Cooperative Behavior in the Evolution of Alignment and Structure in Vertically Aligned Carbon-Nanotube Arrays Grown using Chemical Vapor Deposition
Abstract
We discuss the origin and the influence of autocatalytic kinetics on the structure-property relationship in the evolution of macromolecular structure during self-organized growth of vertically aligned carbon-nanotube arrays by chemical vapor deposition of acetylene. Real-time thickness measurements consistent with postgrowth structural characterization show that the rate of carbon incorporation governs not just the length of individual nanotubes, but also cooperative properties such as packing density, alignment, and order in the arrays, which profoundly affect the mechanical strength and the thermal and electrical conductivity of the assembly. Our analysis shows that the autocatalytic kinetics points to radical chain polymerization of acetylene as the most likely mechanism capable of producing the large variations in carbon-addition rates revealed by real-time data. This fresh insight provides alternative approaches for targeting specific array properties using the polymerization reaction framework for creating novel applications in high-density energy storage, advanced interconnects, and high-efficiency heat dissipation.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Binghamton Univ., State Univ. of New York, Binghamton, NY (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1504014
- Alternate Identifier(s):
- OSTI ID: 1463927; OSTI ID: 1770651
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Applied
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 2; Journal ID: ISSN 2331-7019
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Eres, Gyula, Rouleau, Christopher M., Puretzky, Alexander A., Geohegan, David B., and Wang, Howard. Cooperative Behavior in the Evolution of Alignment and Structure in Vertically Aligned Carbon-Nanotube Arrays Grown using Chemical Vapor Deposition. United States: N. p., 2018.
Web. doi:10.1103/PhysRevApplied.10.024010.
Eres, Gyula, Rouleau, Christopher M., Puretzky, Alexander A., Geohegan, David B., & Wang, Howard. Cooperative Behavior in the Evolution of Alignment and Structure in Vertically Aligned Carbon-Nanotube Arrays Grown using Chemical Vapor Deposition. United States. https://doi.org/10.1103/PhysRevApplied.10.024010
Eres, Gyula, Rouleau, Christopher M., Puretzky, Alexander A., Geohegan, David B., and Wang, Howard. Fri .
"Cooperative Behavior in the Evolution of Alignment and Structure in Vertically Aligned Carbon-Nanotube Arrays Grown using Chemical Vapor Deposition". United States. https://doi.org/10.1103/PhysRevApplied.10.024010. https://www.osti.gov/servlets/purl/1504014.
@article{osti_1504014,
title = {Cooperative Behavior in the Evolution of Alignment and Structure in Vertically Aligned Carbon-Nanotube Arrays Grown using Chemical Vapor Deposition},
author = {Eres, Gyula and Rouleau, Christopher M. and Puretzky, Alexander A. and Geohegan, David B. and Wang, Howard},
abstractNote = {We discuss the origin and the influence of autocatalytic kinetics on the structure-property relationship in the evolution of macromolecular structure during self-organized growth of vertically aligned carbon-nanotube arrays by chemical vapor deposition of acetylene. Real-time thickness measurements consistent with postgrowth structural characterization show that the rate of carbon incorporation governs not just the length of individual nanotubes, but also cooperative properties such as packing density, alignment, and order in the arrays, which profoundly affect the mechanical strength and the thermal and electrical conductivity of the assembly. Our analysis shows that the autocatalytic kinetics points to radical chain polymerization of acetylene as the most likely mechanism capable of producing the large variations in carbon-addition rates revealed by real-time data. This fresh insight provides alternative approaches for targeting specific array properties using the polymerization reaction framework for creating novel applications in high-density energy storage, advanced interconnects, and high-efficiency heat dissipation.},
doi = {10.1103/PhysRevApplied.10.024010},
journal = {Physical Review Applied},
number = 2,
volume = 10,
place = {United States},
year = {Fri Aug 10 00:00:00 EDT 2018},
month = {Fri Aug 10 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Aspects of autocatalytic reaction kinetics
journal, November 1983
- Frenklach, Michael; Clary, David
- Industrial & Engineering Chemistry Fundamentals, Vol. 22, Issue 4
Influence of the growth conditions on the defect density of single-walled carbon nanotubes
journal, June 2012
- Picher, Matthieu; Navas, Hugo; Arenal, Raul
- Carbon, Vol. 50, Issue 7
Nascent morphology of polyacetylene
journal, November 1979
- Karasz, Frank E.; Chien, James C. W.; Galkiewicz, R.
- Nature, Vol. 282, Issue 5736
Integrated simulation of active carbon nanotube forest growth and mechanical compression
journal, May 2015
- Maschmann, Matthew R.
- Carbon, Vol. 86
Controlled synthesis of single-chirality carbon nanotubes
journal, August 2014
- Sanchez-Valencia, Juan Ramon; Dienel, Thomas; Gröning, Oliver
- Nature, Vol. 512, Issue 7512
Radical processes in the pyrolysis of acetylene
journal, March 1993
- Kiefer, John H.
- International Journal of Chemical Kinetics, Vol. 25, Issue 3
Model for Self-Assembly of Carbon Nanotubes from Acetylene Based on Real-Time Studies of Vertically Aligned Growth Kinetics
journal, August 2009
- Eres, Gyula; Rouleau, C. M.; Yoon, Mina
- The Journal of Physical Chemistry C, Vol. 113, Issue 35
An activation-deactivation model for catalytic deposition of carbon
journal, November 1992
- Mcallister, P.
- Journal of Catalysis, Vol. 138, Issue 1
Science and Statistics
journal, December 1976
- Box, George E. P.
- Journal of the American Statistical Association, Vol. 71, Issue 356
Catalysts for the growth of carbon nanotube “forests” and superaligned arrays
journal, November 2017
- Chen, Guohai; Futaba, Don N.; Hata, Kenji
- MRS Bulletin, Vol. 42, Issue 11
In situ control of the catalyst efficiency in chemical vapor deposition of vertically aligned carbon nanotubes on predeposited metal catalyst films
journal, March 2004
- Eres, Gyula; Puretzky, A. A.; Geohegan, D. B.
- Applied Physics Letters, Vol. 84, Issue 10
Direct Observation of Single-Walled Carbon Nanotube Growth at the Atomistic Scale
journal, March 2006
- Lin, Ming; Ying Tan, Joyce Pei; Boothroyd, Chris
- Nano Letters, Vol. 6, Issue 3
Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes
journal, November 2004
- Hata, K.
- Science, Vol. 306, Issue 5700
Reaction mechanism of soot formation in flames
journal, February 2002
- Frenklach, Michael
- Physical Chemistry Chemical Physics, Vol. 4, Issue 11
An Analytical Solution to the Kinetics of Breakable Filament Assembly
journal, December 2009
- Knowles, T. P. J.; Waudby, C. A.; Devlin, G. L.
- Science, Vol. 326, Issue 5959
Radical processes in the pyrolysis of acetylene
journal, March 1992
- Benson, Sidney W.
- International Journal of Chemical Kinetics, Vol. 24, Issue 3
Nanotubes as polymers
journal, October 2009
- Green, Micah J.; Behabtu, Natnael; Pasquali, Matteo
- Polymer, Vol. 50, Issue 21
Population Growth Dynamics of Carbon Nanotubes
journal, October 2011
- Bedewy, Mostafa; Meshot, Eric R.; Reinker, Michael J.
- ACS Nano, Vol. 5, Issue 11
Synthesis of carbon nanotubes with and without catalyst particles
journal, April 2011
- Rümmeli, Mark Hermann; Bachmatiuk, Alicja; Börrnert, Felix
- Nanoscale Research Letters, Vol. 6, Issue 1
Altering the catalytic activity of thin metal catalyst films for controlled growth of chemical vapor deposited vertically aligned carbon nanotube arrays
journal, December 2008
- Rouleau, C. M.; Eres, G.; Cui, H.
- Applied Physics A, Vol. 93, Issue 4
Kinetics of Water-Assisted Single-Walled Carbon Nanotube Synthesis Revealed by a Time-Evolution Analysis
journal, July 2005
- Futaba, Don N.; Hata, Kenji; Yamada, Takeo
- Physical Review Letters, Vol. 95, Issue 5
Order in vertically aligned carbon nanotube arrays
journal, May 2006
- Wang, H.; Xu, Z.; Eres, G.
- Applied Physics Letters, Vol. 88, Issue 21
Sigmoidal Nucleation and Growth Curves Across Nature Fit by the Finke–Watzky Model of Slow Continuous Nucleation and Autocatalytic Growth: Explicit Formulas for the Lag and Growth Times Plus Other Key Insights
journal, February 2017
- Bentea, Lucian; Watzky, Murielle A.; Finke, Richard G.
- The Journal of Physical Chemistry C, Vol. 121, Issue 9
High-Speed in Situ X-ray Scattering of Carbon Nanotube Film Nucleation and Self-Organization
journal, May 2012
- Meshot, Eric R.; Verploegen, Eric; Bedewy, Mostafa
- ACS Nano, Vol. 6, Issue 6
Formation of carbon fibers from acetylene
journal, October 1970
- Tesner, P. A.; Robinovich, E. Y.; Rafalkes, I. S.
- Carbon, Vol. 8, Issue 4
Polyyne Chain Growth and Ring Collapse Drives Ni-Catalyzed SWNT Growth: A QM/MD Investigation
journal, April 2010
- Page, Alister J.; Irle, Stephan; Morokuma, Keiji
- The Journal of Physical Chemistry C, Vol. 114, Issue 18
Multiple Alkynes React with Ethylene To Enhance Carbon Nanotube Synthesis, Suggesting a Polymerization-like Formation Mechanism
journal, November 2010
- Plata, Desirée L.; Meshot, Eric R.; Reddy, Christopher M.
- ACS Nano, Vol. 4, Issue 12
Quantum chemical simulations reveal acetylene-based growth mechanisms in the chemical vapor deposition synthesis of carbon nanotubes
journal, June 2014
- Wang, Ying; Gao, Xingfa; Qian, Hu-Jun
- Carbon, Vol. 72
The role of cap chirality in the mechanism of growth of single-wall carbon nanotubes
journal, November 2008
- Gómez-Gualdrón, Diego A.; Balbuena, Perla B.
- Nanotechnology, Vol. 19, Issue 48
An induction period in the pyrolysis of acetylene
journal, January 2001
- Xu, Xuejun; Pacey, Philip D.
- Physical Chemistry Chemical Physics, Vol. 3, Issue 14
Molecular Beam-Controlled Nucleation and Growth of Vertically Aligned Single-Wall Carbon Nanotube Arrays
journal, September 2005
- Eres, Gyula; Kinkhabwala, Anika A.; Cui, Hongtao
- The Journal of Physical Chemistry B, Vol. 109, Issue 35
Hydrogen Abstraction/Acetylene Addition Revealed
journal, June 2014
- Parker, Dorian S. N.; Kaiser, Ralf I.; Troy, Tyler P.
- Angewandte Chemie International Edition, Vol. 53, Issue 30
One-step synthesis of graphene via catalyst-free gas-phase hydrocarbon detonation
journal, May 2013
- Nepal, Arjun; Singh, Gajendra P.; Flanders, Bret N.
- Nanotechnology, Vol. 24, Issue 24
Acetylene: A Key Growth Precursor for Single-Walled Carbon Nanotube Forests
journal, September 2009
- Zhong, G.; Hofmann, S.; Yan, F.
- The Journal of Physical Chemistry C, Vol. 113, Issue 40
The relationship between the growth rate and the lifetime in carbon nanotube synthesis
journal, January 2015
- Chen, Guohai; Davis, Robert C.; Kimura, Hiroe
- Nanoscale, Vol. 7, Issue 19
Large-Scale Synthesis of Aligned Carbon Nanotubes
journal, December 1996
- Li, W. Z.; Xie, S. S.; Qian, L. X.
- Science, Vol. 274, Issue 5293
New carbon-rich organometallic architectures based on cyclobutadienecyclopentadienylcobalt and ferrocene modules
journal, October 2003
- Bunz, Uwe H. F.
- Journal of Organometallic Chemistry, Vol. 683, Issue 2
In situ measurements and modeling of carbon nanotube array growth kinetics during chemical vapor deposition
journal, July 2005
- Puretzky, A. A.; Geohegan, D. B.; Jesse, S.
- Applied Physics A, Vol. 81, Issue 2
Carbon Nanotubes: Present and Future Commercial Applications
journal, January 2013
- De Volder, Michael F. L.; Tawfick, Sameh H.; Baughman, Ray H.
- Science, Vol. 339, Issue 6119
Quantifying the Hierarchical Order in Self-Aligned Carbon Nanotubes from Atomic to Micrometer Scale
journal, April 2017
- Meshot, Eric R.; Zwissler, Darwin W.; Bui, Ngoc
- ACS Nano, Vol. 11, Issue 6
Real-Time Imaging of Self-Organization and Mechanical Competition in Carbon Nanotube Forest Growth
journal, November 2016
- Balakrishnan, Viswanath; Bedewy, Mostafa; Meshot, Eric R.
- ACS Nano, Vol. 10, Issue 12
Hydrogen Abstraction/Acetylene Addition Revealed
journal, June 2014
- Parker, Dorian S. N.; Kaiser, Ralf I.; Troy, Tyler P.
- Angewandte Chemie, Vol. 126, Issue 30
An analytical solution to the kinetics of breakable filament assembly
text, January 2009
- Knowles, T. P. J.; Waudby, C. A.; Devlin, G. L.
- American Association for the Advancement of Science (AAAS)
Principles of polymerization
journal, November 1992
- Peppas, N. A.
- Journal of Controlled Release, Vol. 22, Issue 3
Science and Statistics
journal, June 2021
- Schipke, Jochen D.
- Diving and Hyperbaric Medicine Journal, Vol. 51, Issue 2
Works referencing / citing this record:
Thermal Transport in 3D Nanostructures
journal, August 2019
- Zhan, Haifei; Nie, Yihan; Chen, Yongnan
- Advanced Functional Materials, Vol. 30, Issue 8
Directed and On-Demand Alignment of Carbon Nanotube: A Review toward 3D Printing of Electronics
journal, January 2019
- Goh, Guo Liang; Agarwala, Shweta; Yeong, Wai Yee
- Advanced Materials Interfaces, Vol. 6, Issue 4
Vertically aligned carbon nanotube arrays as a thermal interface material
journal, February 2019
- Ping, Linquan; Hou, Peng-Xiang; Liu, Chang
- APL Materials, Vol. 7, Issue 2