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Title: Multi-Tasking POM Systems

Abstract

Polyoxometalate (POM)-based materials of current interest are summarized, and specific types of POM-containing systems are described in which material facilitates multiple complex interactions or catalytic processes. We specifically highlight POM-containing multi-hydrogen-bonding polymers that form gels upon exposure to select organic liquids and simultaneously catalyze hydrolytic or oxidative decontamination, as well as water oxidation catalysts (WOCs) that can be interfaced with light-absorbing photoelectrode materials for photoelectrocatalytic water splitting.

Authors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Emory Univ., Atlanta, GA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Defense Threat Reduction Agency (DTRA) (United States)
OSTI Identifier:
1465604
Alternate Identifier(s):
OSTI ID: 1510430
Grant/Contract Number:  
FG02-07ER15906; HDTRA1-16-1-0029
Resource Type:
Published Article
Journal Name:
Frontiers in Chemistry
Additional Journal Information:
Journal Name: Frontiers in Chemistry Journal Volume: 6; Journal ID: ISSN 2296-2646
Publisher:
Frontiers Media SA
Country of Publication:
Switzerland
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; polyoxometalates (POMs); heterogeneous catalysis; multi-functional polymers; catalytic water oxidation; photoelectrochemical water splitting

Citation Formats

Sullivan, Kevin P., Yin, Qiushi, Collins-Wildman, Daniel L., Tao, Meilin, Geletii, Yurii V., Musaev, Djamaladdin G., Lian, Tianquan, and Hill, Craig L. Multi-Tasking POM Systems. Switzerland: N. p., 2018. Web. doi:10.3389/fchem.2018.00365.
Sullivan, Kevin P., Yin, Qiushi, Collins-Wildman, Daniel L., Tao, Meilin, Geletii, Yurii V., Musaev, Djamaladdin G., Lian, Tianquan, & Hill, Craig L. Multi-Tasking POM Systems. Switzerland. doi:10.3389/fchem.2018.00365.
Sullivan, Kevin P., Yin, Qiushi, Collins-Wildman, Daniel L., Tao, Meilin, Geletii, Yurii V., Musaev, Djamaladdin G., Lian, Tianquan, and Hill, Craig L. Tue . "Multi-Tasking POM Systems". Switzerland. doi:10.3389/fchem.2018.00365.
@article{osti_1465604,
title = {Multi-Tasking POM Systems},
author = {Sullivan, Kevin P. and Yin, Qiushi and Collins-Wildman, Daniel L. and Tao, Meilin and Geletii, Yurii V. and Musaev, Djamaladdin G. and Lian, Tianquan and Hill, Craig L.},
abstractNote = {Polyoxometalate (POM)-based materials of current interest are summarized, and specific types of POM-containing systems are described in which material facilitates multiple complex interactions or catalytic processes. We specifically highlight POM-containing multi-hydrogen-bonding polymers that form gels upon exposure to select organic liquids and simultaneously catalyze hydrolytic or oxidative decontamination, as well as water oxidation catalysts (WOCs) that can be interfaced with light-absorbing photoelectrode materials for photoelectrocatalytic water splitting.},
doi = {10.3389/fchem.2018.00365},
journal = {Frontiers in Chemistry},
number = ,
volume = 6,
place = {Switzerland},
year = {2018},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.3389/fchem.2018.00365

Citation Metrics:
Cited by: 3 works
Citation information provided by
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Figures / Tables:

FIGURE 1 FIGURE 1: | Some uses and ongoing research efforts involving POMs in materials.

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