skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Square supramolecular assemblies of uranyl complexes in organic solvents

Abstract

Uranyl, ligand and solvent interactions lead to unique supramolecular assembly.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Washington State University, Pullman, USA
  2. Colorado School of Mines, Golden, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1465224
Grant/Contract Number:  
SC0001815
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 54 Journal Issue: 72; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Servis, Michael J., Wu, David T., Shafer, Jenifer C., and Clark, Aurora E. Square supramolecular assemblies of uranyl complexes in organic solvents. United Kingdom: N. p., 2018. Web. doi:10.1039/C8CC05277H.
Servis, Michael J., Wu, David T., Shafer, Jenifer C., & Clark, Aurora E. Square supramolecular assemblies of uranyl complexes in organic solvents. United Kingdom. doi:10.1039/C8CC05277H.
Servis, Michael J., Wu, David T., Shafer, Jenifer C., and Clark, Aurora E. Mon . "Square supramolecular assemblies of uranyl complexes in organic solvents". United Kingdom. doi:10.1039/C8CC05277H.
@article{osti_1465224,
title = {Square supramolecular assemblies of uranyl complexes in organic solvents},
author = {Servis, Michael J. and Wu, David T. and Shafer, Jenifer C. and Clark, Aurora E.},
abstractNote = {Uranyl, ligand and solvent interactions lead to unique supramolecular assembly.},
doi = {10.1039/C8CC05277H},
journal = {ChemComm},
number = 72,
volume = 54,
place = {United Kingdom},
year = {2018},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8CC05277H

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Sans Study Of Third Phase Formation In The U(vi)-hno 3 /tbp- n -dodecane System
journal, January 2003

  • Chiarizia, R.; Jensen, M. P.; Borkowski, M.
  • Separation Science and Technology, Vol. 38, Issue 12-13
  • DOI: 10.1081/SS-120022601

Dissecting the cation–cation interaction between two uranyl units
journal, January 2016

  • Tecmer, Paweł; Hong, Sung W.; Boguslawski, Katharina
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 27
  • DOI: 10.1039/C6CP03542F

Trefoil-Shaped Outer-Sphere Ion Clusters Mediate Lanthanide(III) Ion Transport with Diglycolamide Ligands
journal, November 2017

  • Brigham, Derek M.; Ivanov, Alexander S.; Moyer, Bruce A.
  • Journal of the American Chemical Society, Vol. 139, Issue 48
  • DOI: 10.1021/jacs.7b07318

Elucidation of the Structure of Organic Solutions in Solvent Extraction by Combining Molecular Dynamics and X-ray Scattering
journal, April 2014

  • Ferru, Geoffroy; Gomes Rodrigues, Donatien; Berthon, Laurence
  • Angewandte Chemie International Edition, Vol. 53, Issue 21
  • DOI: 10.1002/anie.201402677

Separations Chemistry for Actinide Elements: Recent Developments and Historical Perspective
journal, January 1997


A Review of Third Phase Formation in Extraction of Actinides by Neutral Organophosphorus Extractants
journal, November 1996


6-31G* basis set for third-row atoms
journal, January 2001

  • Rassolov, Vitaly A.; Ratner, Mark A.; Pople, John A.
  • Journal of Computational Chemistry, Vol. 22, Issue 9
  • DOI: 10.1002/jcc.1058

Outer-Sphere Water Clusters Tune the Lanthanide Selectivity of Diglycolamides
journal, June 2018


Third Phase Formation Revisited: The U(VI), HNO 3 –TBP, n ‐Dodecane System
journal, January 2003

  • Chiarizia, R.; Jensen, M. P.; Borkowski, M.
  • Solvent Extraction and Ion Exchange, Vol. 21, Issue 1
  • DOI: 10.1081/SEI-120017545

Design of Density Functionals by Combining the Method of Constraint Satisfaction with Parametrization for Thermochemistry, Thermochemical Kinetics, and Noncovalent Interactions
journal, January 2006

  • Zhao, Yan; Schultz, Nathan E.; Truhlar, Donald G.
  • Journal of Chemical Theory and Computation, Vol. 2, Issue 2
  • DOI: 10.1021/ct0502763

Supramolecular polymers constructed by orthogonal self-assembly based on host–guest and metal–ligand interactions
journal, January 2015

  • Wei, Peifa; Yan, Xuzhou; Huang, Feihe
  • Chemical Society Reviews, Vol. 44, Issue 3
  • DOI: 10.1039/C4CS00327F

The structure of tributyl phosphate solutions: Nitric acid, uranium (VI), and zirconium (IV)
journal, November 2017


Application of the Baxter Model for Hard Spheres with Surface Adhesion to SANS Data for the U(VI)−HNO 3 , TBP− n -Dodecane System
journal, November 2003

  • Chiarizia, Renato; Nash, Ken L.; Jensen, Mark P.
  • Langmuir, Vol. 19, Issue 23
  • DOI: 10.1021/la030152i

Structural insights into the multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate–n-dodecane solvent extraction system
journal, January 2017

  • Antonio, Mark R.; Ellis, Ross J.; Estes, Shanna L.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 32
  • DOI: 10.1039/C7CP03350H

Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen
journal, January 1989

  • Dunning, Thom H.
  • The Journal of Chemical Physics, Vol. 90, Issue 2
  • DOI: 10.1063/1.456153

Segmented contraction scheme for small-core actinide pseudopotential basis sets
journal, March 2004


Supramolecular Catalysis in Metal–Ligand Cluster Hosts
journal, April 2015

  • Brown, Casey J.; Toste, F. Dean; Bergman, Robert G.
  • Chemical Reviews, Vol. 115, Issue 9
  • DOI: 10.1021/cr4001226

Complexation-Induced Supramolecular Assembly Drives Metal-Ion Extraction
journal, August 2014

  • Ellis, Ross J.; Meridiano, Yannick; Muller, Julie
  • Chemistry - A European Journal, Vol. 20, Issue 40
  • DOI: 10.1002/chem.201403859

The Effect of Diluent on Third Phase Formation in Thorium Nitrate - tbp System: some Novel Empirical Correlations
journal, May 1993

  • Rao, P. R. Vasudeva; Dhamodaran, R.; Srinivasan, T. G.
  • Solvent Extraction and Ion Exchange, Vol. 11, Issue 4
  • DOI: 10.1080/07366299308918179