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Title: A wide-bandgap polymer based on the alkylphenyl-substituted benzo[1,2- b :4,5- b ′]dithiophene unit with high power conversion efficiency of over 11%

Abstract

A novel wide bandgap polymer PTZP with E optg of 2.01 eV was designed and synthesized. PSCs based on PTZP exhibited high PCE of 11.8%. PCEs of over 10% were obtained with an active layer thickness of 200 nm or an area of 0.81 cm 2 . PTZP was shown to be a promising conjugated polymer for the fabrication of efficient large area PSCs.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1];  [2]; ORCiD logo [1]; ORCiD logo [3]
  1. Laboratory of Advanced Optoelectronic Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123
  2. State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China
  3. Institute of Molecular Functional Materials, Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1464651
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry A Journal Volume: 6 Journal Issue: 34; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Guo, Xia, Li, Wanbin, Guo, Huan, Guo, Bing, Wu, Jingnan, Ma, Wei, Zhang, Maojie, and Wong, Wai-Yeung. A wide-bandgap polymer based on the alkylphenyl-substituted benzo[1,2- b :4,5- b ′]dithiophene unit with high power conversion efficiency of over 11%. United Kingdom: N. p., 2018. Web. doi:10.1039/C8TA05868G.
Guo, Xia, Li, Wanbin, Guo, Huan, Guo, Bing, Wu, Jingnan, Ma, Wei, Zhang, Maojie, & Wong, Wai-Yeung. A wide-bandgap polymer based on the alkylphenyl-substituted benzo[1,2- b :4,5- b ′]dithiophene unit with high power conversion efficiency of over 11%. United Kingdom. https://doi.org/10.1039/C8TA05868G
Guo, Xia, Li, Wanbin, Guo, Huan, Guo, Bing, Wu, Jingnan, Ma, Wei, Zhang, Maojie, and Wong, Wai-Yeung. Mon . "A wide-bandgap polymer based on the alkylphenyl-substituted benzo[1,2- b :4,5- b ′]dithiophene unit with high power conversion efficiency of over 11%". United Kingdom. https://doi.org/10.1039/C8TA05868G.
@article{osti_1464651,
title = {A wide-bandgap polymer based on the alkylphenyl-substituted benzo[1,2- b :4,5- b ′]dithiophene unit with high power conversion efficiency of over 11%},
author = {Guo, Xia and Li, Wanbin and Guo, Huan and Guo, Bing and Wu, Jingnan and Ma, Wei and Zhang, Maojie and Wong, Wai-Yeung},
abstractNote = {A novel wide bandgap polymer PTZP with E optg of 2.01 eV was designed and synthesized. PSCs based on PTZP exhibited high PCE of 11.8%. PCEs of over 10% were obtained with an active layer thickness of 200 nm or an area of 0.81 cm 2 . PTZP was shown to be a promising conjugated polymer for the fabrication of efficient large area PSCs.},
doi = {10.1039/C8TA05868G},
journal = {Journal of Materials Chemistry A},
number = 34,
volume = 6,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C8TA05868G

Citation Metrics:
Cited by: 25 works
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Works referenced in this record:

Dithienocarbazole and Isoindigo based Amorphous Low Bandgap Conjugated Polymers for Efficient Polymer Solar Cells
journal, October 2013


Balanced Partnership between Donor and Acceptor Components in Nonfullerene Organic Solar Cells with >12% Efficiency
journal, March 2018

  • Lin, Yuze; Zhao, Fuwen; Prasad, Shyamal K. K.
  • Advanced Materials, Vol. 30, Issue 16
  • DOI: 10.1002/adma.201706363

Synergistic effects of an alkylthieno[3,2-b]thiophene π-bridging backbone extension on the photovoltaic performances of donor–acceptor copolymers
journal, January 2017

  • Hwang, Hyeongjin; Sin, Dong Hun; Kulshreshtha, Chandramouli
  • Journal of Materials Chemistry A, Vol. 5, Issue 21
  • DOI: 10.1039/C7TA02557B

Thiophene-Fused Benzothiadiazole: A Strong Electron-Acceptor Unit to Build D–A Copolymer for Highly Efficient Polymer Solar Cells
journal, May 2014

  • Zhou, Pengcheng; Zhang, Zhi-Guo; Li, Yongfang
  • Chemistry of Materials, Vol. 26, Issue 11
  • DOI: 10.1021/cm501052a

A Wide-Bandgap Donor Polymer for Highly Efficient Non-fullerene Organic Solar Cells with a Small Voltage Loss
journal, April 2017

  • Chen, Shangshang; Liu, Yuhang; Zhang, Lin
  • Journal of the American Chemical Society, Vol. 139, Issue 18
  • DOI: 10.1021/jacs.7b01606

Influence of 2,2-bithiophene and thieno[3,2-b] thiophene units on the photovoltaic performance of benzodithiophene-based wide-bandgap polymers
journal, January 2017

  • Pan, Xuexue; Xiong, Wentao; Liu, Tao
  • Journal of Materials Chemistry C, Vol. 5, Issue 18
  • DOI: 10.1039/C7TC00720E

Enhancing Performance of Nonfullerene Acceptors via Side-Chain Conjugation Strategy
journal, July 2017


Naphtho[1,2-b:5,6- b ′]dithiophene Based Two-Dimensional Conjugated Polymers for Highly Efficient Thick-Film Inverted Polymer Solar Cells
journal, December 2014

  • Zhu, Xiangwei; Fang, Jin; Lu, Kun
  • Chemistry of Materials, Vol. 26, Issue 24
  • DOI: 10.1021/cm5033223

Highly Conjugated Side-Chain-Substituted Benzo[1,2- b :4,5- b ′]dithiophene-Based Conjugated Polymers for Use in Polymer Solar Cells
journal, December 2013

  • Chung, Ha-Seul; Lee, Woo-Hyung; Song, Chang Eun
  • Macromolecules, Vol. 47, Issue 1
  • DOI: 10.1021/ma402245t

New Alkylfuranyl-Substituted Benzo[1,2- b :4,5- b ′]dithiophene-Based Donor–Acceptor Polymers for Highly Efficient Solar Cells
journal, February 2013

  • Wang, Yang; Yang, Feng; Liu, Ying
  • Macromolecules, Vol. 46, Issue 4
  • DOI: 10.1021/ma3025738

A liquid crystal material as the third component for ternary polymer solar cells with an efficiency of 10.83% and enhanced stability
journal, January 2017

  • Ma, Xiaoling; Zhang, Fujun; An, Qiaoshi
  • Journal of Materials Chemistry A, Vol. 5, Issue 25
  • DOI: 10.1039/C7TA03472E

4-Alkyl-3,5-difluorophenyl-Substituted Benzodithiophene-Based Wide Band Gap Polymers for High-Efficiency Polymer Solar Cells
journal, September 2015

  • Li, Guangwu; Gong, Xue; Zhang, Jicheng
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 6
  • DOI: 10.1021/acsami.5b08769

Efficient Polymer Solar Cells Based on Poly(3-hexylthiophene) and Indene–C 60 Bisadduct Fabricated with Non-halogenated Solvents
journal, May 2014

  • Guo, Xia; Zhang, Maojie; Cui, Chaohua
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 11
  • DOI: 10.1021/am500836u

Molecular Design toward Highly Efficient Photovoltaic Polymers Based on Two-Dimensional Conjugated Benzodithiophene
journal, April 2014

  • Ye, Long; Zhang, Shaoqing; Huo, Lijun
  • Accounts of Chemical Research, Vol. 47, Issue 5
  • DOI: 10.1021/ar5000743

High Efficiency Nonfullerene Polymer Solar Cells with Thick Active Layer and Large Area
journal, July 2017


Effects of donor unit and π-bridge on photovoltaic properties of D-A copolymers based on benzo[1,2- b :4,5- c ']-dithiophene-4,8-dione acceptor unit
journal, April 2014

  • Bin, Haijun; Xiao, Lu; Liu, Yong
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 52, Issue 14
  • DOI: 10.1002/pola.27209

Benzo[1,2-b:4,5-b′]difuran and furan substituted diketopyrrolopyrrole alternating copolymer for organic photovoltaics with high fill factor
journal, January 2017

  • Du, Jia; Fortney, Andria; Washington, Katherine E.
  • Journal of Materials Chemistry A, Vol. 5, Issue 30
  • DOI: 10.1039/C7TA04618A

Design and Synthesis of a Low Bandgap Small Molecule Acceptor for Efficient Polymer Solar Cells
journal, July 2016


Recent Advances in Wide-Bandgap Photovoltaic Polymers
journal, March 2017


Systematic Investigation of Benzodithiophene- and Diketopyrrolopyrrole-Based Low-Bandgap Polymers Designed for Single Junction and Tandem Polymer Solar Cells
journal, June 2012

  • Dou, Letian; Gao, Jing; Richard, Eric
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja301460s

An Electron Acceptor Challenging Fullerenes for Efficient Polymer Solar Cells
journal, January 2015


Fused Tris(thienothiophene)-Based Electron Acceptor with Strong Near-Infrared Absorption for High-Performance As-Cast Solar Cells
journal, January 2018


PBDTTTZ: A Broad Band Gap Conjugated Polymer with High Photovoltaic Performance in Polymer Solar Cells
journal, June 2011

  • Huo, Lijun; Guo, Xia; Zhang, Shaoqing
  • Macromolecules, Vol. 44, Issue 11
  • DOI: 10.1021/ma200743b

Side Chain Structure Affects the Photovoltaic Performance of Two-Dimensional Conjugated Polymers
journal, December 2013

  • Jiang, Jian-Ming; Lin, His-Kuei; Lin, Yu-Che
  • Macromolecules, Vol. 47, Issue 1
  • DOI: 10.1021/ma401897b

A wide-bandgap conjugated polymer for highly efficient inverted single and tandem polymer solar cells
journal, January 2016

  • Guo, Bing; Guo, Xia; Li, Wanbin
  • Journal of Materials Chemistry A, Vol. 4, Issue 34
  • DOI: 10.1039/C6TA04950H

A polymer tandem solar cell with 10.6% power conversion efficiency
journal, February 2013

  • You, Jingbi; Dou, Letian; Yoshimura, Ken
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2411

Research Progress of Benzo[1,2- b :4,5- b' ]difuran Organic Photovoltaic Materials
journal, January 2016

  • Pan, Xuexue; Huo, Lijun
  • Chinese Journal of Organic Chemistry, Vol. 36, Issue 4
  • DOI: 10.6023/cjoc201512028

The Active Layer Morphology of Organic Solar Cells Probed with Grazing Incidence Scattering Techniques
journal, February 2014


Importance of Optimal Composition in Random Terpolymer-Based Polymer Solar Cells
journal, August 2013

  • Kang, Tae Eui; Cho, Han-Hee; Kim, Hyeong jun
  • Macromolecules, Vol. 46, Issue 17
  • DOI: 10.1021/ma401274r

Scalable fabrication of perovskite solar cells
journal, March 2018


Recombination in polymer-fullerene bulk heterojunction solar cells
journal, December 2010


Terthiophene-Based D–A Polymer with an Asymmetric Arrangement of Alkyl Chains That Enables Efficient Polymer Solar Cells
journal, October 2015

  • Hu, Huawei; Jiang, Kui; Yang, Guofang
  • Journal of the American Chemical Society, Vol. 137, Issue 44
  • DOI: 10.1021/jacs.5b08556

Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells
journal, November 2014

  • Liu, Yuhang; Zhao, Jingbo; Li, Zhengke
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6293

Design, Synthesis, and Photovoltaic Characterization of a Small Molecular Acceptor with an Ultra-Narrow Band Gap
journal, February 2017

  • Yao, Huifeng; Cui, Yong; Yu, Runnan
  • Angewandte Chemie International Edition, Vol. 56, Issue 11
  • DOI: 10.1002/anie.201610944

Effects of Backbone Planarity and Tightly Packed Alkyl Chains in the Donor–Acceptor Polymers for High Photostability
journal, October 2016


Effect of Isomerization on High-Performance Nonfullerene Electron Acceptors
journal, June 2018

  • Wang, Jiayu; Zhang, Junxiang; Xiao, Yiqun
  • Journal of the American Chemical Society, Vol. 140, Issue 29
  • DOI: 10.1021/jacs.8b04027

Highly efficient halogen-free solvent processed small-molecule organic solar cells enabled by material design and device engineering
journal, January 2017

  • Wan, Jiahui; Xu, Xiaopeng; Zhang, Guangjun
  • Energy & Environmental Science, Vol. 10, Issue 8
  • DOI: 10.1039/C7EE00805H

Thiazole-Based Organic Semiconductors for Organic Electronics
journal, May 2012


High-Efficiency Nonfullerene Organic Solar Cells with a Parallel Tandem Configuration
journal, July 2017

  • Zuo, Lijian; Yu, Jiangsheng; Shi, Xueliang
  • Advanced Materials, Vol. 29, Issue 34
  • DOI: 10.1002/adma.201702547

Molecular Optimization Enables over 13% Efficiency in Organic Solar Cells
journal, May 2017

  • Zhao, Wenchao; Li, Sunsun; Yao, Huifeng
  • Journal of the American Chemical Society, Vol. 139, Issue 21
  • DOI: 10.1021/jacs.7b02677

Recent advances in wide bandgap semiconducting polymers for polymer solar cells
journal, January 2017

  • Ma, Yunlong; Kang, Zhenjing; Zheng, Qingdong
  • Journal of Materials Chemistry A, Vol. 5, Issue 5
  • DOI: 10.1039/C6TA09325F

High-Lamellar Ordering and Amorphous-Like π-Network in Short-Chain Thiazolothiazole−Thiophene Copolymers Lead to High Mobilities
journal, February 2009

  • Osaka, Itaru; Zhang, Rui; Sauvé, Geneviève
  • Journal of the American Chemical Society, Vol. 131, Issue 7
  • DOI: 10.1021/ja801475h

High-performance fullerene-free polymer solar cells with 6.31% efficiency
journal, January 2015

  • Lin, Yuze; Zhang, Zhi-Guo; Bai, Huitao
  • Energy & Environmental Science, Vol. 8, Issue 2
  • DOI: 10.1039/C4EE03424D

Synthesis and Photovoltaic Properties of D–A Copolymers Based on Alkyl-Substituted Indacenodithiophene Donor Unit
journal, September 2011

  • Zhang, Maojie; Guo, Xia; Wang, Xiaochen
  • Chemistry of Materials, Vol. 23, Issue 18
  • DOI: 10.1021/cm2019586

Medium band gap conjugated polymers from thienoacene derivatives and pentacyclic aromatic lactam as promising alternatives of poly(3-hexylthiophene) in photovoltaic application
journal, October 2017

  • Gao, Peili; Tong, Junfeng; Guo, Pengzhi
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 56, Issue 1
  • DOI: 10.1002/pola.28874

Conjugated Ladder Polymers by a Cyclopentannulation Polymerization
journal, April 2017

  • Bheemireddy, Sambasiva R.; Hautzinger, Matthew P.; Li, Tao
  • Journal of the American Chemical Society, Vol. 139, Issue 16
  • DOI: 10.1021/jacs.6b12916

Synthesis and Characterization of Dioctyloxybenzo[1,2- b :4,3- b ′]dithiophene-Containing Copolymers for Polymer Solar Cells
journal, October 2011

  • Zhang, Maojie; Sun, Yeping; Guo, Xia
  • Macromolecules, Vol. 44, Issue 19
  • DOI: 10.1021/ma201565f

A Wide Bandgap Polymer with Strong π-π Interaction for Efficient Fullerene-Free Polymer Solar Cells
journal, June 2016

  • Yao, Huifeng; Yu, Runnan; Shin, Tae Joo
  • Advanced Energy Materials, Vol. 6, Issue 15
  • DOI: 10.1002/aenm.201600742

Isolating and quantifying the impact of domain purity on the performance of bulk heterojunction solar cells
journal, January 2017

  • Huang, Wenchao; Gann, Eliot; Chandrasekaran, Naresh
  • Energy & Environmental Science, Vol. 10, Issue 8
  • DOI: 10.1039/C7EE01387F

A Facile Planar Fused-Ring Electron Acceptor for As-Cast Polymer Solar Cells with 8.71% Efficiency
journal, February 2016

  • Lin, Yuze; He, Qiao; Zhao, Fuwen
  • Journal of the American Chemical Society, Vol. 138, Issue 9
  • DOI: 10.1021/jacs.6b00853

Dithienobenzodithiophene-Based Small Molecule Organic Solar Cells with over 7% Efficiency via Additive- and Thermal-Annealing-Free Processing
journal, December 2016

  • Song, Hyeng Gun; Kim, Yu Jin; Lee, Ji Sang
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 50
  • DOI: 10.1021/acsami.6b11297

Wide Bandgap Copolymers Based on Quinoxalino[6,5-f].quinoxaline for Highly Efficient Nonfullerene Polymer Solar Cells
journal, May 2017

  • Yu, Ting; Xu, Xiaopeng; Zhang, Guangjun
  • Advanced Functional Materials, Vol. 27, Issue 28
  • DOI: 10.1002/adfm.201701491

A near-infrared non-fullerene electron acceptor for high performance polymer solar cells
journal, January 2017

  • Li, Yongxi; Zhong, Lian; Gautam, Bhoj
  • Energy & Environmental Science, Vol. 10, Issue 7
  • DOI: 10.1039/C7EE00844A

Solution-Processed Organic Solar Cells Based on Dialkylthiol-Substituted Benzodithiophene Unit with Efficiency near 10%
journal, October 2014

  • Kan, Bin; Zhang, Qian; Li, Miaomiao
  • Journal of the American Chemical Society, Vol. 136, Issue 44
  • DOI: 10.1021/ja509703k

Polymer Main-Chain Substitution Effects on the Efficiency of Nonfullerene BHJ Solar Cells
journal, July 2017

  • Firdaus, Yuliar; Maffei, Luna Pratali; Cruciani, Federico
  • Advanced Energy Materials, Vol. 7, Issue 21
  • DOI: 10.1002/aenm.201700834

A Polybenzo[1,2-b:4,5-b′]dithiophene Derivative with Deep HOMO Level and Its Application in High-Performance Polymer Solar Cells
journal, January 2010


Small-Molecule Solar Cells with Simultaneously Enhanced Short-Circuit Current and Fill Factor to Achieve 11% Efficiency
journal, June 2017


Small-Molecule Acceptor Based on the Heptacyclic Benzodi(cyclopentadithiophene) Unit for Highly Efficient Nonfullerene Organic Solar Cells
journal, March 2017

  • Kan, Bin; Feng, Huanran; Wan, Xiangjian
  • Journal of the American Chemical Society, Vol. 139, Issue 13
  • DOI: 10.1021/jacs.7b01170

Developments of furan and benzodifuran semiconductors for organic photovoltaics
journal, January 2015

  • Huang, Peishen; Du, Jia; Biewer, Michael C.
  • Journal of Materials Chemistry A, Vol. 3, Issue 12
  • DOI: 10.1039/C4TA07111E

Polymer Solar Cells with 90% External Quantum Efficiency Featuring an Ideal Light- and Charge-Manipulation Layer
journal, February 2018

  • Chen, Jing-De; Li, Yan-Qing; Zhu, Jingshuai
  • Advanced Materials, Vol. 30, Issue 13
  • DOI: 10.1002/adma.201706083