Iodine in Metal–Organic Frameworks at High Pressure

Lobanov, Sergey S.; Daly, John A.; Goncharov, Alexander F.; Chan, Xiaojun; Ghose, Sanjit K.; Zhong, Hui; Ehm, Lars; Kim, Taejin; Parise, John B.

doi:10.1021/acs.jpca.8b05443

Title: Iodine in Metal–Organic Frameworks at High Pressure

Journal Article · 03 July 2018 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory

DOI: https://doi.org/10.1021/acs.jpca.8b05443 · OSTI ID:1463855

^[1]; Daly, John A. ^[2]; Goncharov, Alexander F. ^[3]; Chan, Xiaojun ^[4]; Ghose, Sanjit K. ^[5]; Zhong, Hui ^[6]; Ehm, Lars ^[7];

^[4]; Parise, John B. ^[8]

Stony Brook Univ., NY (United States). Dept. of Geosciences; Helmholtz Center Potsdam, (Germany). German Research Center for GeoSciences (GFZ)
Stony Brook Univ., NY (United States). Dept. of Chemistry
Carnegie Inst. of Washington, Washington, DC (United States). Geophysical Lab.
Stony Brook Univ., NY (United States). Dept. of Materials Science and Chemical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Stony Brook Univ., NY (United States). Joint Photon Sciences Inst.
Stony Brook Univ., NY (United States). Dept. of Geosciences; Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Stony Brook Univ., NY (United States). Dept. of Geosciences, Dept. of Chemistry and Joint Photon Sciences Inst.; Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Capture of highly volatile radioactive iodine is a promising application of metal–organic frameworks (MOFs), thanks to their high porosity with flexible chemical architecture. Specifically, strong charge-transfer binding of iodine to the framework enables efficient and selective iodine uptake as well as its long-term storage. As such, precise knowledge of the electronic structure of iodine is essential for a detailed modeling of the iodine sorption process, which will allow for rational design of iodophilic MOFs in the future. Here we probe the electronic structure of iodine in MOFs at variable iodine···framework interaction by Raman and optical absorption spectroscopy at high pressure (P). The electronic structure of iodine in the straight channels of SBMOF-1 (Ca-sdb, sdb = 4,4'-sulfonyldibenzoate) is modified irreversibly at P > 3.4 GPa by charge transfer, marking a polymerization of iodine molecules into a 1D polyiodide chain. In contrast, iodine in the sinusoidal channels of SBMOF-3 (Cd-sdb) retains its molecular (I₂) character up to at least 8.4 GPa. Such divergent high-pressure behavior of iodine in the MOFs with similar port size and chemistry illustrates adaptations of the electronic structure of iodine to channel topology and strength of the iodine···framework interaction, which can be used to tailor iodine-immobilizing MOFs.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; EAR 1763287

OSTI ID:: 1463855

Report Number(s):: BNL-207930-2018-JAAM; TRN: US1902336

Journal Information:: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Vol. 122, Issue 29; ISSN 1089-5639

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 25 works

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References (74)

The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Metal–Organic Frameworks for Air Purification of Toxic Chemicals DeCoste, Jared B.; Peterson, Gregory W. Chemical Reviews, Vol. 114, Issue 11 https://doi.org/10.1021/cr4006473	journal	April 2014
Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities Soelberg, Nick R.; Garn, Troy G.; Greenhalgh, Mitchell R. Science and Technology of Nuclear Installations, Vol. 2013 https://doi.org/10.1155/2013/702496	journal	January 2013
Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8 Sava, Dorina F.; Rodriguez, Mark A.; Chapman, Karena W. Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja204757x	journal	August 2011
Competitive I ₂ Sorption by Cu-BTC from Humid Gas Streams Sava, Dorina F.; Chapman, Karena W.; Rodriguez, Mark A. Chemistry of Materials, Vol. 25, Issue 13 https://doi.org/10.1021/cm401762g	journal	June 2013
Capture of iodine in highly stable metal–organic frameworks: a systematic study Falaise, Clément; Volkringer, Christophe; Facqueur, Jacques Chemical Communications, Vol. 49, Issue 87 https://doi.org/10.1039/c3cc43728k	journal	January 2013
A Luminescent Zinc(II) Metal–Organic Framework (MOF) with Conjugated π-Electron Ligand for High Iodine Capture and Nitro-Explosive Detection Yao, Ru-Xin; Cui, Xin; Jia, Xiao-Xia Inorganic Chemistry, Vol. 55, Issue 18 https://doi.org/10.1021/acs.inorgchem.6b01312	journal	August 2016
Capture of organic iodides from nuclear waste by metal-organic framework-based molecular traps Li, Baiyan; Dong, Xinglong; Wang, Hao Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00526-3	journal	September 2017
Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal–Organic Frameworks Zhang, Xinran; da Silva, Ivan; Godfrey, Harry G. W. Journal of the American Chemical Society, Vol. 139, Issue 45 https://doi.org/10.1021/jacs.7b08748	journal	November 2017
Iodine Adsorption in Metal Organic Frameworks in the Presence of Humidity Banerjee, Debasis; Chen, Xianyin; Lobanov, Sergey S. ACS Applied Materials & Interfaces, Vol. 10, Issue 13 https://doi.org/10.1021/acsami.8b02651	journal	March 2018
Highly Efficient Iodine Capture by Layered Double Hydroxides Intercalated with Polysulfides Ma, Shulan; Islam, Saiful M.; Shim, Yurina Chemistry of Materials, Vol. 26, Issue 24 https://doi.org/10.1021/cm5036997	journal	December 2014
Highly Efficient Enrichment of Volatile Iodine by Charged Porous Aromatic Frameworks with Three Sorption Sites Yan, Zhuojun; Yuan, Ye; Tian, Yuyang Angewandte Chemie International Edition, Vol. 54, Issue 43 https://doi.org/10.1002/anie.201503362	journal	August 2015
Reversible Iodine Capture by Nonporous Pillar[6]arene Crystals Jie, Kecheng; Zhou, Yujuan; Li, Errui Journal of the American Chemical Society, Vol. 139, Issue 43 https://doi.org/10.1021/jacs.7b09850	journal	October 2017
Thermochemical Evidence for Strong Iodine Chemisorption by ZIF-8 Hughes, James T.; Sava, Dorina F.; Nenoff, Tina M. Journal of the American Chemical Society, Vol. 135, Issue 44 https://doi.org/10.1021/ja406081r	journal	October 2013
The water-based synthesis of chemically stable Zr-based MOFs using pyridine-containing ligands and their exceptionally high adsorption capacity for iodine Wang, Zhe; Huang, Ying; Yang, Jian Dalton Transactions, Vol. 46, Issue 23 https://doi.org/10.1039/C7DT01084B	journal	January 2017
A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons Benesi, H. A.; Hildebrand, J. H. Journal of the American Chemical Society, Vol. 71, Issue 8 https://doi.org/10.1021/ja01176a030	journal	August 1949
Molecular Compounds and their Spectra. III. The Interaction of Electron Donors and Acceptors Mulliken, Robert S. The Journal of Physical Chemistry, Vol. 56, Issue 7 https://doi.org/10.1021/j150499a001	journal	July 1952
Structures of Complexes Formed by Halogen Molecules with Aromatic and with Oxygenated Solvents ¹ Mulliken, Robert S. Journal of the American Chemical Society, Vol. 72, Issue 1 https://doi.org/10.1021/ja01157a151	journal	January 1950
Molecular Complexes Involving Iodine ¹ Hastings, S. H.; Franklin, J. L.; Schiller, J. C. Journal of the American Chemical Society, Vol. 75, Issue 12 https://doi.org/10.1021/ja01108a033	journal	June 1953
The Raman spectra of some iodine, bromine, and iodine monochloride charge-transfer coomplexes in solution Klaeboe, Peter. Journal of the American Chemical Society, Vol. 89, Issue 15 https://doi.org/10.1021/ja00991a001	journal	July 1967
Molecular Compounds and their Spectra. II Mulliken, Robert S. Journal of the American Chemical Society, Vol. 74, Issue 3 https://doi.org/10.1021/ja01123a067	journal	February 1952
Effect of Pressure on Iodine Complexes. II. Absorption Spectra of the Charge Transfer Bands with Diethyl Ether, Diethyl Sulfide, and Diethyl Selenide in Heptane Sawamura, Seiji; Taniguchi, Yoshihiro; Suzuki, Keizo Bulletin of the Chemical Society of Japan, Vol. 52, Issue 2 https://doi.org/10.1246/bcsj.52.284	journal	February 1979
Modulated structure of solid iodine during its molecular dissociation under high pressure Kenichi, Takemura; Kyoko, Sato; Hiroshi, Fujihisa Nature, Vol. 423, Issue 6943 https://doi.org/10.1038/nature01724	journal	June 2003
Synthesis, Structure, and Bonding in Polyiodide and Metal Iodide−Iodine Systems Svensson, Per H.; Kloo, Lars Chemical Reviews, Vol. 103, Issue 5 https://doi.org/10.1021/cr0204101	journal	May 2003
The Chemical Imagination at Work inVery Tight Places Grochala, Wojciech; Hoffmann, Roald; Feng, Ji Angewandte Chemie International Edition, Vol. 46, Issue 20 https://doi.org/10.1002/anie.200602485	journal	May 2007
Iodine Release and Recovery, Influence of Polyiodide Anions on Electrical Conductivity and Nonlinear Optical Activity in an Interdigitated and Interpenetrated Bipillared-Bilayer Metal–Organic Framework Yin, Zheng; Wang, Qiang-Xin; Zeng, Ming-Hua Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja211381e	journal	March 2012
Iodine-templated assembly of unprecedented 3d–4f metal–organic frameworks as photocatalysts for hydrogen generation Hu, Xiao-Li; Sun, Chun-Yi; Qin, Chao Chemical Communications, Vol. 49, Issue 34 https://doi.org/10.1039/c3cc39173f	journal	January 2013
Effect of ligand geometry on selective gas-adsorption: the case of a microporous cadmium metal organic framework with a V-shaped linker Plonka, Anna M.; Banerjee, Debasis; Woerner, William R. Chemical Communications, Vol. 49, Issue 63 https://doi.org/10.1039/c3cc43299h	journal	January 2013
A Calcium Coordination Framework Having Permanent Porosity and High CO ₂ /N ₂ Selectivity Banerjee, Debasis; Zhang, Zhijuan; Plonka, Anna M. Crystal Growth & Design, Vol. 12, Issue 5 https://doi.org/10.1021/cg300274n	journal	March 2012
Thermal conductivity of lower-mantle minerals Goncharov, Alexander F.; Beck, Pierre; Struzhkin, Viktor V. Physics of the Earth and Planetary Interiors, Vol. 174, Issue 1-4 https://doi.org/10.1016/j.pepi.2008.07.033	journal	May 2009
Experimental study of thermal conductivity at high pressures: Implications for the deep Earth’s interior Goncharov, Alexander F.; Lobanov, Sergey S.; Tan, Xiaojing Physics of the Earth and Planetary Interiors, Vol. 247 https://doi.org/10.1016/j.pepi.2015.02.004	journal	October 2015
Two-dimensional detector software: From real detector to idealised image or two-theta scan Hammersley, A. P.; Svensson, S. O.; Hanfland, M. High Pressure Research, Vol. 14, Issue 4-6, p. 235-248 https://doi.org/10.1080/08957959608201408	journal	January 1996
Iodine Revisited Mulliken, Robert S. The Journal of Chemical Physics, Vol. 55, Issue 1 https://doi.org/10.1063/1.1675521	journal	July 1971
Resolution of the visible-infrared absorption spectrum of I2 into three contributing transitions Tellinghuisen, Joel The Journal of Chemical Physics, Vol. 58, Issue 7 https://doi.org/10.1063/1.1679584	journal	January 1973
Component Analysis of the Visible Absorption Spectra of I ₂ and Br ₂ in Inert Solvents: A Critique of Band Decomposition by Least-Squares Fitting Gray, Richard Ian; Luckett, Keith M.; Tellinghuisen, Joel The Journal of Physical Chemistry A, Vol. 105, Issue 50 https://doi.org/10.1021/jp012618g	journal	December 2001
Analysis of the Visible Absorption Spectrum of I ₂ in Inert Solvents Using a Physical Model Tellinghuisen, Joel The Journal of Physical Chemistry A, Vol. 116, Issue 1 https://doi.org/10.1021/jp211215v	journal	December 2011
Iodine-benzene charge-transfer complex: Potential energy surface and transition probabilities studied at several levels of theory Grozema, Ferdinand C.; Zijlstra, Robert W. J.; Swart, Marcel International Journal of Quantum Chemistry, Vol. 75, Issue 4-5 https://doi.org/10.1002/(SICI)1097-461X(1999)75:4/5<709::AID-QUA38>3.0.CO;2-N	journal	January 1999
Regularities in the Spectra of Molecular Complexes McConnell, H.; Ham, J. S.; Platt, J. R. The Journal of Chemical Physics, Vol. 21, Issue 1 https://doi.org/10.1063/1.1698626	journal	January 1953
Resonance Raman spectroscopic study on iodine in various organic solvents: Spectroscopic constants and halfband widths of the I2 vibration Kiefer, W.; Bernstein, H. J. Journal of Raman Spectroscopy, Vol. 1, Issue 5 https://doi.org/10.1002/jrs.1250010502	journal	November 1973
High-pressure studies of solid iodine by Raman spectroscopy Olijnyk, H.; Li, W.; Wokaun, A. Physical Review B, Vol. 50, Issue 2 https://doi.org/10.1103/PhysRevB.50.712	journal	July 1994
FT-Raman Study on Charge-Transfer Polyiodide Complexes and Comparison with Resonance Raman Results Deplano, Paola; Devillanova, Francesco A.; Ferraro, John R. Applied Spectroscopy, Vol. 48, Issue 10 https://doi.org/10.1366/0003702944027372	journal	October 1994
On the Use of Raman Spectroscopy in the Characterization of Iodine in Charge-Transfer Complexes Deplano, Paola; Devillanova, Francesco A.; Ferraro, John R. Applied Spectroscopy, Vol. 46, Issue 11 https://doi.org/10.1366/0003702924926880	journal	November 1992
Raman spectra of alkali metal-iodine matrix reaction products. Resonance Raman spectrum of the iodine molecular anion, I2- Howard, Wilmont F.; Andrews, Lester Journal of the American Chemical Society, Vol. 97, Issue 11 https://doi.org/10.1021/ja00844a005	journal	May 1975
Negative Linear Compressibility of a Metal–Organic Framework Li, Wei; Probert, Michael R.; Kosa, Monica Journal of the American Chemical Society, Vol. 134, Issue 29 https://doi.org/10.1021/ja305196u	journal	July 2012
Supramolecular mechanics in a metal–organic framework Ogborn, Joseph M.; Collings, Ines E.; Moggach, Stephen A. Chemical Science, Vol. 3, Issue 10 https://doi.org/10.1039/c2sc20596c	journal	January 2012
Metal–organic frameworks with wine-rack motif: What determines their flexibility and elastic properties? Ortiz, Aurélie U.; Boutin, A.; Fuchs, Alain H. The Journal of Chemical Physics, Vol. 138, Issue 17 https://doi.org/10.1063/1.4802770	journal	May 2013
On the Flexibility of Metal–Organic Frameworks Sarkisov, Lev; Martin, Richard L.; Haranczyk, Maciej Journal of the American Chemical Society, Vol. 136, Issue 6 https://doi.org/10.1021/ja411673b	journal	January 2014
Giant negative linear compression positively coupled to massive thermal expansion in a metal–organic framework Cai, Weizhao; Katrusiak, Andrzej Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5337	journal	July 2014
Structural studies of metal–organic frameworks under high pressure McKellar, Scott C.; Moggach, Stephen A. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 71, Issue 6 https://doi.org/10.1107/S2052520615018168	journal	November 2015
Pressure-Induced Bond Rearrangement and Reversible Phase Transformation in a Metal-Organic Framework Spencer, Elinor C.; Kiran, Mangalampalli S. R. N.; Li, Wei Angewandte Chemie International Edition, Vol. 53, Issue 22 https://doi.org/10.1002/anie.201310276	journal	April 2014
Vibrational Spectroscopy of Iodine-Doped Poly(Phenyl)Acetylene Ferraro, John R.; Martin, Kathleen; Furlani, Anita Applied Spectroscopy, Vol. 38, Issue 2 https://doi.org/10.1366/0003702844554017	journal	March 1984
Ionization Reaction in Iodine/Pyridine Solutions: What Can We Learn from Conductivity Measurements, Far-Infrared Spectroscopy, and Raman Scattering? Tassaing, T.; Besnard, M. The Journal of Physical Chemistry A, Vol. 101, Issue 15 https://doi.org/10.1021/jp963767f	journal	April 1997
The Spectra of Iodine Solutions. II. The Effects of High Pressures upon Iodine Complexes ¹ Ham, Joe Journal of the American Chemical Society, Vol. 76, Issue 15 https://doi.org/10.1021/ja01644a003	journal	August 1954
Electronic absorption spectra of symmetrical and asymmetrical trihalide ions Gabes, W.; Stufkens, D. J. Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 30, Issue 9 https://doi.org/10.1016/0584-8539(74)80134-0	journal	September 1974
Electronic spectra and structures of polyiodide chain complexes Mizuno, Masagi; Tanaka, Jiro; Harada, Issei The Journal of Physical Chemistry, Vol. 85, Issue 13 https://doi.org/10.1021/j150613a006	journal	June 1981
Ab initio calculations of the ground and excited states of I2− and ICl− Maslen, P. E.; Faeder, J.; Parson, R. Chemical Physics Letters, Vol. 263, Issue 1-2 https://doi.org/10.1016/S0009-2614(96)01162-1	journal	December 1996
Modeling structure and dynamics of solvated molecular ions: Photodissociation and recombination in I2−(CO2) Faeder, J.; Delaney, N.; Maslen, P. E. Chemical Physics, Vol. 239, Issue 1-3 https://doi.org/10.1016/S0301-0104(98)00309-7	journal	December 1998
Template self-assembly of polyiodide networks J. Blake, Alexander; Li, Wan-Sheung; Lippolis, Vito Chemical Society Reviews, Vol. 27, Issue 3 https://doi.org/10.1039/a827195z	journal	January 1998
Reversible Intercalation of Charged Iodine Chains into Carbon Nanotube Ropes Grigorian, L.; Williams, K. A.; Fang, S. Physical Review Letters, Vol. 80, Issue 25 https://doi.org/10.1103/PhysRevLett.80.5560	journal	June 1998
“Organic Metals”—The Intermolecular Migration of Aromaticity Perlstein, Jerome H. Angewandte Chemie International Edition in English, Vol. 16, Issue 8 https://doi.org/10.1002/anie.197705191	journal	August 1977
Structural Distortions and Charge Density Waves in Iodine Chains Encapsulated inside Carbon Nanotubes Komsa, Hannu-Pekka; Senga, Ryosuke; Suenaga, Kazutomo Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b00969	journal	May 2017
Electrically Activated Conductivity and White Light Emission of a Hydrocarbon Nanoring-Iodine Assembly Ozaki, Noriaki; Sakamoto, Hirotoshi; Nishihara, Taishi Angewandte Chemie International Edition, Vol. 56, Issue 37 https://doi.org/10.1002/anie.201703648	journal	June 2017
On the Intra- and Intermolecular Bonding in Polyiodides Kloo, Lars; Rosdahl, Jan; Svensson, Per H. European Journal of Inorganic Chemistry, Vol. 2002, Issue 5 https://doi.org/10.1002/1099-0682(200205)2002:5<1203::aid-ejic1203>3.0.co;2-o	journal	May 2002
The Chemical Imagination at Work inVery Tight Places Grochala, Wojciech; Hoffmann, Roald; Feng, Ji Angewandte Chemie International Edition, Vol. 46, Issue 20 https://doi.org/10.1002/anie.200602485	journal	May 2007
Structural Distortions and Charge Density Waves in Iodine Chains Encapsulated inside Carbon Nanotubes Komsa, Hannu-Pekka; Senga, Ryosuke; Suenaga, Kazutomo Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b00969	journal	May 2017
Metal–Organic Frameworks for Air Purification of Toxic Chemicals DeCoste, Jared B.; Peterson, Gregory W. Chemical Reviews, Vol. 114, Issue 11 https://doi.org/10.1021/cr4006473	journal	April 2014
On the Flexibility of Metal–Organic Frameworks Sarkisov, Lev; Martin, Richard L.; Haranczyk, Maciej Journal of the American Chemical Society, Vol. 136, Issue 6 https://doi.org/10.1021/ja411673b	journal	January 2014
Ionization Reaction in Iodine/Pyridine Solutions: What Can We Learn from Conductivity Measurements, Far-Infrared Spectroscopy, and Raman Scattering? Tassaing, T.; Besnard, M. The Journal of Physical Chemistry A, Vol. 101, Issue 15 https://doi.org/10.1021/jp963767f	journal	April 1997
Modulated structure of solid iodine during its molecular dissociation under high pressure Kenichi, Takemura; Kyoko, Sato; Hiroshi, Fujihisa Nature, Vol. 423, Issue 6943 https://doi.org/10.1038/nature01724	journal	June 2003
Giant negative linear compression positively coupled to massive thermal expansion in a metal–organic framework Cai, Weizhao; Katrusiak, Andrzej Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5337	journal	July 2014
Capture of iodine in highly stable metal–organic frameworks: a systematic study Falaise, Clément; Volkringer, Christophe; Facqueur, Jacques Chemical Communications, Vol. 49, Issue 87 https://doi.org/10.1039/c3cc43728k	journal	January 2013
Resolution of the visible-infrared absorption spectrum of I2 into three contributing transitions Tellinghuisen, Joel The Journal of Chemical Physics, Vol. 58, Issue 7 https://doi.org/10.1063/1.1679584	journal	January 1973
Compression curves of transition metals in the Mbar range: Experiments and projector augmented-wave calculations Dewaele, Agnès; Torrent, Marc; Loubeyre, Paul Physical Review B, Vol. 78, Issue 10 https://doi.org/10.1103/physrevb.78.104102	journal	September 2008
Effect of Pressure on Iodine Complexes. II. Absorption Spectra of the Charge Transfer Bands with Diethyl Ether, Diethyl Sulfide, and Diethyl Selenide in Heptane Sawamura, Seiji; Taniguchi, Yoshihiro; Suzuki, Keizo Bulletin of the Chemical Society of Japan, Vol. 52, Issue 2 https://doi.org/10.1246/bcsj.52.284	journal	February 1979

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