99TcO4-remediation by a cationic polymeric network
Abstract
Direct removal of 99TcO4- from the highly acidic solution of used nuclear fuel is highly beneficial for the recovery of uranium and plutonium and more importantly aids in the elimination of 99Tc discharge into the environment. However, this task represents a huge challenge given the combined extreme conditions of super acidity, high ionic strength, and strong radiation field. Here in this paper we overcome this challenge using a cationic polymeric network with significant TcO4- uptake capabilities in four aspects: the fastest sorption kinetics, the highest sorption capacity, the most promising uptake performance from highly acidic solutions, and excellent radiation-resistance and hydrolytic stability among all anion sorbent materials reported. In addition, this material is fully recyclable for multiple sorption/desorption trials, making it extremely attractive for waste partitioning and emergency remediation. The excellent TcO4 - uptake capability is elucidated by X-ray absorption spectroscopy, solidstate NMR measurement, and density functional theory analysis on anion coordination and bonding.
- Authors:
-
[2];
[4];
- Soochow Univ., Suzhou (China). State Key Lab. of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions
- Soochow Univ., Suzhou (China). State Key Lab. of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions
- Tsinghua Univ., Beijing (China). Collaborative Innovation Center of Advanced Nuclear Energy Technology, Inst. of Nuclear and New Energy Technology
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Suzhou CNNC Huadong Radiation Co., Suzhou (China)
- CGN Dasheng Electron Accelerator Technology Co., Suzhou (China)
- Chinese Academy of Sciences (CAS), Shanghai (China). Shanghai Inst. of Microsystem and Information Technology, State Key Lab. of Functional Materials for Informatics
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry, Faculty of Science
- Florida State Univ., Tallahassee, FL (United States). Dept. of Chemistry and Biochemistry
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST); Univ. of Notre Dame, IN (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1464461
- Grant/Contract Number:
- NA0003763
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Related Information: Electronic supplementary information (ESI) available: Experimental details, adsorption capacity data, PXRD patterns, nitrogen isotherms, and SEM images. CCDC 1843055 and 1843056. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8ce00992a; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY; 36 MATERIALS SCIENCE
Citation Formats
Li, Jie, Dai, Xing, Zhu, Lin, Xu, Chao, Zhang, Duo, Silver, Mark A., Li, Peng, Chen, Lanhua, Li, Yongzhong, Zuo, Douwen, Zhang, Hui, Xiao, Chengliang, Chen, Jing, Diwu, Juan, Farha, Omar K., Albrecht-Schmitt, Thomas E., Chai, Zhifang, and Wang, Shuao. 99TcO4-remediation by a cationic polymeric network. United States: N. p., 2018.
Web. doi:10.1038/s41467-018-05380-5.
Li, Jie, Dai, Xing, Zhu, Lin, Xu, Chao, Zhang, Duo, Silver, Mark A., Li, Peng, Chen, Lanhua, Li, Yongzhong, Zuo, Douwen, Zhang, Hui, Xiao, Chengliang, Chen, Jing, Diwu, Juan, Farha, Omar K., Albrecht-Schmitt, Thomas E., Chai, Zhifang, & Wang, Shuao. 99TcO4-remediation by a cationic polymeric network. United States. https://doi.org/10.1038/s41467-018-05380-5
Li, Jie, Dai, Xing, Zhu, Lin, Xu, Chao, Zhang, Duo, Silver, Mark A., Li, Peng, Chen, Lanhua, Li, Yongzhong, Zuo, Douwen, Zhang, Hui, Xiao, Chengliang, Chen, Jing, Diwu, Juan, Farha, Omar K., Albrecht-Schmitt, Thomas E., Chai, Zhifang, and Wang, Shuao. Wed .
"99TcO4-remediation by a cationic polymeric network". United States. https://doi.org/10.1038/s41467-018-05380-5. https://www.osti.gov/servlets/purl/1464461.
@article{osti_1464461,
title = {99TcO4-remediation by a cationic polymeric network},
author = {Li, Jie and Dai, Xing and Zhu, Lin and Xu, Chao and Zhang, Duo and Silver, Mark A. and Li, Peng and Chen, Lanhua and Li, Yongzhong and Zuo, Douwen and Zhang, Hui and Xiao, Chengliang and Chen, Jing and Diwu, Juan and Farha, Omar K. and Albrecht-Schmitt, Thomas E. and Chai, Zhifang and Wang, Shuao},
abstractNote = {Direct removal of 99TcO4- from the highly acidic solution of used nuclear fuel is highly beneficial for the recovery of uranium and plutonium and more importantly aids in the elimination of 99Tc discharge into the environment. However, this task represents a huge challenge given the combined extreme conditions of super acidity, high ionic strength, and strong radiation field. Here in this paper we overcome this challenge using a cationic polymeric network with significant TcO4- uptake capabilities in four aspects: the fastest sorption kinetics, the highest sorption capacity, the most promising uptake performance from highly acidic solutions, and excellent radiation-resistance and hydrolytic stability among all anion sorbent materials reported. In addition, this material is fully recyclable for multiple sorption/desorption trials, making it extremely attractive for waste partitioning and emergency remediation. The excellent TcO4 - uptake capability is elucidated by X-ray absorption spectroscopy, solidstate NMR measurement, and density functional theory analysis on anion coordination and bonding.},
doi = {10.1038/s41467-018-05380-5},
journal = {Nature Communications},
number = 1,
volume = 9,
place = {United States},
year = {2018},
month = {8}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 183 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Design of a strong-base anion exchanger and its adsorption and elution behavior for rhenium( VII )
journal, January 2016
- Zu, Jianhua; Ye, Maosong; Wang, Puyin
- RSC Advances, Vol. 6, Issue 23
NDTB-1: A Supertetrahedral Cationic Framework That Removes TcO 4 − from Solution
journal, February 2010
- Wang, Shuao; Alekseev, Evgeny V.; Diwu, Juan
- Angewandte Chemie International Edition, Vol. 49, Issue 6
Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging
journal, December 2009
- Horcajada, Patricia; Chalati, Tamim; Serre, Christian
- Nature Materials, Vol. 9, Issue 2
Covalent Organic Frameworks as a Decorating Platform for Utilization and Affinity Enhancement of Chelating Sites for Radionuclide Sequestration
journal, March 2018
- Sun, Qi; Aguila, Briana; Earl, Lyndsey D.
- Advanced Materials, Vol. 30, Issue 20
Removal of selenate from water by chemical reduction
journal, January 1988
- Murphy, Andrew P.
- Industrial & Engineering Chemistry Research, Vol. 27, Issue 1
An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity
journal, June 2010
- Yuan, Daqiang; Zhao, Dan; Sun, Daofeng
- Angewandte Chemie International Edition, Vol. 49, Issue 31, p. 5357-5361
Metal–organic framework materials as catalysts
journal, January 2009
- Lee, JeongYong; Farha, Omar K.; Roberts, John
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
Creation of a new type of ion exchange material for rapid, high-capacity, reversible and selective ion exchange without swelling and entrainment
journal, January 2016
- Li, Baiyan; Zhang, Yiming; Ma, Dingxuan
- Chemical Science, Vol. 7, Issue 3
Water Purification: Adsorption over Metal-Organic Frameworks
journal, February 2016
- Li, Siqing; Chen, Yifa; Pei, Xiaokun
- Chinese Journal of Chemistry, Vol. 34, Issue 2
Evaluation of Brønsted acidity and proton topology in Zr- and Hf-based metal–organic frameworks using potentiometric acid–base titration
journal, January 2016
- Klet, Rachel C.; Liu, Yangyang; Wang, Timothy C.
- Journal of Materials Chemistry A, Vol. 4, Issue 4
Hydrogen storage in metal–organic frameworks
journal, January 2009
- Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
Superior capability of MgAl2O4 for selenite removal from contaminated groundwater during its reconstruction of layered double hydroxides
journal, April 2017
- Tian, Na; Zhou, Zhaoxin; Tian, Xike
- Separation and Purification Technology, Vol. 176
Exceptional Perrhenate/Pertechnetate Uptake and Subsequent Immobilization by a Low-Dimensional Cationic Coordination Polymer: Overcoming the Hofmeister Bias Selectivity
journal, May 2017
- Zhu, Lin; Xiao, Chengliang; Dai, Xing
- Environmental Science & Technology Letters, Vol. 4, Issue 7
Impeding 99Tc(IV) mobility in novel waste forms
journal, June 2016
- Lee, Mal-Soon; Um, Wooyong; Wang, Guohui
- Nature Communications, Vol. 7, Issue 1
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals
journal, July 2007
- Zhao, Yan; Truhlar, Donald G.
- Theoretical Chemistry Accounts, Vol. 120, Issue 1-3
Coupled synthesis and self-assembly of nanoparticles to give structures with controlled organization
journal, November 1999
- Li, Mei; Schnablegger, Heimo; Mann, Stephen
- Nature, Vol. 402, Issue 6760
Layered Rare-Earth Hydroxides: A Class of Pillared Crystalline Compounds for Intercalation Chemistry
journal, December 2006
- Gándara, Felipe; Perles, Josefina; Snejko, Natalia
- Angewandte Chemie International Edition, Vol. 45, Issue 47
Weaving of organic threads into a crystalline covalent organic framework
journal, January 2016
- Liu, Y.; Ma, Y.; Zhao, Y.
- Science, Vol. 351, Issue 6271
Use of redox reagents for stabilization of Pu and Np valence forms in aqueous reprocessing of spent nuclear fuel: Chemical and technological aspects
journal, August 2009
- Marchenko, V. I.; Dvoeglazov, K. N.; Volk, V. I.
- Radiochemistry, Vol. 51, Issue 4
A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials
journal, July 2011
- Fei, Honghan; Bresler, Marc R.; Oliver, Scott R. J.
- Journal of the American Chemical Society, Vol. 133, Issue 29
Structure and hydrogen bonding of the hydrated selenite and selenate ions in aqueous solution
journal, January 2014
- Eklund, Lars; Persson, Ingmar
- Dalton Trans., Vol. 43, Issue 17
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010
- Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
- The Journal of Chemical Physics, Vol. 132, Issue 15
Zirconium-Based Metal–Organic Framework for Removal of Perrhenate from Water
journal, August 2016
- Banerjee, Debasis; Xu, Wenqian; Nie, Zimin
- Inorganic Chemistry, Vol. 55, Issue 17
Enhanced immobilization of ReO4− by nanoscale zerovalent iron supported on layered double hydroxide via an advanced XAFS approach: Implications for TcO4− sequestration
journal, September 2016
- Sheng, Guodong; Tang, Yanna; Linghu, Wensheng
- Applied Catalysis B: Environmental, Vol. 192
Adsorption of rhenium(VII) on 4-amino-1,2,4-triazole resin
journal, February 2008
- Xiong, Chunhua; Yao, Caiping; Wu, Xiangmei
- Hydrometallurgy, Vol. 90, Issue 2-4
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
journal, January 1988
- Lee, Chengteh; Yang, Weitao; Parr, Robert G.
- Physical Review B, Vol. 37, Issue 2
Adsorption of selenite and selenate ions onto thiourea-formaldehyde resin
journal, May 2011
- Gezer, Nisa; Gülfen, Mustafa; Aydın, Ali Osman
- Journal of Applied Polymer Science, Vol. 122, Issue 2
Ln 2 (OH) 5 NO 3 · x H 2 O (Ln = Y, Gd−Lu): A Novel Family of Anion Exchange Intercalation Hosts
journal, January 2008
- McIntyre, Laura J.; Jackson, Lauren K.; Fogg, Andrew M.
- Chemistry of Materials, Vol. 20, Issue 1
Cationic inorganic materials for anionic pollutant trapping and catalysis
journal, January 2009
- Oliver, Scott R. J.
- Chemical Society Reviews, Vol. 38, Issue 7
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002
- Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
- Science, Vol. 295, Issue 5554, p. 469-472
Efficient and Selective Uptake of TcO 4 – by a Cationic Metal–Organic Framework Material with Open Ag + Sites
journal, March 2017
- Sheng, Daopeng; Zhu, Lin; Xu, Chao
- Environmental Science & Technology, Vol. 51, Issue 6
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Rapid Simultaneous Removal of Toxic Anions [HSeO 3 ] − , [SeO 3 ] 2– , and [SeO 4 ] 2– , and Metals Hg 2+ , Cu 2+ , and Cd 2+ by MoS 4 2– Intercalated Layered Double Hydroxide
journal, August 2017
- Ma, Lijiao; Islam, Saiful M.; Xiao, Chengliang
- Journal of the American Chemical Society, Vol. 139, Issue 36
Interaction Mechanism of Re(VII) with Zirconium Dioxide Nanoparticles Archored onto Reduced Graphene Oxides
journal, February 2017
- Gao, Yang; Chen, Ke; Tan, Xiaoli
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 3
Simultaneous speciation of inorganic rhenium and molybdenum in the industrial wastewater by amino-functionalized nano-SiO2
journal, October 2015
- Li, Yanhui; Wang, Qiong; Li, Qi
- Journal of the Taiwan Institute of Chemical Engineers, Vol. 55
High Efficiency Adsorption and Removal of Selenate and Selenite from Water Using Metal–Organic Frameworks
journal, June 2015
- Howarth, Ashlee J.; Katz, Michael J.; Wang, Timothy C.
- Journal of the American Chemical Society, Vol. 137, Issue 23
Contracted Gaussian basis sets for molecular calculations. I. Second row atoms, Z=11–18
journal, May 1980
- McLean, A. D.; Chandler, G. S.
- The Journal of Chemical Physics, Vol. 72, Issue 10, p. 5639-5648
Adsorption and separation of rhenium(VII) using N-methylimidazolium functionalized strong basic anion exchange resin: Adsorption and separation of Re(VII) using anion exchange resin
journal, August 2012
- Jia, Min; Cui, Hongmin; Jin, Weiqun
- Journal of Chemical Technology & Biotechnology, Vol. 88, Issue 3
Reversible Anion Exchange and Catalytic Properties of Two Cationic Metal−Organic Frameworks Based on Cu(I) and Ag(I)
journal, May 2010
- Fei, Honghan; Rogow, David L.; Oliver, Scott R. J.
- Journal of the American Chemical Society, Vol. 132, Issue 20
Development of Bifunctional Anion-Exchange Resins with Improved Selectivity and Sorptive Kinetics for Pertechnetate: Batch-Equilibrium Experiments
journal, September 2000
- Bonnesen, Peter V.; Brown, Gilbert M.; Alexandratos, Spiro D.
- Environmental Science & Technology, Vol. 34, Issue 17
Compositional and structural control on anion sorption capability of layered double hydroxides (LDHs)
journal, September 2006
- Wang, Yifeng; Gao, Huizhen
- Journal of Colloid and Interface Science, Vol. 301, Issue 1
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Selective Selenate Adsorption on Cationated Amino-Functionalized MCM-41
journal, November 2003
- Yokoi, Toshiyuki; Tatsumi, Takashi; Yoshitake, Hideaki
- Bulletin of the Chemical Society of Japan, Vol. 76, Issue 11
Chemical behavior of neptunium in the presence of technetium in nitric acid media
journal, January 2014
- Zhou, Xianming; Ye, Guo-an; Zhang, Hu
- Radiochimica Acta, Vol. 102, Issue 1-2
Cationic Covalent Organic Frameworks: A Simple Platform of Anionic Exchange for Porosity Tuning and Proton Conduction
journal, April 2016
- Ma, Heping; Liu, Bailing; Li, Bin
- Journal of the American Chemical Society, Vol. 138, Issue 18
Probing the correlations between the defects in metal–organic frameworks and their catalytic activity by an epoxide ring-opening reaction
journal, January 2016
- Liu, Yangyang; Klet, Rachel C.; Hupp, Joseph T.
- Chemical Communications, Vol. 52, Issue 50
Topology-directed design of porous organic frameworks and their advanced applications
journal, January 2013
- Zou, Xiaoqin; Ren, Hao; Zhu, Guangshan
- Chemical Communications, Vol. 49, Issue 38
Improving Re(VII) Adsorption on Diisobutylamine-Functionalized Graphene Oxide
journal, December 2016
- Xiong, Ying; Cui, Xurui; Zhang, Peng
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1
Metal–organic frameworks for applications in remediation of oxyanion/cation-contaminated water
journal, January 2015
- Howarth, Ashlee J.; Liu, Yangyang; Hupp, Joseph T.
- CrystEngComm, Vol. 17, Issue 38
A review of the radiation stability of ion exchange materials
journal, November 1986
- Pillay, K. K. S.
- Journal of Radioanalytical and Nuclear Chemistry Articles, Vol. 102, Issue 1
Technetium: behaviour during reprocessing of spent nuclear fuel and in environmental objects
journal, February 2003
- Popova, Natal'ya N.; Tananaev, Ivan G.; Rovnyi, Sergei I.
- Russian Chemical Reviews, Vol. 72, Issue 2
Efficient diffuse function-augmented basis sets for anion calculations. III. The 3-21+G basis set for first-row elements, Li-F
journal, October 1983
- Clark, Timothy; Chandrasekhar, Jayaraman; Spitznagel, G�nther W.
- Journal of Computational Chemistry, Vol. 4, Issue 3
Removal of TcO 4 − ions from solution: materials and future outlook
journal, January 2016
- Banerjee, Debasis; Kim, Dongsang; Schweiger, Michael J.
- Chemical Society Reviews, Vol. 45, Issue 10
Science and technology for water purification in the coming decades
journal, March 2008
- Shannon, Mark A.; Bohn, Paul W.; Elimelech, Menachem
- Nature, Vol. 452, Issue 7185, p. 301-310
Self—Consistent Molecular Orbital Methods. XII. Further Extensions of Gaussian—Type Basis Sets for Use in Molecular Orbital Studies of Organic Molecules
journal, March 1972
- Hehre, W. J.; Ditchfield, R.; Pople, J. A.
- The Journal of Chemical Physics, Vol. 56, Issue 5, p. 2257-2261
Identifying the Recognition Site for Selective Trapping of 99 TcO 4 – in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework
journal, October 2017
- Zhu, Lin; Sheng, Daopeng; Xu, Chao
- Journal of the American Chemical Society, Vol. 139, Issue 42
Towards the use of metal–organic frameworks for water reuse: a review of the recent advances in the field of organic pollutants removal and degradation and the next steps in the field
journal, January 2015
- Dias, Elton M.; Petit, Camille
- Journal of Materials Chemistry A, Vol. 3, Issue 45
Introduction to Metal–Organic Frameworks
journal, September 2011
- Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 673-674
A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis
journal, July 2010
- Ma, Liqing; Falkowski, Joseph M.; Abney, Carter
- Nature Chemistry, Vol. 2, Issue 10
Alternative energy technologies
journal, November 2001
- Dresselhaus, M. S.; Thomas, I. L.
- Nature, Vol. 414, Issue 6861
Role of assisted natural remediation in environmental cleanup
journal, October 2004
- Adriano, D. C.; Wenzel, W. W.; Vangronsveld, J.
- Geoderma, Vol. 122, Issue 2-4
Removal of Pertechnetate-Related Oxyanions from Solution Using Functionalized Hierarchical Porous Frameworks
journal, October 2016
- Banerjee, Debasis; Elsaidi, Sameh K.; Aguila, Briana
- Chemistry - A European Journal, Vol. 22, Issue 49
Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009
- Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4− in a Supertetrahedral Cationic Framework
journal, March 2012
- Wang, Shuao; Yu, Ping; Purse, Bryant A.
- Advanced Functional Materials, Vol. 22, Issue 11
Postsynthetically Modified Covalent Organic Frameworks for Efficient and Effective Mercury Removal
journal, February 2017
- Sun, Qi; Aguila, Briana; Perman, Jason
- Journal of the American Chemical Society, Vol. 139, Issue 7
Adsorption of selenite and selenate by nanocrystalline aluminum oxide, neat and impregnated in chitosan beads
journal, March 2014
- Yamani, Jamila S.; Lounsbury, Amanda W.; Zimmerman, Julie B.
- Water Research, Vol. 50
N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts
journal, January 2011
- Rose, Marcus; Notzon, Andreas; Heitbaum, Maja
- Chemical Communications, Vol. 47, Issue 16
Selenium Sequestration in a Cationic Layered Rare Earth Hydroxide: A Combined Batch Experiments and EXAFS Investigation
journal, July 2017
- Zhu, Lin; Zhang, Linjuan; Li, Jie
- Environmental Science & Technology, Vol. 51, Issue 15
Experimental and theoretical study on selenate uptake to zirconium metal–organic frameworks: Effect of defects and ligands
journal, December 2017
- Li, Jie; Liu, Yang; Wang, Xiangxue
- Chemical Engineering Journal, Vol. 330
Competitive Incorporation of Perrhenate and Nitrate into Sodalite
journal, October 2014
- Dickson, Johnbull O.; Harsh, James B.; Flury, Markus
- Environmental Science & Technology, Vol. 48, Issue 21
Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II)
journal, February 2016
- Ding, San-Yuan; Dong, Ming; Wang, Ya-Wen
- Journal of the American Chemical Society, Vol. 138, Issue 9
Desymmetrized Vertex Design for the Synthesis of Covalent Organic Frameworks with Periodically Heterogeneous Pore Structures
journal, October 2015
- Zhu, Youlong; Wan, Shun; Jin, Yinghua
- Journal of the American Chemical Society, Vol. 137, Issue 43
Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications
journal, February 2017
- Islamoglu, Timur; Goswami, Subhadip; Li, Zhanyong
- Accounts of Chemical Research, Vol. 50, Issue 4
Selenate Removal from Sulfate Containing Aqueous Solutions
journal, October 2005
- Jegadeesan, G.; Mondal, K.
- Environmental Technology, Vol. 26, Issue 10
The atom, the molecule, and the covalent organic framework
journal, March 2017
- Diercks, Christian S.; Yaghi, Omar M.
- Science, Vol. 355, Issue 6328
Rapid removal of organic micropollutants from water by a porous β-cyclodextrin polymer
journal, December 2015
- Alsbaiee, Alaaeddin; Smith, Brian J.; Xiao, Leilei
- Nature, Vol. 529, Issue 7585
Adsorption mechanisms of selenium oxyanions at the aluminum oxide/water interface
journal, November 2006
- Peak, Derek
- Journal of Colloid and Interface Science, Vol. 303, Issue 2
Porous Organic Materials: Strategic Design and Structure–Function Correlation
journal, December 2016
- Das, Saikat; Heasman, Patrick; Ben, Teng
- Chemical Reviews, Vol. 117, Issue 3
A Water-Stable Cationic Metal-Organic Framework as a Dual Adsorbent of Oxoanion Pollutants
journal, February 2016
- Desai, Aamod V.; Manna, Biplab; Karmakar, Avishek
- Angewandte Chemie International Edition, Vol. 55, Issue 27
Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis
journal, April 2008
- Kuhn, Pierre; Antonietti, Markus; Thomas, Arne
- Angewandte Chemie International Edition, Vol. 47, Issue 18
Superacidity in Sulfated Metal–Organic Framework-808
journal, September 2014
- Jiang, Juncong; Gándara, Felipe; Zhang, Yue-Biao
- Journal of the American Chemical Society, Vol. 136, Issue 37
Tailoring Microporosity in Covalent Organic Frameworks
journal, July 2008
- Tilford, R. William; Mugavero, Sam J.; Pellechia, Perry J.
- Advanced Materials, Vol. 20, Issue 14
Review of 15 years of research on ecotoxicology and remediation of land contaminated by agricultural drainage sediment rich in selenium
journal, March 2004
- Wu, Lin
- Ecotoxicology and Environmental Safety, Vol. 57, Issue 3
Reticular Chemistry—Construction, Properties, and Precision Reactions of Frameworks
journal, November 2016
- Yaghi, Omar M.
- Journal of the American Chemical Society, Vol. 138, Issue 48
Adsorption of Rhenium(VII) with Anion Exchange Resin D318
journal, January 2010
- Shu, Zengnian; Yang, Minghua
- Chinese Journal of Chemical Engineering, Vol. 18, Issue 3
Reductive immobilization of Re(VII) by graphene modified nanoscale zero-valent iron particles using a plasma technique
journal, November 2015
- Li, Jie; Chen, Changlun; Zhang, Rui
- Science China Chemistry, Vol. 59, Issue 1
Porous-Organic-Framework-Templated Nitrogen-Rich Porous Carbon as a More Proficient Electrocatalyst than Pt/C for the Electrochemical Reduction of Oxygen
journal, November 2012
- Pachfule, Pradip; Dhavale, Vishal M.; Kandambeth, Sharath
- Chemistry - A European Journal, Vol. 19, Issue 3
Energy-adjustedab initio pseudopotentials for the second and third row transition elements
journal, January 1990
- Andrae, D.; H�u�ermann, U.; Dolg, M.
- Theoretica Chimica Acta, Vol. 77, Issue 2
Efficient Capture of Perrhenate and Pertechnetate by a Mesoporous Zr Metal–Organic Framework and Examination of Anion Binding Motifs
journal, January 2018
- Drout, Riki J.; Otake, Kenichi; Howarth, Ashlee J.
- Chemistry of Materials, Vol. 30, Issue 4
Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework
journal, September 2018
- Rangwani, Sean; Howarth, Ashlee J.; DeStefano, Matthew R.
- Polyhedron, Vol. 151
Metal-organic frameworks (MOFs) in water filtration membranes for desalination and other applications
journal, June 2018
- Kadhom, Mohammed; Deng, Baolin
- Applied Materials Today, Vol. 11
Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents
journal, January 2017
- Bobbitt, N. Scott; Mendonca, Matthew L.; Howarth, Ashlee J.
- Chemical Society Reviews, Vol. 46, Issue 11
Pore surface engineering in covalent organic frameworks
journal, September 2011
- Nagai, Atsushi; Guo, Zhaoqi; Feng, Xiao
- Nature Communications, Vol. 2, Issue 1
Aquatic selenium pollution is a global environmental safety issue
journal, September 2004
- Lemly, A. Dennis
- Ecotoxicology and Environmental Safety, Vol. 59, Issue 1
Adsorption mechanism of selenate and selenite on the binary oxide systems
journal, September 2009
- Chan, Ya Ting; Kuan, Wen Hui; Chen, Tsan Yao
- Water Research, Vol. 43, Issue 17
The Adsorption of Gases on Plane Surfaces of Glass, mica and Platinum.
journal, September 1918
- Langmuir, Irving
- Journal of the American Chemical Society, Vol. 40, Issue 9
Particulate uranium, plutonium and polonium in the biogeochemistries of the coastal zone
journal, January 1979
- Hodge, V. F.; Koide, M.; Goldberg, E. D.
- Nature, Vol. 277, Issue 5693
Bio-inspired nano-traps for uranium extraction from seawater and recovery from nuclear waste
journal, April 2018
- Sun, Qi; Aguila, Briana; Perman, Jason
- Nature Communications, Vol. 9, Issue 1
Shape-Controllable Formation of Poly-imidazolium Salts for Stable Palladium N-Heterocyclic Carbene Polymers
journal, June 2014
- Zhao, Huaixia; Li, Liuyi; Wang, Yangxin
- Scientific Reports, Vol. 4, Issue 1
Alternative energy technologies
journal, January 2000
- Kolar, James L.
- Environmental Quality Management, Vol. 10, Issue 2
Layered Rare-Earth Hydroxides: A Class of Pillared Crystalline Compounds for Intercalation Chemistry
journal, December 2006
- Gándara, Felipe; Perles, Josefina; Snejko, Natalia
- Angewandte Chemie, Vol. 118, Issue 47
A Water-Stable Cationic Metal-Organic Framework as a Dual Adsorbent of Oxoanion Pollutants
journal, February 2016
- Desai, Aamod V.; Manna, Biplab; Karmakar, Avishek
- Angewandte Chemie, Vol. 128, Issue 27
Manipulating anion intercalation enables a high-voltage aqueous dual ion battery
journal, May 2021
- Huang, Zhaodong; Hou, Yue; Wang, Tairan
- Nature Communications, Vol. 12, Issue 1
NDTB-1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution
journal, December 2009
- Wang, Shuao; Alekseev, Evgeny V.; Diwu, Juan
- Angewandte Chemie, Vol. 122, Issue 6
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
text, January 1988
- Robert, Parr,; Chengteh, Lee,; Weitao, Yang,
- The University of North Carolina at Chapel Hill University Libraries
Works referencing / citing this record:
Emerging Functional Porous Polymeric and Carbonaceous Materials for Environmental Treatment and Energy Storage
journal, November 2019
- Zheng, Bingna; Lin, Xidong; Zhang, Xingcai
- Advanced Functional Materials, Vol. 30, Issue 41
Functionalized Porous Aromatic Frameworks as High‐Performance Adsorbents for the Rapid Removal of Boric Acid from Water
journal, February 2019
- Kamcev, Jovan; Taylor, Mercedes K.; Shin, Dong‐Myeong
- Advanced Materials, Vol. 31, Issue 18
Successful Decontamination of 99 TcO 4 − in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets
journal, March 2019
- Sheng, Daopeng; Zhu, Lin; Dai, Xing
- Angewandte Chemie, Vol. 131, Issue 15
Successful Decontamination of 99 TcO 4 − in Groundwater at Legacy Nuclear Sites by a Cationic Metal-Organic Framework with Hydrophobic Pockets
journal, March 2019
- Sheng, Daopeng; Zhu, Lin; Dai, Xing
- Angewandte Chemie International Edition, Vol. 58, Issue 15
A Layered Cationic Aluminum Oxyhydroxide as a Highly Efficient and Selective Trap for Heavy Metal Oxyanions
journal, June 2020
- Bai, Pu; Dong, Zhuoya; Wang, Shuang
- Angewandte Chemie International Edition
Phosphonate modified MoS2 composite material for effective adsorption of uranium(VI) in aqueous solution
journal, December 2019
- Kou, Ying; Zhang, Ling; Liu, Bo
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 323, Issue 1
Anion-adaptive crystalline cationic material for 99TcO4− trapping
journal, April 2019
- Mei, Lei; Li, Fei-ze; Lan, Jian-hui
- Nature Communications, Vol. 10, Issue 1
Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption
journal, April 2019
- Sun, Qi; Zhu, Lin; Aguila, Briana
- Nature Communications, Vol. 10, Issue 1
Super-resolution imaging of non-fluorescent reactions via competition
journal, July 2019
- Mao, Xianwen; Liu, Chunming; Hesari, Mahdi
- Nature Chemistry, Vol. 11, Issue 8
Ultra-highly selective trapping of perrhenate/pertechnetate by a flexible cationic coordination framework
journal, January 2019
- Li, Cheng-Peng; Ai, Jin-Yun; Zhou, Hang
- Chemical Communications, Vol. 55, Issue 12
Highly efficient adsorption of uranium( vi ) from aqueous solution by a novel adsorbent: titanium phosphate nanotubes
journal, January 2018
- Tang, Mengling; Chen, Juan; Wang, Peifang
- Environmental Science: Nano, Vol. 5, Issue 10
Macroscopic and microscopic investigation of uranium elimination by Ca–Mg–Al-layered double hydroxide supported nanoscale zero valent iron
journal, January 2018
- Pang, Hongwei; Wu, Yihan; Huang, Shuyi
- Inorganic Chemistry Frontiers, Vol. 5, Issue 10
Construction of a cationic organic network for highly efficient removal of anionic contaminants from water
journal, January 2019
- Li, Zhi-Jun; Xue, Hua-Dong; Zhang, Yu-Quan
- New Journal of Chemistry, Vol. 43, Issue 29
A Layered Cationic Aluminum Oxyhydroxide as a Highly Efficient and Selective Trap for Heavy Metal Oxyanions
journal, June 2020
- Bai, Pu; Dong, Zhuoya; Wang, Shuang
- Angewandte Chemie, Vol. 132, Issue 44