skip to main content

DOE PAGESDOE PAGES

Title: Water at Interfaces

The interfaces of neat water and aqueous solutions play a prominent role in many technological processes and in the environment. Examples of aqueous interfaces are ultrathin water films that cover most hydrophilic surfaces under ambient relative humidities, the liquid/solid interface which drives many electrochemical reactions, and the liquid/vapor interface, which governs the uptake and release of trace gases by the oceans and cloud droplets. In this work, we review some of the recent experimental and theoretical advances in our knowledge of the properties of aqueous interfaces and discuss open questions and gaps in our understanding.
Authors:
 [1] ;  [2] ;  [3] ;  [4] ;  [5] ;  [6] ;  [6] ;  [7] ;  [8] ;  [9] ;  [10] ;  [1] ;  [11] ;  [12]
  1. Uppsala Univ. (Sweden). Dept. of Physics and Astronomy
  2. Technical Univ. of Denmark, Lyngby (Denmark); Univ. of Copenhagen (Denmark). Dept. of Chemistry
  3. Univ. of Liverpool (United Kingdom). Dept. of Chemistry
  4. Univ. College London, Bloomsbury (United Kingdom). Thomas Young Center, London Center for Nanotechnology, Dept. of Physics and Astronomy and Dept. of Chemistry; Beijing Computational Science Research Center (CSRC), Beijing (China)
  5. Princeton Univ., NJ (United States). Princeton Center for Theoretical Science
  6. Univ. College London, Bloomsbury (United Kingdom). Thomas Young Center, London Center for Nanotechnology, Dept. of Physics and Astronomy and Dept. of Chemistry
  7. Univ. of Copenhagen (Denmark). Dept. of Chemistry
  8. Peking Univ., Beijing (China). International Center for Quantum Materials and School of Physics
  9. Univ. College London, Bloomsbury (United Kingdom). Thomas Young Center, London Center for Nanotechnology, Dept. of Physics and Astronomy and Dept. of Chemistry; Federal Inst. of Technology, Lausanne (Switzerland). Lab. for Fundamental BioPhotonics, Lab. of Computational Science and Modeling, Inst. of Bioengineering and Materials Science and Engineering, School of Engineering and Lausanne Center for Ultrafast Science
  10. KTH Royal Inst. of Technology, Stockholm (Sweden). Dept. of Chemistry
  11. Uppsala Univ. (Sweden). Dept. of Physics and Astronomy; Swedish Univ. of Agricultural Sciences (SLU), Uppsala (Sweden). Dept. of Chemistry and Biotechnology
  12. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
Publication Date:
Grant/Contract Number:
AC02-05CH11231; 616121
Type:
Accepted Manuscript
Journal Name:
Chemical Reviews
Additional Journal Information:
Journal Volume: 116; Journal Issue: 13; Related Information: © 2016 American Chemical Society.; Journal ID: ISSN 0009-2665
Publisher:
American Chemical Society
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division; Royal Swedish Academy of Sciences (RSAS); Swedish Research Council (SRC); European Research Council (ERC); European Union (EU); Swedish Foundation for Strategic Research (SSF); Carl Tryggers Foundation
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1465403

Björneholm, Olle, Hansen, Martin H., Hodgson, Andrew, Liu, Li-Min, Limmer, David T., Michaelides, Angelos, Pedevilla, Philipp, Rossmeisl, Jan, Shen, Huaze, Tocci, Gabriele, Tyrode, Eric, Walz, Marie-Madeleine, Werner, Josephina, and Bluhm, Hendrik. Water at Interfaces. United States: N. p., Web. doi:10.1021/acs.chemrev.6b00045.
Björneholm, Olle, Hansen, Martin H., Hodgson, Andrew, Liu, Li-Min, Limmer, David T., Michaelides, Angelos, Pedevilla, Philipp, Rossmeisl, Jan, Shen, Huaze, Tocci, Gabriele, Tyrode, Eric, Walz, Marie-Madeleine, Werner, Josephina, & Bluhm, Hendrik. Water at Interfaces. United States. doi:10.1021/acs.chemrev.6b00045.
Björneholm, Olle, Hansen, Martin H., Hodgson, Andrew, Liu, Li-Min, Limmer, David T., Michaelides, Angelos, Pedevilla, Philipp, Rossmeisl, Jan, Shen, Huaze, Tocci, Gabriele, Tyrode, Eric, Walz, Marie-Madeleine, Werner, Josephina, and Bluhm, Hendrik. 2016. "Water at Interfaces". United States. doi:10.1021/acs.chemrev.6b00045. https://www.osti.gov/servlets/purl/1465403.
@article{osti_1465403,
title = {Water at Interfaces},
author = {Björneholm, Olle and Hansen, Martin H. and Hodgson, Andrew and Liu, Li-Min and Limmer, David T. and Michaelides, Angelos and Pedevilla, Philipp and Rossmeisl, Jan and Shen, Huaze and Tocci, Gabriele and Tyrode, Eric and Walz, Marie-Madeleine and Werner, Josephina and Bluhm, Hendrik},
abstractNote = {The interfaces of neat water and aqueous solutions play a prominent role in many technological processes and in the environment. Examples of aqueous interfaces are ultrathin water films that cover most hydrophilic surfaces under ambient relative humidities, the liquid/solid interface which drives many electrochemical reactions, and the liquid/vapor interface, which governs the uptake and release of trace gases by the oceans and cloud droplets. In this work, we review some of the recent experimental and theoretical advances in our knowledge of the properties of aqueous interfaces and discuss open questions and gaps in our understanding.},
doi = {10.1021/acs.chemrev.6b00045},
journal = {Chemical Reviews},
number = 13,
volume = 116,
place = {United States},
year = {2016},
month = {5}
}