Non-hysteretic first-order phase transition with large latent heat and giant low-field magnetocaloric effect

Guillou, F.; Pathak, A. K.; Paudyal, D.; Mudryk, Y.; Wilhelm, F.; Rogalev, A.; Pecharsky, V. K.

doi:10.1038/s41467-018-05268-4

Title: Non-hysteretic first-order phase transition with large latent heat and giant low-field magnetocaloric effect

Journal Article · 26 July 2018 · Nature Communications

DOI: https://doi.org/10.1038/s41467-018-05268-4 · OSTI ID:1464472

Guillou, F. ^[1]; Pathak, A. K. ^[1]; Paudyal, D. ^[1];

^[1]; Wilhelm, F. ^[2]; Rogalev, A. ^[2]; Pecharsky, V. K. ^[3]

Ames Lab. and Iowa State Univ., Ames, IA (United States)
European Synchrotron Radiation Facility (ESRF), Grenoble (France)
Ames Lab. and Iowa State Univ., Ames, IA (United States); Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering

First-order magnetic transitions (FOMTs) with a large discontinuity in magnetization are highly sought in the development of advanced functional magnetic materials. Isosymmetric magnetoelastic FOMTs that do not perturb crystal symmetry are especially rare, and only a handful of material families, almost exclusively transition metal-based, are known to exhibit them. Yet, here we report a surprising isosymmetric FOMT in a rare-earth intermetallic, Eu2In. What makes this transition in Eu₂In even more remarkable is that it is associated with a large latent heat and an exceptionally high magnetocaloric effect in low magnetic fields, but with tiny lattice discontinuities and negligible hysteresis. Finally, an active role of the Eu-5d and In-4p states and a rather unique electronic structure borne by In to Eu charge transfer, altogether result in an unusual exchange mechanism that both sets the transition in motion and unveils an approach toward developing specific magnetic functionalities ad libitum.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1464472

Report Number(s):: IS-J-9693; PII: 5268

Journal Information:: Nature Communications, Vol. 9, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 86 works

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Combinatorial search of thermoelastic shape-memory alloys with extremely small hysteresis width Cui, Jun; Chu, Yong S.; Famodu, Olugbenga O. Nature Materials, Vol. 5, Issue 4 https://doi.org/10.1038/nmat1593	journal	March 2006
Giant magnetocaloric effect driven by structural transitions Liu, Jian; Gottschall, Tino; Skokov, Konstantin P. Nature Materials, Vol. 11, Issue 7 https://doi.org/10.1038/nmat3334	journal	May 2012
Low-oxygen rare earth steels Li, Dianzhong; Wang, Pei; Chen, Xing-Qiu Nature Materials, Vol. 21, Issue 10 https://doi.org/10.1038/s41563-022-01352-9	journal	September 2022
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Giant magnetocaloric effect of MnAs1−xSbx Wada, H.; Tanabe, Y. Applied Physics Letters, Vol. 79, Issue 20 https://doi.org/10.1063/1.1419048	journal	November 2001
Magnetic characteristics of rare‐earth indium R ₂ In ( R =Y, Nd, Sm, Gd, Tb, Dy, Ho, Er, and Tm) intermetallic compounds Gamari‐Seale, Helen; Anagnostopoulos, T.; Yakinthos, J. K. Journal of Applied Physics, Vol. 50, Issue 1 https://doi.org/10.1063/1.325629	journal	January 1979
A theoretical and experimental study of magnetism in Gd ₂ In Singh, Vijay; Bhattacharyya, Amitava; Majumdar, Subham Journal of Applied Physics, Vol. 111, Issue 5 https://doi.org/10.1063/1.3693306	journal	March 2012
Heat capacity near first order phase transitions and the magnetocaloric effect: An analysis of the errors, and a case study of Gd5(Si2Ge2) and Dy Pecharsky, V. K.; Gschneidner, K. A. Journal of Applied Physics, Vol. 86, Issue 11 https://doi.org/10.1063/1.371734	journal	December 1999
Material-based figure of merit for caloric materials Griffith, L. D.; Mudryk, Y.; Slaughter, J. Journal of Applied Physics, Vol. 123, Issue 3 https://doi.org/10.1063/1.5004173	journal	January 2018
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Derivation of the heat capacity anomaly at a first-order transition by using a semi-adiabatic relaxation technique Hardy, Vincent; Bréard, Yohann; Martin, Christine Journal of Physics: Condensed Matter, Vol. 21, Issue 7 https://doi.org/10.1088/0953-8984/21/7/075403	journal	January 2009
First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method Anisimov, Vladimir I.; Aryasetiawan, F.; Lichtenstein, A. I. Journal of Physics: Condensed Matter, Vol. 9, Issue 4, p. 767-808 https://doi.org/10.1088/0953-8984/9/4/002	journal	January 1997
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A case of multifunctional intermetallic compounds: negative thermal expansion coupling with magnetocaloric effect in (Gd,Ho)(Co,Fe) ₂ Hu, Jinyu; Lin, Kun; Cao, Yili Inorganic Chemistry Frontiers, Vol. 6, Issue 11 https://doi.org/10.1039/c9qi00880b	journal	January 2019
The first-order magnetoelastic transition in Eu ₂ In: A ¹⁵¹ Eu Mössbauer study Ryan, D. H.; Paudyal, Durga; Guillou, Francois AIP Advances, Vol. 9, Issue 12 https://doi.org/10.1063/1.5129683	journal	December 2019
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Effect of chemical and hydrostatic pressure on the coupled magnetostructural transition of Ni-Mn-In Heusler alloys Devi, P.; Mejía, C. Salazar; Caron, L. Physical Review Materials, Vol. 3, Issue 12 https://doi.org/10.1103/physrevmaterials.3.122401	journal	December 2019
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Effect of chemical and hydrostatic pressure on the coupled magnetostructural transition of Ni-Mn-In Heusler alloys Devi, P.; Mejia, C. Salazar; Caron, L. arXiv https://doi.org/10.48550/arxiv.2004.07145	text	January 2020

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