Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation

doi:10.1039/c7qi00056a

Title: Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation

Ni(ii) ions have been deposited on the Zr ₆nodes of a metal–organic framework (MOF), UiO-66,viaan ALD-like process (ALD = atomic layer deposition).

Authors:

; Peters, Aaron W. ^[1] ; ; ; Schweitzer, Neil M. ^[1] ; Hupp, Joseph T. ^[1] ; Farha, Omar K. ^[2]

Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)

Publication Date:: 2017-03-09

Grant/Contract Number:: SC0012702

Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry Frontiers (Online)

Additional Journal Information:: Journal Name: Inorganic Chemistry Frontiers (Online); Journal Volume: 4; Journal Issue: 5; Journal ID: ISSN 2052-1553

Publisher:: Royal Society of Chemistry

Research Org:: Univ. of Texas, Austin, TX (United States). Energy Frontier Research Center (EFRC)

Sponsoring Org:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

OSTI Identifier:: 1463269


                    Li, Zhanyong, Peters, Aaron W., Liu, Jian, Zhang, Xuan, Schweitzer, Neil M., Hupp, Joseph T., and Farha, Omar K.. Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation.  United States: N. p.,  
        Web.  doi:10.1039/c7qi00056a.

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                    Li, Zhanyong, Peters, Aaron W., Liu, Jian, Zhang, Xuan, Schweitzer, Neil M., Hupp, Joseph T., & Farha, Omar K.. Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation.  United States.  doi:10.1039/c7qi00056a.

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                    Li, Zhanyong, Peters, Aaron W., Liu, Jian, Zhang, Xuan, Schweitzer, Neil M., Hupp, Joseph T., and Farha, Omar K.. 2017.  
        "Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation".  United States.  
        doi:10.1039/c7qi00056a.  https://www.osti.gov/servlets/purl/1463269.

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@article{osti_1463269,

  title        = {Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation},

  author       = {Li, Zhanyong and Peters, Aaron W. and Liu, Jian and Zhang, Xuan and Schweitzer, Neil M. and Hupp, Joseph T. and Farha, Omar K.},

  abstractNote = {Ni(ii) ions have been deposited on the Zr6nodes of a metal–organic framework (MOF), UiO-66,viaan ALD-like process (ALD = atomic layer deposition).},

  doi          = {10.1039/c7qi00056a},

  journal      = {Inorganic Chemistry Frontiers (Online)},

  number       = 5,

  volume       = 4,

  place        = {United States},

  year         = {2017},

  month        = {3}

}

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Accepted Manuscript (DOE)
Publisher's Version of Record
10.1039/c7qi00056a
https://doi.org/10.1039/c7qi00056a

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Works referenced in this record:

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

Morris, William; Volosskiy, Boris; Demir, Selcuk
Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
DOI: 10.1021/ic300825s

Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes
journal, June 2015

Yang, Dong; Odoh, Samuel O.; Wang, Timothy C.
Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396
DOI: 10.1021/jacs.5b02956

Defining the Proton Topology of the Zr₆-Based Metal–Organic Framework NU-1000
journal, October 2014

Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
DOI: 10.1021/jz501899j

Vanadium-Node-Functionalized UiO-66: A Thermally Stable MOF-Supported Catalyst for the Gas-Phase Oxidative Dehydrogenation of Cyclohexene
journal, June 2014

Nguyen, Huong Giang T.; Schweitzer, Neil M.; Chang, Chih-Yi
ACS Catalysis, Vol. 4, Issue 8, p. 2496-2500
DOI: 10.1021/cs5001448

Effect of Pd Nanoparticle Size on the Catalytic Hydrogenation of Allyl Alcohol
journal, April 2006

Wilson, Orla M.; Knecht, Marc R.; Garcia-Martinez, Joaquin C.
Journal of the American Chemical Society, Vol. 128, Issue 14, p. 4510-4511
DOI: 10.1021/ja058217m

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013

Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
DOI: 10.1021/ja4050828

Metals@MOFs - Loading MOFs with Metal Nanoparticles for Hybrid Functions
journal, July 2010

Meilikhov, Mikhail; Yusenko, Kirill; Esken, Daniel
European Journal of Inorganic Chemistry, Vol. 2010, Issue 24, p. 3701-3714
DOI: 10.1002/ejic.201000473

Atomic Layer Deposition of Nanostructured Materials for Energy and Environmental Applications
journal, January 2012

Marichy, Catherine; Bechelany, Mikhael; Pinna, Nicola
Advanced Materials, Vol. 24, Issue 8, p. 1017-1032
DOI: 10.1002/adma.201104129

Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014

Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
DOI: 10.1021/ja500330a

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
DOI: 10.1021/ja8057953

Atomic Layer Deposition: An Overview
journal, January 2010

George, Steven M.
Chemical Reviews, Vol. 110, Issue 1, p. 111-131
DOI: 10.1021/cr900056b

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
Science, Vol. 341, Issue 6149, p. 1230444-1230444
DOI: 10.1126/science.1230444

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Title: Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation

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