Cobalt(ii) acyl intermediates in carbon–carbon bond formation and oxygenation

Reinig, Regina R.; Fought, Ellie L.; Ellern, Arkady; Windus, Theresa L.; Sadow, Aaron D.

doi:10.1039/C8DT02661K

Title: Cobalt(ii) acyl intermediates in carbon–carbon bond formation and oxygenation

Journal Article · 30 July 2018 · Dalton Transactions

DOI: https://doi.org/10.1039/C8DT02661K · OSTI ID:1464488

Reinig, Regina R. ^[1]; Fought, Ellie L. ^[1]; Ellern, Arkady ^[1]; Windus, Theresa L. ^[1];

^[1]

Iowa State Univ., Ames, IA (United States)

Tetrahedral cobalt( ii ) hydrocarbyl and CO reversibly form acylcobalt, coupling to give α-hydroxyketone compounds, or oxygenation with O ₂ to cobalt( ii ) carboxylates.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1464488

Alternate ID(s):: OSTI ID: 1463748

Report Number(s):: IS-J-9719

Journal Information:: Dalton Transactions, Vol. 47, Issue 35; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

CCDC 1845864: Experimental Crystal Structure Determination: IFIWAY : phenyl-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt toluene solvate Space Group: P 1 (2), Cell: a 11.2319(9)Å b 11.4422(10)Å c 14.0564(12)Å, α 88.211(2)° β 87.338(2)° γ 63.3930(10)° Reinig, Regina R.; Fought, Ellie L.; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys0q The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845865: Experimental Crystal Structure Determination: IFIWEC : (benzyl)-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt Reinig, Regina; Fought, Ellie; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys1r The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845866: Experimental Crystal Structure Determination: IFIYEE : butyl-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt Reinig, Regina R.; Fought, Ellie L.; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys2s The current record is supplemented by this dataset	dataset	July 2018
CCDC 1845867: Experimental Crystal Structure Determination: IFIWIG : (2-benzyl-3-oxo-1,4-diphenylbutan-2-olato)-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt pentane solvate Reinig, Regina; Fought, Ellie; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys3t The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845868: Experimental Crystal Structure Determination: IFIWOM : (benzoato)-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt Space Group: P 1 (2), Cell: a 10.3916(9)Å b 12.2557(9)Å c 13.3566(12)Å, α 94.681(7)° β 110.553(6)° γ 112.444(5)° Reinig, Regina R.; Fought, Ellie L.; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys4v The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845869: Experimental Crystal Structure Determination: IFIWUS : ethyl-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt Reinig, Regina; Fought, Ellie; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys5w The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845870: Experimental Crystal Structure Determination: IFIXAZ : ((trimethylsilyl)methyl)-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt unknown solvate Reinig, Regina; Fought, Ellie; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys6x The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845871: Experimental Crystal Structure Determination: IFIXED : (phenylacetato)-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt Reinig, Regina R.; Fought, Ellie L.; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys7y The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845872: Experimental Crystal Structure Determination: IFIXIH : (propanoato)-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt Space Group: P 21/c (14), Cell: a 14.271(3)Å b 23.235(5)Å c 15.881(3)Å, α 90.00(3)° β 99.79(3)° γ 90.00(3)° Reinig, Regina R.; Fought, Ellie L.; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys8z The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845873: Experimental Crystal Structure Determination: IFIXON : (pentanoato)-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt Reinig, Regina; Fought, Ellie; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zys90 The current record is supplemented by this dataset	dataset	May 2018
CCDC 1845874: Experimental Crystal Structure Determination: IFIXUT : carbonyl-(propanoyl)-(tris(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenylborate)-cobalt pentane solvate Reinig, Regina; Fought, Ellie; Ellern, Arkady https://doi.org/10.5517/ccdc.csd.cc1zysb1 The current record is supplemented by this dataset	dataset	May 2018

Title: Cobalt(ii) acyl intermediates in carbon–carbon bond formation and oxygenation

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