Driving towards cost-competitive biofuels through catalytic fast pyrolysis by rethinking catalyst selection and reactor configuration
Abstract
Catalytic fast pyrolysis (CFP) has emerged as an attractive process for the conversion of lignocellulosic biomass into renewable fuels and products. Considerable research and development has focused on using circulating-bed reactors with zeolite catalysts (e.g., HZSM-5) for CFP because of their propensity to form gasoline-range aromatic hydrocarbons. However, the high selectivity for aromatics comes at the expense of low carbon yield, a key economic driver for this process. In this contribution, we evaluate non-zeolite catalysts in a fixed-bed reactor configuration for an integrated CFP process to produce fuel blendstocks from lignocellulosic biomass. These experimental efforts are coupled with technoeconomic analysis (TEA) to benchmark the process and guide research and development activities to minimize costs. The results indicate that CFP bio-oil can be produced from pine with improved yield by using a bifunctional metal-acid 2 wt% Pt/TiO2 catalyst in a fixed-bed reactor operated with co-fed H-2 at near atmospheric pressure, as compared to H-ZSM5 in a circulating-bed reactor. The Pt/TiO2 catalyst exhibited good stability over 13 reaction-regeneration cycles with no evidence of irreversible deactivation. The CFP bio-oil was continuously hydrotreated for 140 h time-on-stream using a single-stage system with 84 wt% of the hydrotreated product having a boiling point in themore »
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[2];
[1];
[1];
[1];
[1];
[1];
[1];
[1];
[3];
[1];
[1]
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States); Argonne National Laboratory (ANL), Argonne, IL (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office (BETO)
- OSTI Identifier:
- 1468521
- Alternate Identifier(s):
- OSTI ID: 1465598; OSTI ID: 1490208; OSTI ID: 1492554
- Report Number(s):
- NREL/JA-5100-71877; PNNL-SA-136791
Journal ID: ISSN 1754-5692
- Grant/Contract Number:
- AC36-08GO28308; AC02-06CH11357; AC06-76RL01830; AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Energy & Environmental Science
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 10; Journal ID: ISSN 1754-5692
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; catalytic fast pyrolysis; biomass; bio-oil
Citation Formats
Griffin, Michael B., Iisa, Kristiina, Wang, Huamin, Dutta, Abhijit, Orton, Kellene A., French, Richard J., Santosa, Daniel M., Wilson, Nolan, Christensen, Earl, Nash, Connor, Van Allsburg, Kurt M., Baddour, Frederick G., Ruddy, Daniel A., Tan, Eric C. D., Cai, Hao, Mukarakate, Calvin, and Schaidle, Joshua A. Driving towards cost-competitive biofuels through catalytic fast pyrolysis by rethinking catalyst selection and reactor configuration. United States: N. p., 2018.
Web. doi:10.1039/C8EE01872C.
Griffin, Michael B., Iisa, Kristiina, Wang, Huamin, Dutta, Abhijit, Orton, Kellene A., French, Richard J., Santosa, Daniel M., Wilson, Nolan, Christensen, Earl, Nash, Connor, Van Allsburg, Kurt M., Baddour, Frederick G., Ruddy, Daniel A., Tan, Eric C. D., Cai, Hao, Mukarakate, Calvin, & Schaidle, Joshua A. Driving towards cost-competitive biofuels through catalytic fast pyrolysis by rethinking catalyst selection and reactor configuration. United States. https://doi.org/10.1039/C8EE01872C
Griffin, Michael B., Iisa, Kristiina, Wang, Huamin, Dutta, Abhijit, Orton, Kellene A., French, Richard J., Santosa, Daniel M., Wilson, Nolan, Christensen, Earl, Nash, Connor, Van Allsburg, Kurt M., Baddour, Frederick G., Ruddy, Daniel A., Tan, Eric C. D., Cai, Hao, Mukarakate, Calvin, and Schaidle, Joshua A. Tue .
"Driving towards cost-competitive biofuels through catalytic fast pyrolysis by rethinking catalyst selection and reactor configuration". United States. https://doi.org/10.1039/C8EE01872C. https://www.osti.gov/servlets/purl/1468521.
@article{osti_1468521,
title = {Driving towards cost-competitive biofuels through catalytic fast pyrolysis by rethinking catalyst selection and reactor configuration},
author = {Griffin, Michael B. and Iisa, Kristiina and Wang, Huamin and Dutta, Abhijit and Orton, Kellene A. and French, Richard J. and Santosa, Daniel M. and Wilson, Nolan and Christensen, Earl and Nash, Connor and Van Allsburg, Kurt M. and Baddour, Frederick G. and Ruddy, Daniel A. and Tan, Eric C. D. and Cai, Hao and Mukarakate, Calvin and Schaidle, Joshua A.},
abstractNote = {Catalytic fast pyrolysis (CFP) has emerged as an attractive process for the conversion of lignocellulosic biomass into renewable fuels and products. Considerable research and development has focused on using circulating-bed reactors with zeolite catalysts (e.g., HZSM-5) for CFP because of their propensity to form gasoline-range aromatic hydrocarbons. However, the high selectivity for aromatics comes at the expense of low carbon yield, a key economic driver for this process. In this contribution, we evaluate non-zeolite catalysts in a fixed-bed reactor configuration for an integrated CFP process to produce fuel blendstocks from lignocellulosic biomass. These experimental efforts are coupled with technoeconomic analysis (TEA) to benchmark the process and guide research and development activities to minimize costs. The results indicate that CFP bio-oil can be produced from pine with improved yield by using a bifunctional metal-acid 2 wt% Pt/TiO2 catalyst in a fixed-bed reactor operated with co-fed H-2 at near atmospheric pressure, as compared to H-ZSM5 in a circulating-bed reactor. The Pt/TiO2 catalyst exhibited good stability over 13 reaction-regeneration cycles with no evidence of irreversible deactivation. The CFP bio-oil was continuously hydrotreated for 140 h time-on-stream using a single-stage system with 84 wt% of the hydrotreated product having a boiling point in the gasoline and distillate range. This integrated biomass-to-blendstock process was determined to exhibit an energy efficiency of 50% and a carbon efficiency of 38%, based on the experimental results and process modelling. TEA of the integrated process revealed a modelled minimum fuel selling price (MFSP) of $4.34 per gasoline gallon equivalent (GGE), which represents a cost reduction of $0.85 GGE(-1) compared to values reported for CFP with a zeolite catalyst. TEA also indicated that catalyst cost was a significant factor influencing the MFSP, which informed additional CFP experiments in which lower-cost Mo2C and high-dispersion 0.5 wt% Pt/TiO2 catalysts were synthesized and evaluated. These materials demonstrated CFP carbon yield and oil oxygen content similar to those of the 2 wt% Pt/TiO2 catalyst, offering proof-of-concept that the lower-cost catalysts can be effective for CFP and providing a route to reduce the modelled MFSP to $3.86-3.91 GGE(-1). This report links foundational science and applied engineering to demonstrate the potential of fixed-bed CFP and highlights the impact of coupled TEA to guide research activities towards cost reductions.},
doi = {10.1039/C8EE01872C},
journal = {Energy & Environmental Science},
number = 10,
volume = 11,
place = {United States},
year = {Tue Aug 21 00:00:00 EDT 2018},
month = {Tue Aug 21 00:00:00 EDT 2018}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 88 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Recent advances in heterogeneous catalysts for bio-oil upgrading via “ex situ catalytic fast pyrolysis”: catalyst development through the study of model compounds
journal, January 2014
- Ruddy, Daniel A.; Schaidle, Joshua A.; Ferrell III, Jack R.
- Green Chem., Vol. 16, Issue 2
Chemical Titration and Transient Kinetic Studies of Site Requirements in Mo 2 C-Catalyzed Vapor Phase Anisole Hydrodeoxygenation
journal, June 2015
- Lee, Wen-Sheng; Kumar, Anurag; Wang, Zhenshu
- ACS Catalysis, Vol. 5, Issue 7
Late-Transition-Metal-Modified β-Mo 2 C Catalysts for Enhanced Hydrogenation during Guaiacol Deoxygenation
journal, November 2017
- Baddour, Frederick G.; Witte, Vanessa A.; Nash, Connor P.
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 12
Catalytic routes for the conversion of biomass into liquid hydrocarbon transportation fuels
journal, January 2011
- Serrano-Ruiz, Juan Carlos; Dumesic, James A.
- Energy Environ. Sci., Vol. 4, Issue 1
Role of Oxophilic Supports in the Selective Hydrodeoxygenation of m-Cresol on Pd Catalysts
journal, September 2014
- de Souza, Priscilla M.; Nie, Lei; Borges, Luiz E. P.
- Catalysis Letters, Vol. 144, Issue 12
Conceptual Process Design and Techno-Economic Assessment of Ex Situ Catalytic Fast Pyrolysis of Biomass: A Fixed Bed Reactor Implementation Scenario for Future Feasibility
journal, October 2015
- Dutta, Abhijit; Schaidle, Joshua A.; Humbird, David
- Topics in Catalysis, Vol. 59, Issue 1
Zeolite-catalyzed biomass conversion to fuels and chemicals
journal, January 2011
- Taarning, Esben; Osmundsen, Christian M.; Yang, Xiaobo
- Energy Environ. Sci., Vol. 4, Issue 3
Catalytic Pyrolysis of Pine Over HZSM-5 with Different Binders
journal, October 2015
- Iisa, Kristiina; French, Richard J.; Orton, Kellene A.
- Topics in Catalysis, Vol. 59, Issue 1
Experimental and Computational Investigation of Acetic Acid Deoxygenation over Oxophilic Molybdenum Carbide: Surface Chemistry and Active Site Identity
journal, January 2016
- Schaidle, Joshua A.; Blackburn, Jeffrey; Farberow, Carrie A.
- ACS Catalysis, Vol. 6, Issue 2
Catalytic Hydroprocessing of Fast Pyrolysis Bio-oil from Pine Sawdust
journal, May 2012
- Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.
- Energy & Fuels, Vol. 26, Issue 6
Selective Hydrodeoxygenation of Guaiacol Catalyzed by Platinum Supported on Magnesium Oxide
journal, August 2012
- Nimmanwudipong, Tarit; Aydin, Ceren; Lu, Jing
- Catalysis Letters, Vol. 142, Issue 10
Characterization and Catalytic Upgrading of Aqueous Stream Carbon from Catalytic Fast Pyrolysis of Biomass
journal, November 2017
- Starace, Anne K.; Black, Brenna A.; Lee, David D.
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 12
Role of Keto Intermediates in the Hydrodeoxygenation of Phenol over Pd on Oxophilic Supports
journal, January 2015
- de Souza, Priscilla M.; Rabelo-Neto, Raimundo C.; Borges, Luiz E. P.
- ACS Catalysis, Vol. 5, Issue 2
In Situ and ex Situ Catalytic Pyrolysis of Pine in a Bench-Scale Fluidized Bed Reactor System
journal, December 2015
- Iisa, Kristiina; French, Richard J.; Orton, Kellene A.
- Energy & Fuels, Vol. 30, Issue 3
Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil
journal, August 2014
- Elliott, Douglas C.; Wang, Huamin; French, Richard
- Energy & Fuels, Vol. 28, Issue 9
Understanding the role of TiO 2 crystal structure on the enhanced activity and stability of Ru/TiO 2 catalysts for the conversion of lignin-derived oxygenates
journal, January 2014
- Omotoso, Taiwo; Boonyasuwat, Sunya; Crossley, Steven P.
- Green Chem., Vol. 16, Issue 2
Selective conversion of furfural to cyclopentanone or cyclopentanol using different preparation methods of Cu–Co catalysts
journal, January 2015
- Li, Xing-Long; Deng, Jin; Shi, Jing
- Green Chemistry, Vol. 17, Issue 2
Quantitative 13 C NMR characterization of fast pyrolysis oils
journal, January 2016
- Happs, R. M.; Iisa, K.; Ferrell III, J. R.
- RSC Advances, Vol. 6, Issue 104
Reactive catalytic fast pyrolysis of biomass to produce high-quality bio-crude
journal, January 2017
- Wang, Kaige; Dayton, David C.; Peters, Jonathan E.
- Green Chemistry, Vol. 19, Issue 14
Fast pyrolysis oil from pinewood chips co-processing with vacuum gas oil in an FCC unit for second generation fuel production
journal, January 2017
- Pinho, Andrea de Rezende; de Almeida, Marlon B. B.; Mendes, Fabio Leal
- Fuel, Vol. 188
Catalytic Fast Pyrolysis: Influencing Bio-Oil Quality with the Catalyst-to-Biomass Ratio
journal, July 2016
- Paasikallio, Ville; Kalogiannis, Konstantinos; Lappas, Angelos
- Energy Technology, Vol. 5, Issue 1
Conversion of Guaiacol over Supported Ru Catalysts
journal, June 2013
- Boonyasuwat, Sunya; Omotoso, Taiwo; Resasco, Daniel E.
- Catalysis Letters, Vol. 143, Issue 8
Oxygen removal from intact biomass to produce liquid fuel range hydrocarbons via fast-hydropyrolysis and vapor-phase catalytic hydrodeoxygenation
journal, January 2015
- Venkatakrishnan, Vinod Kumar; Delgass, W. Nicholas; Ribeiro, Fabio H.
- Green Chemistry, Vol. 17, Issue 1
Product quality and catalyst deactivation in a four day catalytic fast pyrolysis production run
journal, January 2014
- Paasikallio, Ville; Lindfors, Christian; Kuoppala, Eeva
- Green Chemistry, Vol. 16, Issue 7
Production of low-oxygen bio-oil via ex situ catalytic fast pyrolysis and hydrotreating
journal, November 2017
- Iisa, Kristiina; French, Richard J.; Orton, Kellene A.
- Fuel, Vol. 207
Overview of Applications of Biomass Fast Pyrolysis Oil
journal, March 2004
- Czernik, S.; Bridgwater, A. V.
- Energy & Fuels, Vol. 18, Issue 2, p. 590-598
Red Mud Catalytic Pyrolysis of Pinyon Juniper and Single-Stage Hydrotreatment of Oils
journal, July 2016
- Agblevor, Foster A.; Elliott, Douglas C.; Santosa, Daniel M.
- Energy & Fuels, Vol. 30, Issue 10
A fundamental study of Pt tetraammine impregnation of silica1. The electrostatic nature of platinum adsorption
journal, July 2004
- Schreier, M.
- Journal of Catalysis, Vol. 225, Issue 1
Thermochemical wastewater valorization via enhanced microbial toxicity tolerance
journal, January 2018
- Jayakody, Lahiru N.; Johnson, Christopher W.; Whitham, Jason M.
- Energy & Environmental Science, Vol. 11, Issue 6
Integrated hydropyrolysis and hydroconversion (IH 2® ) for the direct production of gasoline and diesel fuels or blending components from biomass, Part 2: continuous testing
journal, November 2013
- Marker, Terry L.; Felix, Larry G.; Linck, Martin B.
- Environmental Progress & Sustainable Energy, Vol. 33, Issue 3
Integration of catalytic fast pyrolysis and hydroprocessing: a pathway to refinery intermediates and “drop-in” fuels from biomass
journal, January 2016
- Mante, Ofei D.; Dayton, David C.; Gabrielsen, Jostein
- Green Chemistry, Vol. 18, Issue 22
Historical Developments in Hydroprocessing Bio-oils
journal, May 2007
- Elliott, Douglas C.
- Energy & Fuels, Vol. 21, Issue 3, p. 1792-1815
Insights into the catalytic activity and surface modification of MoO 3 during the hydrodeoxygenation of lignin-derived model compounds into aromatic hydrocarbons under low hydrogen pressures
journal, January 2014
- Prasomsri, Teerawit; Shetty, Manish; Murugappan, Karthick
- Energy Environ. Sci., Vol. 7, Issue 8
Advances in the study of coke formation over zeolite catalysts in the methanol-to-hydrocarbon process
journal, June 2016
- Liu, B.; Slocombe, D.; AlKinany, M.
- Applied Petrochemical Research, Vol. 6, Issue 3
Characterization of upgraded fast pyrolysis oak oil distillate fractions from sulfided and non-sulfided catalytic hydrotreating
journal, August 2017
- Olarte, Mariefel V.; Padmaperuma, Asanga B.; Ferrell, Jack R.
- Fuel, Vol. 202
An investigation into support cooperativity for the deoxygenation of guaiacol over nanoparticle Ni and Rh 2 P
journal, January 2017
- Griffin, Michael B.; Baddour, Frederick G.; Habas, Susan E.
- Catalysis Science & Technology, Vol. 7, Issue 14
Direct catalytic upgrading of biomass pyrolysis vapors by a dual function Ru/TiO 2 catalyst
journal, February 2013
- Wan, Shaolong; Pham, Trung; Zhang, Sarah
- AIChE Journal, Vol. 59, Issue 7
Mo2C catalyzed vapor phase hydrodeoxygenation of lignin-derived phenolic compound mixtures to aromatics under ambient pressure
journal, January 2016
- Chen, Cha-Jung; Lee, Wen-Sheng; Bhan, Aditya
- Applied Catalysis A: General, Vol. 510
Integrated Biorefining: Coproduction of Renewable Resol Biopolymer for Aqueous Stream Valorization
journal, July 2017
- Wilson, A. Nolan; Price, Mariel J.; Mukarakate, Calvin
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 8
Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part I: Conversion over various catalysts
journal, December 1995
- Adjaye, J. D.; Bakhshi, N. N.
- Fuel Processing Technology, Vol. 45, Issue 3
Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks: An Integrated Study of the Fast Pyrolysis–Hydrotreating Pathway
journal, April 2015
- Howe, Daniel; Westover, Tyler; Carpenter, Daniel
- Energy & Fuels, Vol. 29, Issue 5
Selective vapor-phase hydrodeoxygenation of anisole to benzene on molybdenum carbide catalysts
journal, November 2014
- Lee, Wen-Sheng; Wang, Zhenshu; Wu, Ryan J.
- Journal of Catalysis, Vol. 319
Production of green aromatics and olefins by catalytic fast pyrolysis of wood sawdust
journal, January 2011
- Carlson, Torren R.; Cheng, Yu-Ting; Jae, Jungho
- Energy Environ. Sci., Vol. 4, Issue 1
Real-time monitoring of the deactivation of HZSM-5 during upgrading of pine pyrolysis vapors
journal, January 2014
- Mukarakate, Calvin; Zhang, Xiaodong; Stanton, Alexander R.
- Green Chem., Vol. 16, Issue 3
Synthesis of α-MoC 1− x Nanoparticles with a Surface-Modified SBA-15 Hard Template: Determination of Structure-Function Relationships in Acetic Acid Deoxygenation
journal, June 2016
- Baddour, Frederick G.; Nash, Connor P.; Schaidle, Joshua A.
- Angewandte Chemie International Edition, Vol. 55, Issue 31
Selective Conversion of Furfural to Cyclopentanone with CuZnAl Catalysts
journal, September 2014
- Guo, Jianhua; Xu, Guangyue; Han, Zheng
- ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 10
Experimental and Theoretical Insights into the Hydrogen-Efficient Direct Hydrodeoxygenation Mechanism of Phenol over Ru/TiO 2
journal, October 2015
- Nelson, Ryan C.; Baek, Byeongjin; Ruiz, Pamela
- ACS Catalysis, Vol. 5, Issue 11
Experimental and First-Principles Evidence for Interfacial Activity of Ru/TiO 2 for the Direct Conversion of m -Cresol to Toluene
journal, July 2017
- Omotoso, Taiwo O.; Baek, Byeongjin; Grabow, Lars C.
- ChemCatChem, Vol. 9, Issue 14
Integrated hydropyrolysis and hydroconversion (IH2) for the direct production of gasoline and diesel fuels or blending components from biomass, part 1: Proof of principle testing
journal, December 2011
- Marker, Terry L.; Felix, Larry G.; Linck, Martin B.
- Environmental Progress & Sustainable Energy, Vol. 31, Issue 2
Role of the Support and Reaction Conditions on the Vapor-Phase Deoxygenation of m -Cresol over Pt/C and Pt/TiO 2 Catalysts
journal, March 2016
- Griffin, Michael B.; Ferguson, Glen A.; Ruddy, Daniel A.
- ACS Catalysis, Vol. 6, Issue 4
A fundamental study of platinum tetraammine impregnation of silica2. The effect of method of preparation, loading, and calcination temperature on (reduced) particle size
journal, July 2004
- Miller, J.
- Journal of Catalysis, Vol. 225, Issue 1
Co-processing raw bio-oil and gasoil in an FCC Unit
journal, March 2015
- Pinho, Andrea de Rezende; de Almeida, Marlon B. B.; Mendes, Fabio Leal
- Fuel Processing Technology, Vol. 131
Catalytic pyrolysis of biomass for biofuels production
journal, January 2010
- French, Richard; Czernik, Stefan
- Fuel Processing Technology, Vol. 91, Issue 1
Renewable fuel production from hydropyrolysis of residual biomass using molybdenum carbide-based catalysts: An analytical Py-GC/MS investigation
journal, March 2018
- Machado, Marta A.; He, Songbo; Davies, Thomas E.
- Catalysis Today, Vol. 302
Supported molybdenum oxides as effective catalysts for the catalytic fast pyrolysis of lignocellulosic biomass
journal, January 2016
- Murugappan, Karthick; Mukarakate, Calvin; Budhi, Sridhar
- Green Chemistry, Vol. 18, Issue 20
Catalytic fast pyrolysis of glucose with HZSM-5: The combined homogeneous and heterogeneous reactions
journal, March 2010
- Carlson, Torren R.; Jae, Jungho; Lin, Yu-Chuan
- Journal of Catalysis, Vol. 270, Issue 1
Effective hydrodeoxygenation of biomass-derived oxygenates into unsaturated hydrocarbons by MoO3 using low H2 pressures
journal, January 2013
- Prasomsri, Teerawit; Nimmanwudipong, Tarit; Román-Leshkov, Yuriy
- Energy & Environmental Science, Vol. 6, Issue 6, p. 1732-1738
Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation
journal, January 2014
- Saidi, Majid; Samimi, Fereshteh; Karimipourfard, Dornaz
- Energy Environ. Sci., Vol. 7, Issue 1
Catalytic upgrading of biomass fast pyrolysis vapors with titania and zirconia/titania based catalysts
journal, August 2010
- Lu, Qiang; Zhang, Ying; Tang, Zhe
- Fuel, Vol. 89, Issue 8
Reactivity and stability investigation of supported molybdenum oxide catalysts for the hydrodeoxygenation (HDO) of m-cresol
journal, November 2015
- Shetty, Manish; Murugappan, Karthick; Prasomsri, Teerawit
- Journal of Catalysis, Vol. 331
Hydrodeoxygenation of Phenol over Zirconia-Supported Catalysts: The Effect of Metal Type on Reaction Mechanism and Catalyst Deactivation
journal, June 2017
- Teles, Camila A.; Rabelo-Neto, Raimundo C.; Jacobs, Gary
- ChemCatChem, Vol. 9, Issue 14
2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy
report, July 2016
- Langholtz, M. H.; Stokes, B. J.; Eaton, L. M.
- DOE/EE-1440
Synthesis of α-MoC 1− x Nanoparticles with a Surface-Modified SBA-15 Hard Template: Determination of Structure-Function Relationships in Acetic Acid Deoxygenation
journal, June 2016
- Baddour, Frederick G.; Nash, Connor P.; Schaidle, Joshua A.
- Angewandte Chemie, Vol. 128, Issue 31
Experimental and First-Principles Evidence for Interfacial Activity of Ru/TiO 2 for the Direct Conversion of m -Cresol to Toluene
journal, July 2017
- Omotoso, Taiwo O.; Baek, Byeongjin; Grabow, Lars C.
- ChemCatChem, Vol. 9, Issue 14
Works referencing / citing this record:
Potential synergies of drop‐in biofuel production with further co‐processing at oil refineries
journal, December 2018
- van Dyk, Susan; Su, Jianping; Mcmillan, James D.
- Biofuels, Bioproducts and Biorefining, Vol. 13, Issue 3
Hybridization of ZSM‐5 with Spinel Oxides for Biomass Vapour Upgrading
journal, January 2020
- Atanda, Luqman; Batalha, Nuno; Stark, Terra
- ChemCatChem, Vol. 12, Issue 5
Methanol to high-octane gasoline within a market-responsive biorefinery concept enabled by catalysis
journal, July 2019
- Ruddy, Daniel A.; Hensley, Jesse E.; Nash, Connor P.
- Nature Catalysis, Vol. 2, Issue 7
Synergistic effect of Mo–W carbides on selective hydrodeoxygenation of guaiacol to oxygen-free aromatic hydrocarbons
journal, January 2019
- Tran, Chi-Cong; Han, Yinglei; Garcia-Perez, Manuel
- Catalysis Science & Technology, Vol. 9, Issue 6
Metal–acid nanoplate-supported ultrafine Ru nanoclusters for efficient catalytic fractionation of lignin into aromatic alcohols
journal, January 2019
- Ullah, Naseeb; Odda, Atheer Hameid; Liang, Kuang
- Green Chemistry, Vol. 21, Issue 10
Effects of the controllable mesostructure of nano-sized ZSM-5 on the co-cracking of phenolic bio-oil model compounds and ethanol
journal, January 2019
- Wang, Wenbo; Luo, Zhongyang; Li, Simin
- Catalysis Science & Technology, Vol. 9, Issue 13