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Title: High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores

The host–guest system TCNQ@Cu 3 BTC 2 is a striking example of how semiconductivity can be introduced by guest incorporation in an otherwise insulating parent material.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ;  [2] ;  [3] ; ORCiD logo [1] ; ORCiD logo [4] ; ORCiD logo [5] ; ORCiD logo [2] ; ORCiD logo [3] ; ORCiD logo [1]
  1. Department of Chemistry, Technical University Munich, 85748 Garching, Germany
  2. Institute of Physical Chemistry, Center for Materials Research (ZFM), Justus-Liebig-University Giessen, 35392 Giessen, Germany
  3. Sandia National Laboratories, Livermore, USA
  4. Laboratory of Organic Chemistry, Wageningen University & Research, 6708 WE Wageningen, The Netherlands
  5. Laboratory of Organic Chemistry, Wageningen University & Research, 6708 WE Wageningen, The Netherlands, School of Pharmaceutical Sciences and Technology
Publication Date:
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 37; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1464563

Schneider, Christian, Ukaj, Dardan, Koerver, Raimund, Talin, A. Alec, Kieslich, Gregor, Pujari, Sidharam P., Zuilhof, Han, Janek, Jürgen, Allendorf, Mark D., and Fischer, Roland A.. High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores. United Kingdom: N. p., Web. doi:10.1039/C8SC02471E.
Schneider, Christian, Ukaj, Dardan, Koerver, Raimund, Talin, A. Alec, Kieslich, Gregor, Pujari, Sidharam P., Zuilhof, Han, Janek, Jürgen, Allendorf, Mark D., & Fischer, Roland A.. High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores. United Kingdom. doi:10.1039/C8SC02471E.
Schneider, Christian, Ukaj, Dardan, Koerver, Raimund, Talin, A. Alec, Kieslich, Gregor, Pujari, Sidharam P., Zuilhof, Han, Janek, Jürgen, Allendorf, Mark D., and Fischer, Roland A.. 2018. "High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores". United Kingdom. doi:10.1039/C8SC02471E.
@article{osti_1464563,
title = {High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores},
author = {Schneider, Christian and Ukaj, Dardan and Koerver, Raimund and Talin, A. Alec and Kieslich, Gregor and Pujari, Sidharam P. and Zuilhof, Han and Janek, Jürgen and Allendorf, Mark D. and Fischer, Roland A.},
abstractNote = {The host–guest system TCNQ@Cu 3 BTC 2 is a striking example of how semiconductivity can be introduced by guest incorporation in an otherwise insulating parent material.},
doi = {10.1039/C8SC02471E},
journal = {Chemical Science},
number = 37,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}

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