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Title: Outlook and Challenges for Hydrogen Storage in Nanoporous Materials

Considerable progress has been made recently in the use of nanoporous materials for hydrogen storage. In our article, the current status of the field and future challenges are discussed, ranging from important open fundamental questions, such as the density and volume of the adsorbed phase and its relationship to overall storage capacity, to the development of new functional materials and complete storage system design. With regard to fundamentals, the use of neutron scattering to study adsorbed H 2, suitable adsorption isotherm equations, and the accurate computational modelling and simulation of H 2 adsorption are discussed. We cover new materials and they include flexible metal–organic frameworks, core–shell materials, and porous organic cage compounds. The article concludes with a discussion of the experimental investigation of real adsorptive hydrogen storage tanks, the improvement in the thermal conductivity of storage beds, and new storage system concepts and designs.
 [1] ;  [2] ;  [3] ;  [3] ;  [3] ;  [4] ;  [5] ;  [6] ;  [7] ;  [7] ;  [8] ;  [7] ;  [9] ;  [9] ;  [9] ;  [9] ;  [10] ;  [11] ;  [11] ;  [12]
  1. Hiden Isochema Ltd., Warrington (United Kingdom)
  2. Griffith Univ., Brisbane (Australia). Queensland Micro- and Nanotechnology Centre
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  4. National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Delaware, Newark, DE (United States)
  5. Univ. of Quebec, Trois-Riveres, QC (Canada); Qatar Univ., Doha (Qatar)
  6. Univ. fo Crete (Greece)
  7. Univ. of Crete (Greece)
  8. Inst. of Nanoscience and Nanotechnology, Athens (Greece)
  9. Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
  10. United Technologies Research Center, East Harfort, CT (United States)
  11. Univ. of Quebec, Trois-Riveres, QC (Canada)
  12. Max Planck Inst. for Intelligent Systems, Stuttgart (Germany)
Publication Date:
Report Number(s):
Journal ID: ISSN 0947-8396
Grant/Contract Number:
AC36-08GO28308; FC36-09GO19006
Published Article
Journal Name:
Applied Physics. A, Materials Science and Processing
Additional Journal Information:
Journal Volume: 122; Related Information: Applied Physics A; Journal ID: ISSN 0947-8396
Research Org:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE National Nuclear Security Administration (NNSA)
Country of Publication:
United States
08 HYDROGEN; 36 MATERIALS SCIENCE; nanoporous materials; hydrogen storage; flexible metal-organic frameworks; core-shell materials; porous organic cage compounds
OSTI Identifier:
Alternate Identifier(s):
OSTI ID: 1242676