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Title: High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores

The host–guest system TCNQ@Cu 3 BTC 2 is a striking example of how semiconductivity can be introduced by guest incorporation in an otherwise insulating parent material.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ;  [2] ;  [3] ; ORCiD logo [1] ; ORCiD logo [4] ; ORCiD logo [5] ; ORCiD logo [2] ; ORCiD logo [3] ; ORCiD logo [1]
  1. Department of Chemistry, Technical University Munich, 85748 Garching, Germany
  2. Institute of Physical Chemistry, Center for Materials Research (ZFM), Justus-Liebig-University Giessen, 35392 Giessen, Germany
  3. Sandia National Laboratories, Livermore, USA
  4. Laboratory of Organic Chemistry, Wageningen University & Research, 6708 WE Wageningen, The Netherlands
  5. Laboratory of Organic Chemistry, Wageningen University & Research, 6708 WE Wageningen, The Netherlands, School of Pharmaceutical Sciences and Technology
Publication Date:
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1464563