Multi-Tasking POM Systems
Abstract
Polyoxometalate (POM)-based materials of current interest are summarized, and specific types of POM-containing systems are described in which material facilitates multiple complex interactions or catalytic processes. We specifically highlight POM-containing multi-hydrogen-bonding polymers that form gels upon exposure to select organic liquids and simultaneously catalyze hydrolytic or oxidative decontamination, as well as water oxidation catalysts (WOCs) that can be interfaced with light-absorbing photoelectrode materials for photoelectrocatalytic water splitting.
- Authors:
- Publication Date:
- Research Org.:
- Emory Univ., Atlanta, GA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Defense Threat Reduction Agency (DTRA) (United States)
- OSTI Identifier:
- 1465604
- Alternate Identifier(s):
- OSTI ID: 1510430
- Grant/Contract Number:
- FG02-07ER15906; HDTRA1-16-1-0029
- Resource Type:
- Published Article
- Journal Name:
- Frontiers in Chemistry
- Additional Journal Information:
- Journal Name: Frontiers in Chemistry Journal Volume: 6; Journal ID: ISSN 2296-2646
- Publisher:
- Frontiers Media SA
- Country of Publication:
- Switzerland
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; polyoxometalates (POMs); heterogeneous catalysis; multi-functional polymers; catalytic water oxidation; photoelectrochemical water splitting
Citation Formats
Sullivan, Kevin P., Yin, Qiushi, Collins-Wildman, Daniel L., Tao, Meilin, Geletii, Yurii V., Musaev, Djamaladdin G., Lian, Tianquan, and Hill, Craig L. Multi-Tasking POM Systems. Switzerland: N. p., 2018.
Web. doi:10.3389/fchem.2018.00365.
Sullivan, Kevin P., Yin, Qiushi, Collins-Wildman, Daniel L., Tao, Meilin, Geletii, Yurii V., Musaev, Djamaladdin G., Lian, Tianquan, & Hill, Craig L. Multi-Tasking POM Systems. Switzerland. https://doi.org/10.3389/fchem.2018.00365
Sullivan, Kevin P., Yin, Qiushi, Collins-Wildman, Daniel L., Tao, Meilin, Geletii, Yurii V., Musaev, Djamaladdin G., Lian, Tianquan, and Hill, Craig L. Tue .
"Multi-Tasking POM Systems". Switzerland. https://doi.org/10.3389/fchem.2018.00365.
@article{osti_1465604,
title = {Multi-Tasking POM Systems},
author = {Sullivan, Kevin P. and Yin, Qiushi and Collins-Wildman, Daniel L. and Tao, Meilin and Geletii, Yurii V. and Musaev, Djamaladdin G. and Lian, Tianquan and Hill, Craig L.},
abstractNote = {Polyoxometalate (POM)-based materials of current interest are summarized, and specific types of POM-containing systems are described in which material facilitates multiple complex interactions or catalytic processes. We specifically highlight POM-containing multi-hydrogen-bonding polymers that form gels upon exposure to select organic liquids and simultaneously catalyze hydrolytic or oxidative decontamination, as well as water oxidation catalysts (WOCs) that can be interfaced with light-absorbing photoelectrode materials for photoelectrocatalytic water splitting.},
doi = {10.3389/fchem.2018.00365},
journal = {Frontiers in Chemistry},
number = ,
volume = 6,
place = {Switzerland},
year = {Tue Aug 21 00:00:00 EDT 2018},
month = {Tue Aug 21 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
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https://doi.org/10.3389/fchem.2018.00365
https://doi.org/10.3389/fchem.2018.00365
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Cited by: 15 works
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Figures / Tables:
FIGURE 1: | Some uses and ongoing research efforts involving POMs in materials.
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