Title: Modulation of hydroxyl variability by ENSO in the absence of external forcing

Abstract

The hydroxyl radical (OH) is the primary oxidant in the troposphere, and the impact of its fluctuations on the methane budget has been disputed in recent years, however measurements of OH are insufficient to characterize global interannual fluctuations relevant for methane. Here, we use a 6,000-y control simulation of preindustrial conditions with a chemistry-climate model to quantify the natural variability in OH and internal feedbacks governing that variability. We find that, even in the absence of external forcing, maximum OH changes are 3.8 ± 0.8% over a decade, which is large in the context of the recent methane growth from 2007–2017. We show that the OH variability is not a white-noise process. A wavelet analysis indicates that OH variability exhibits significant feedbacks with the same periodicity as the El Niño–Southern Oscillation (ENSO). We find intrinsically generated modulation of the OH variability, suggesting that OH may show periods of rapid or no change in future decades that are solely due to the internal climate dynamics (as opposed to external forcings). An empirical orthogonal function analysis further indicates that ENSO is the dominant mode of OH variability, with the modulation of OH occurring primarily through lightning ${\mathrm{N}\mathrm{O}}_x$ . La Niña is associated with an increase in convection in the Tropical Pacific, which increases the simulated occurrence of lightning and allows for more OH production. Understanding this link between OH and ENSO may improve the predictability of the oxidative capacity of the troposphere and assist in elucidating the causes of current and historical trends in methane.

Authors:

Turner, Alexander J. ;

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• Search DOE PAGES for ORCID "0000-0003-1406-7372"
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Fung, Inez; Naik, Vaishali; Horowitz, Larry W. ;

• Search DOE PAGES for author "Horowitz, Larry W."
• Search DOE PAGES for ORCID "0000-0002-5886-3314"
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Cohen, Ronald C.

Publication Date:

2018-08-20

Research Org.:

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:

USDOE Office of Science (SC)

OSTI Identifier:

1465255

Alternate Identifier(s):

OSTI ID: 1482541

Grant/Contract Number:  

[AC02-05CH11231]

Resource Type:

Published Article

Journal Name:

Proceedings of the National Academy of Sciences of the United States of America

Additional Journal Information:

[Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 115 Journal Issue: 36]; Journal ID: ISSN 0027-8424

Publisher:

Proceedings of the National Academy of Sciences

Country of Publication:

United States

Language:

English

Subject:

58 GEOSCIENCES; hydroxyl; ENSO; La Niña; methane; tropospheric oxidative capacity