inside a 0.7 mm capillary filled with a sample powder. Thermal mass flow controllers provide appropriate gas flows and computer-controlled on-the-fly gas mixing capabilities. The capillary system is centered inside an infrared heated, proportional integral differential-controlled capillary furnace allowing access to temperatures up to 1000 °C.
- Authors:
-
[1];
[2];
- Technische Universität Berlin (Germany). Fachgebiet Keramische Werkstoffe / Chair of Advanced Ceramic Materials, Institut für Werkstoffwissenschaften- und Technologien
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- University of Innsbruck (Austria). Institute of Physical Chemistry
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1465703
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Review of Scientific Instruments
- Additional Journal Information:
- Journal Volume: 89; Journal Issue: 3; Related Information: © 2018 Author(s).; Journal ID: ISSN 0034-6748
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 47 OTHER INSTRUMENTATION; 36 MATERIALS SCIENCE
Citation Formats
Schlicker, Lukas, Doran, Andrew, Schneppmüller, Peter, Gili, Albert, Czasny, Mathias, Penner, Simon, and Gurlo, Aleksander. Transmission in situ and operando high temperature X-ray powder diffraction in variable gaseous environments. United States: N. p., 2018.
Web. doi:10.1063/1.5001695.
Schlicker, Lukas, Doran, Andrew, Schneppmüller, Peter, Gili, Albert, Czasny, Mathias, Penner, Simon, & Gurlo, Aleksander. Transmission in situ and operando high temperature X-ray powder diffraction in variable gaseous environments. United States. https://doi.org/10.1063/1.5001695
Schlicker, Lukas, Doran, Andrew, Schneppmüller, Peter, Gili, Albert, Czasny, Mathias, Penner, Simon, and Gurlo, Aleksander. Tue .
"Transmission in situ and operando high temperature X-ray powder diffraction in variable gaseous environments". United States. https://doi.org/10.1063/1.5001695. https://www.osti.gov/servlets/purl/1465703.
@article{osti_1465703,
title = {Transmission in situ and operando high temperature X-ray powder diffraction in variable gaseous environments},
author = {Schlicker, Lukas and Doran, Andrew and Schneppmüller, Peter and Gili, Albert and Czasny, Mathias and Penner, Simon and Gurlo, Aleksander},
abstractNote = {In this paper, we describe a device for time-resolved synchrotron-based in situ and operando X-ray powder diffraction measurements at elevated temperatures under controllable gaseous environments. The respective gaseous sample environment is realized via a gas-tight capillary-in-capillary design, where the gas flow is achieved through an open-end 0.5 mm capillary located inside a 0.7 mm capillary filled with a sample powder. Thermal mass flow controllers provide appropriate gas flows and computer-controlled on-the-fly gas mixing capabilities. The capillary system is centered inside an infrared heated, proportional integral differential-controlled capillary furnace allowing access to temperatures up to 1000 °C.},
doi = {10.1063/1.5001695},
journal = {Review of Scientific Instruments},
number = 3,
volume = 89,
place = {United States},
year = {Tue Mar 06 00:00:00 EST 2018},
month = {Tue Mar 06 00:00:00 EST 2018}
}
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Cited by: 24 works
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Figures / Tables:
Figure 1: Flow chart of the experimental setup (a) and a photograph of the capillary-in-capillary gas-injection setup and capillary furnace as installed at the beamline (b).
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Works referenced in this record:
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Works referencing / citing this record:
On the structural stability of crystalline ceria phases in undoped and acceptor-doped ceria materials under in situ reduction conditions
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- Bekheet, Maged F.; Grünbacher, Matthias; Schlicker, Lukas
- CrystEngComm, Vol. 21, Issue 1
Crystallographic and electronic evolution of lanthanum strontium ferrite (La 0.6 Sr 0.4 FeO 3−δ ) thin film and bulk model systems during iron exsolution
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- Götsch, Thomas; Köpfle, Norbert; Grünbacher, Matthias
- Physical Chemistry Chemical Physics, Vol. 21, Issue 7
Reactive metal-support interaction in the Cu-In 2 O 3 system: intermetallic compound formation and its consequences for CO 2 -selective methanol steam reforming
journal, April 2019
- Ploner, Kevin; Schlicker, Lukas; Gili, Albert
- Science and Technology of Advanced Materials, Vol. 20, Issue 1
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.