A Brief Review of Metallothermic Reduction Reactions for Materials Preparation
Abstract
Abstract Metallothermic reduction reactions (MRRs) are displacement reactions that use reactive metals to reduce compounds so that metals, alloys, nonmetal elementary substances, and composites are produced, often in a scalable manner. In recent years, nonmetal materials, mainly silicon and carbon, particularly in their nanostructured forms obtained using an MRR with magnesium as the reductant, have started to attract much attention. However, reactions using other metals as the reductant have not been widely investigated yet. Furthermore, the reaction mechanisms and their controlling factors remain unclear, and much more effort is needed to advance this emerging field. Here, MRR preparation methods for metals, alloys, nanoporous silicon, nanoporous carbon, and composites are discussed as an introduction for new researchers in this field.
- Authors:
-
[1]
- Oregon State Univ., Corvallis, OR (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1543135
- Alternate Identifier(s):
- OSTI ID: 1463211
- Grant/Contract Number:
- AC02-06CH11357; DE‐EE0008194
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Small Methods
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 12; Journal ID: ISSN 2366-9608
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; lithiothermic; magnesiothermic; metallothermic; nanoporous graphene; nanoporous silicon
Citation Formats
Xing, Zhenyu, Lu, Jun, and Ji, Xiulei. A Brief Review of Metallothermic Reduction Reactions for Materials Preparation. United States: N. p., 2018.
Web. doi:10.1002/smtd.201800062.
Xing, Zhenyu, Lu, Jun, & Ji, Xiulei. A Brief Review of Metallothermic Reduction Reactions for Materials Preparation. United States. https://doi.org/10.1002/smtd.201800062
Xing, Zhenyu, Lu, Jun, and Ji, Xiulei. Tue .
"A Brief Review of Metallothermic Reduction Reactions for Materials Preparation". United States. https://doi.org/10.1002/smtd.201800062. https://www.osti.gov/servlets/purl/1543135.
@article{osti_1543135,
title = {A Brief Review of Metallothermic Reduction Reactions for Materials Preparation},
author = {Xing, Zhenyu and Lu, Jun and Ji, Xiulei},
abstractNote = {Abstract Metallothermic reduction reactions (MRRs) are displacement reactions that use reactive metals to reduce compounds so that metals, alloys, nonmetal elementary substances, and composites are produced, often in a scalable manner. In recent years, nonmetal materials, mainly silicon and carbon, particularly in their nanostructured forms obtained using an MRR with magnesium as the reductant, have started to attract much attention. However, reactions using other metals as the reductant have not been widely investigated yet. Furthermore, the reaction mechanisms and their controlling factors remain unclear, and much more effort is needed to advance this emerging field. Here, MRR preparation methods for metals, alloys, nanoporous silicon, nanoporous carbon, and composites are discussed as an introduction for new researchers in this field.},
doi = {10.1002/smtd.201800062},
journal = {Small Methods},
number = 12,
volume = 2,
place = {United States},
year = {Tue Aug 07 00:00:00 EDT 2018},
month = {Tue Aug 07 00:00:00 EDT 2018}
}
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